Reda Abdel-Hameed

Carbon steel readily corrodes in acidic environments, particularly in HCl, where corrosion severity depends on acid concentration, exposure time, and temperature.

As environmentally safe substitutes for traditional solvents and surfactants, ionic liquids (ILs) have drawn a lot of interest. Among these, IL-based cationic surfactants constitute an important class of multifunctional materials that integrate the unique physicochemical characteristics of ionic liquids with the interfacial activity of surfactants. Due to their dual functionality, they have demonstrated broad applicability as corrosion inhibitors, antimicrobial agents, emulsifiers, and dispersants across the petroleum, pharmaceutical, and environmental sectors. In this case, precursors obtained from natural waste were used to create ionic liquid-based Gemini cationic surfactants (ILGCS) (4a–d). The first of the four primary phases in the synthetic approach was the separation of mixed fatty acids from discarded coffee grounds and culminating in a quaternization reaction to afford the target ILGCS. FT-IR, ¹H and ¹³C NMR spectroscopy were used to completely describe compounds 4a–d. Their surface tension properties were systematically evaluated, and the ILGCS were further assessed for their efficiency as petro-collecting and petro-dispersing agents, in addition to their antimicrobial activity. The results showed that compound 4d recorded the highest surface activity, characterized by the lowest CMC, the largest surface pressure, and the lowest surface tension at micellization. This result suggests that 4d is a promising candidate for further applications that need strong surface activity, such as emulsification, detergency, or solubilization processes. The petro-collecting and dispersing properties of ILGCS (4a–d) were utilized on three different water sources that differ in salinity. All the synthesized gemini surfactants exhibited outstanding petroleum-dispersing efficiency in fresh and seawater. While in distilled water, the petroleum-collecting properties of the gemini surfactants were observed. Four ionic liquid-based Gemini surfactants (4a–d) were evaluated for antimicrobial activity after 24 h of exposure. Compound 4d (u = 6, m = 6) showed the highest inhibition zones against L. monocytogenes (17 mm) and S. aureus (16 mm), indicating strong activity against Gram-positive bacteria. Moderate inhibition was observed for Gram-negative strains E. coli (15 mm) and Salmonella sp. (14 mm), while Candida albicans showed lower susceptibility (13 mm).

In this work, a novel portable paper-based sensor is developed using a porphyrin-embedded molecularly imprinted polymer for caffeine quantification.

The discovery of novel ionic liquids incorporating a sulfonamide moiety has attracted significant attention owing to their unique bioactive properties and versatile applications. The present study focuses on the design, spectroscopic characterization, and evaluation of the petroleum-dispersing and insecticidal activities of seven newly synthesized compounds (4a–e, 5c, and 5e). The synthesized ionic liquid compounds were successfully characterized by spectroscopic methods. Their efficiency in dispersing or collecting thin films of petroleum was evaluated in various water systems. Notably, most of the compounds, especially 4d, demonstrated strong capabilities in removing petroleum films from water. Additionally, the larvicidal activity of the compounds was evaluated against Culex pipiens, one of the most hazardous mosquito vectors. Among them, compounds 4d, 4b, and 5e exhibited significant potency, with LC₅₀ values of 161.03, 207.82, and 229.72 ppm, respectively. These compounds were found to be more effective than 5c, showing 3.07-, 2.38-, and 2.15-fold higher activity. In conclusion, the synthesized compounds demonstrated a dual functionality: efficiently dispersing or collecting oil films from water while also exhibiting larvicidal activity against aquatic Culex pipiens larvae, with compound 4d showing the highest efficacy. Hence, these compounds hold promise for application in both water purification and mosquito control.

We conducted an experiment to test the effectiveness of a new gemini ionic liquid, labeled as N₁,N₁,N₃,N₃-tetramethyl-N₁,N₃-bis(4-nitrobenzyl) propane 1,3-diaminium chloride, in prohibiting carbon steel corrosion in a 1 M hydrochloric acid solution.