Lin Luo

Sorptive removal of hexavalent chromium (Cr(VI)) bears the advantages of simple operation and easy construction. Customized polymeric materials are the attracting adsorbents due to their selectivity, chemical and mechanical stabilities. The mostly investigated polymeric materials for removing Cr(VI) were reviewed in this work. Assembling of robust functional groups, reduction of self-aggregation, and enhancement of stability and mechanical strength, were the general strategies to improve the performance of polymeric adsorbents. The maximum adsorption capacities of these polymers toward Cr(VI) fitted by Langmuir isotherm model ranged from 3.2 to 1185 mg/g. Mechanisms of complexation, chelation, reduction, electrostatic attraction, anion exchange, and hydrogen bonding were involved in the Cr(VI) removal. Influence factors on Cr(VI) removal were itemized. Polymeric adsorbents performed much better in the strong acidic pH range (e.g., pH 2.0) and at higher initial Cr(VI) concentrations. The adsorption of Cr(VI) was an endothermic reaction, and higher reaction temperature favored more robust adsorption. Anions inhibited the removal of Cr(VI) through competitive adsorption, while that was barely affected by cations. Factors that affected the regeneration of these adsorbents were summarized. To realize the goal of industrial application and environmental protection, removal of the Cr(VI) accompanied by its detoxication through reduction is highly encouraged. Moreover, development of adsorbents with strong regeneration ability and low cost, which are robust for removing Cr(VI) at trace levels and a wider pH range, should also be an eternally immutable subject in the future. Work done will be helpful for developing more robust polymeric adsorbents and for promoting the treatment of Cr(VI)-containing wastewater.

The treatment of Sb (III) wastewater produced from mining activities is uniquely challenging and has therefore garnered increasing attention. Here, an amino-modified zirconium-based metal-organic framework material (UiO-66-NH₂) and its composites were loaded onto graphene oxide (GO@UiO-66-NH₂) via the hydrothermal method, after which these materials were used to adsorb Sb (III) in mine wastewater. The effects of adsorption time, pH, initial Sb (III) concentration, temperature, and adsorbent dosage on the removal performance of Sb (III) were then investigated. The adsorption processes of Sb (III) were examined via adsorption kinetic, isotherm, and thermodynamic analyses. XRD, SEM, and FTIR analyses demonstrated the presence of a porous structure and high levels of oxygen-containing functional groups on the UiO-66-NH₂ and GO@UiO-66-NH₂ surfaces. During the Sb (III) adsorption process, the adsorption rates of UiO-66-NH₂ and GO@UiO-66-NH₂ were very fast in the first 10 minutes, and the adsorption equilibrium was achieved in 12 h, with the adsorption efficiencies of 91.76% and 93.79%, respectively. At a pH of 7.0, 25°C, an initial Sb (III) concentration of 100 mg/L, and an adsorbent dosage of 0.04 g/L, the maximum Sb (III) adsorption capacities of UiO-66-NH₂ and GO@UiO-66-NH₂ reached 39.23 mg/g and 61.07 mg/g, respectively. The adsorption process was accurately described by the Langmuir model, meaning that the Sb (III) was adsorbed through single-layer uniform adsorption. Moreover, the adsorption process was highly consistent with the pseudo-second-order model, which was indicative of spontaneous and endothermic chemical adsorption. Additionally, the Sb (III) removal efficiency could be maintained approximately 70% after sorption-desorption recycling four times. Therefore, our study provides an economical and effective method for the removal of Sb (III) in wastewater treatment.