Rahul Sahay

Accumulative rolling bonding (ARB) Cu/Nb nanolaminates have been widely observed to exhibit unique and large numbers of interface-based plasticity mechanisms, and these have been associated with the many extraordinary properties of the material system, especially resistances in extreme engineering environments (mechanical/pressure, thermal, irradiation, etc.) and ability to self-heal defects (microstructural, as well as radiation-induced). Recently, anisotropy in the interface shearing mechanisms in the material system has been observed and much discussed. The Cu/Nb nanolaminates appear to shear on the interface planes to a much larger extent in the transverse direction (TD) than in the rolling direction (RD). Related to that, in this present study we observe interface rotation in Cu/Nb ARB nanolaminates under constrained and unconstrained loading conditions. Although the primary driving force for interface shearing was expected only in the RD, additional shearing in the TD was observed. This is significant as it represents an interface rotation, while there was no external rotational driving force. First, we observed interface rotation in in situ rectangular micropillar compression experiments, where the interface is simply sheared in one particular direction only, i.e., in the RD. This is rather unexpected as, in rectangular micropillar compression, there is no possibility of extra shearing or driving force in the perpendicular direction due to the loading conditions. This motivated us to subsequently perform in situ microbeam bending experiments (microbeam with a pre-made notch) to verify if similar interface rotation could also be observed in other loading modes. In the beam bending mode, the notch area was primarily under tensile stress in the direction of the beam longitudinal axis, with interfacial shear also in the same direction. Hence, we expect interface shearing only in that direction. We then found that interface rotation was also evident and repeatable under certain circumstances, such as under an offset loading. As this behaviour was consistently observed under two distinct loading modes, we propose that it is an intrinsic characteristic of Cu/Nb interfaces (or FCC/BCC interfaces with specific orientation relationships). This interface rotation represents another interface-based or interface-mediated plasticity mechanism at the nanoscale with important potential implications especially for design of metallic thin films with extreme stretchability and other emerging applications.

Functionalizing single-walled carbon nanotubes (SWCNT) with different chemical functional groups directly enhances their chemical adhesion and dispersion in viscous polymeric resins such as polydimethylsiloxane (PDMS). Nevertheless, the ideal surface polarity (hydrophilic or hydrophobic) for SWCNT to foster stronger chemical bonding with PDMS remains uncertain. This investigation delves into the impact of enhanced SWCNT dispersion within PDMS on the surface mechanical characteristics of this flexible composite system. We use carboxylic acid-functionalized SWCNT (COOH–SWCNT) and silane-functionalized SWCNT (sily–SWCNT), recognized for their hydrophilic and hydrophobic surface polarities, respectively, as reinforcing agents at ultra-low weight percentage loadings: 0.05 wt%, 0.5 wt%, and 1 wt%. We perform quasi-static nanoindentation analysis employing a Berkovich tip to probe the localized mechanical behavior of PDMS–SWCNT films at an indentation depth of 1 μm. Plastic deformation within the samples, denoted as plastic work (W_p), as well as the elastic modulus (E), hardness (H), and contact stiffness (S_c) of the composites are examined from the force–displacement curves to elucidate the enhancement in the surface mechanical attributes of the composite films.

Novel fracture/fatigue resistant nickel–niobium oxide (crystalline–amorphous) sandwich nanolayers on a polyimide (PI) substrate as a potential candidate for electrodes or interconnects for flexible electronic or energy devices.

We propose a new formula that extracts the quantum Hall conductance from a single (2+1)D gapped wavefunction. The formula applies to general many-body systems that conserve particle number, and is based on the concept of modular flow: i.e., unitary dynamics generated from the entanglement structure of the wavefunction. The formula is shown to satisfy all formal properties of the Hall conductance: it is odd under time-reversal and reflection, even under charge conjugation, universal and topologically rigid in the thermodynamic limit. Further evidence for relating the formula to the Hall conductance is obtained from conformal field theory arguments. Finally, we numerically check the formula by applying it to a non-interacting Chern band where excellent agreement is obtained.

