Huiting Bi

The optimal δ-MnO ₂ was selected from MnO ₂ polymorphs, and then rGO was incorporated via freeze-drying to fabricate a 3D conductive framework. The δ-MnO ₂ /rGO composite exhibited excellent cycling stability over 1600 cycles.

In-situ growth of bimetallic silicate onto ultrathin graphene, followed by reduction and phosphorization to obtain uniformly dispersed Fe_xNiP on graphene layers. rGO@Fe0.8NiP exhibits excellent OER activity and the overpotential (η₁₀) is 266 mV.

Carbon xerogels co-doped with nitrogen (N) and phosphorus (P) or sulfur (S) were synthesized and employed as catalysts for the electrocatalytic reduction of p-nitrophenol (p-NP). The materials were prepared by first synthesizing N-doped carbon xerogels (NDCX) via the pyrolysis of organic gels, and then introducing P or S atoms to the NDCX by a vapor deposition method. The materials were characterized by various measurements including X-ray diffraction, N₂ physisorption, Transmission electron microscopy, Fourier Infrared spectrometer, and X-ray photoelectron spectra, which showed that N atoms were successfully doped to the carbon xerogels, and the co-doping of P or S atoms affected the existing status of N atoms. Cyclic voltammetry (CV) scanning manifested that the N and P co-doped materials, i.e., P-NDCX-1.0, was the most suitable catalyst for the reaction, showing an overpotential of −0.569 V (vs. Ag/AgCl) and a peak slop of 695.90 μA/V. The material was also stable in the reaction and only a 14 mV shift in the reduction peak overpotential was observed after running for 100 cycles.

Although graphitic carbon nitride (g-C₃N₄) has been reported for several decades, it is still an active material at the present time owing to its amazing properties exhibited in many applications, including photocatalysis. With the rapid development of characterization techniques, in-depth exploration has been conducted to reveal and utilize the natural properties of g-C₃N₄ through modifications. Among these, the assembly of g-C₃N₄ with metal oxides is an effective strategy which can not only improve electron–hole separation efficiency by forming a polymer–inorganic heterojunction, but also compensate for the redox capabilities of g-C₃N₄ owing to the varied oxidation states of metal ions, enhancing its photocatalytic performance. Herein, we summarized the research progress on the synthesis of g-C₃N₄ and its coupling with single- or multiple-metal oxides, and its photocatalytic applications in energy production and environmental protection, including the splitting of water to hydrogen, the reduction of CO₂ to valuable fuels, the degradation of organic pollutants and the disinfection of bacteria. At the end, challenges and prospects in the synthesis and photocatalytic application of g-C₃N₄-based composites are proposed and an outlook is given.