Agata Krasuska

Increasing plastic waste generation has become a pressing environmental problem. One of the most produced waste plastics originates from post-consumer packaging, of which PET constitutes a significant portion. Despite increasing recycling rates, its accumulation has created a need for the development of new recycling methods that can further expand the possibilities of recycling. In this paper, we present the application of Lewis acid catalysts for the depolymerization of PET waste. The obtained results show the formation of diisodecyl terephthalate (DIDTP), which is used as a PVC plasticizer. For this purpose, several Lewis acid catalysts were tested, including tin, cobalt, manganese, zirconium, zinc, and calcium derivatives, alongside zinc acetate and potassium hydroxide, which were used as reference catalysts. Our results show that tin (II) oxalate is the most effective catalyst, and it was then used to synthesize two application samples (crude and purified). The physicochemical properties of PVC mixtures with the obtained samples were determined and compared to commercial plasticizers, where both plasticizers had similar plasticizing properties to PVC plasticization.

The plasticizers used in this study were synthesized from renewable raw materials using succinic acid, oleic acid, and propylene glycol. Four environmentally friendly plasticizer samples were obtained; their chemical structures and compositions were confirmed by gas chromatography (GC) and infrared spectroscopy (FT–IR) analyses, and their physicochemical properties and thermal stability (TGA analysis) were investigated. The obtained ester mixtures were used as poly(vinyl chloride) (PVC) plasticizers and their plasticization efficiency was determined in comparison to traditional, commercially available phthalate plasticizers, such as DEHP (di(2-ethylhexyl phthalate) and DINP (diisononyl phthalate). Mechanical properties and migration resistance were determined for soft PVC with the use of three concentrations of plasticizers (40 PHR, 50 PHR, and 60 PHR). It was observed that the obtained plasticizers exhibited the same plasticization efficiency and were characterized with good mechanical and physical properties in comparison to commercial plasticizers. The tensile strength was approx. 19 MPa, while the elongation at break was approx. 250% for all tested plasticizers at a concentration of 50 PHR. Furthermore, plasticizer migration studies showed that the synthesized plasticizers had excellent resistance to plasticizer leaching. The best migration test result obtained was 70% lower than that for DEHP or DINP. The ester mixture that was found to be the most favorable plasticizer was characterized by good thermal and thermo-oxidative stability (5% weight loss temperature: 227.8 °C in air and 261.1 °C in nitrogen). The results of the research clearly indicate that the synthesized esters can provide a green alternative to toxic phthalate plasticizers.