When silicon solar cells are used in the novel lightweight photovoltaic (PV) modules using a sandwich design with polycarbonate sheets on both the front and back sides of the cells, they are much more prone to impact loading, which may be prevalent in four-season countries during wintertime. Yet, the lightweight PV modules have recently become an increasingly important development, especially for certain segments of the renewable energy markets all over the world—such as exhibition halls, factories, supermarkets, farms, etc.—including in countries with harsh hailstorms during winter. Even in the standard PV module design using glass as the front sheet, the silicon cells inside remain fragile and may be prone to impact loading. This impact loading has been widely known to lead to cracks in the silicon solar cells that over an extended period of time may significantly degrade performance (output power). In our group’s previous work, a 3D helicoidally architected fiber-based polymer composite (enabled by an electrospinning-based additive manufacturing methodology) was found to exhibit excellent impact resistance—absorbing much of the energy from the impact load—such that the silicon solar cells encapsulated on both sides by this material breaks only at significantly higher impact load/energy, compared to when a standard, commercial PV encapsulant material was used. In the present study, we aim to use numerical simulation and modeling to enhance our understanding of the stress distribution and evolution during impact loading on such helicoidally arranged fiber-based composite materials, and thus the damage evolution and mechanisms. This could further aid the implementation of the lightweight PV technology for the unique market needs, especially in countries with extreme winter seasons.

Nanolaminates are extensively studied due to their unique properties, such as impact resistance, high fracture toughness, high strength, and resistance to radiation damage. Varieties of nanolaminates are being fabricated to achieve high strength and fracture toughness. In this study, one such nanolaminate fabricated through accumulative roll bonding (Cu(16)/Nb(16) ARB nanolaminate, where 16 nm is the layer thickness) was used as a test material. Cu(16)/Nb(16) ARB nanolaminate exhibits crystallographic anisotropy due to the existence of distinct interfaces along the rolling direction (RD) and the transverse direction (TD). Nanoindentation was executed using a Berkovich tip, with the main axis oriented either along TD or RD of the Cu(16)/Nb(16) ARB nanolaminate. Subsequently, height profiles were obtained along the main axis of the Berkovich indent for both TD and RD using scanning probe microscopy (SPM), which was later used to estimate the pile-up along the RD and TD. The RD exhibited more pile-up than the TD due to the anisotropy of the Cu(16)/Nb(16) ARB interface and the material plasticity along the TD and RD. An axisymmetric 2D finite element analysis (FEA) was also performed to compare/validate nanoindentation data, such as load vs. displacement curves and pile-up. The FEA simulated load vs. displacement curves matched relatively well with the experimentally generated load–displacement curves, while qualitative agreement was found between the simulated pile-up data and the experimentally obtained pile-up data. The authors believe that pile-up characterization during indentation is of great importance to documenting anisotropy in nanolaminates.

Lightweight photovoltaics (PV) modules are important for certain segments of the renewable energy markets—such as exhibition halls, factories, supermarkets, farms, etc. However, lightweight silicon-based PV modules have their own set of technical challenges or concerns. One of them, which is the subject of this paper, is the lack of impact resistance, especially against hailstorms in deep winter in countries with four seasons. Even if the front sheet can be made sufficiently strong and impact-resistant, the silicon cells inside remain fragile and very prone to impact loading. This leads to cracks that significantly degrade performance (output power) over time. A 3D helicoidally architected fiber-based polymer composite has recently been found to exhibit excellent impact resistance, inspired by the multi-hierarchical internal structures of the mantis shrimp’s dactyl clubs. In previous work, our group demonstrated that via electrospinning-based additive manufacturing methodologies, weak polymer material constituents could be made to exhibit significantly improved toughness and impact properties. In this study, we demonstrate the use of 3D architected fiber-based polymer composites to protect the silicon solar cells by absorbing impact energy. The absorbed energy is equivalent to the energy that would impact the solar cells during hailstorms. We have shown that silicon cells placed under such 3D architected polymer layers break at substantially higher impact load/energy (compared to those placed under standard PV encapsulation polymer material). This could lead to the development of novel PV encapsulant materials for the next generation of lightweight PV modules and technology with excellent impact resistance.