Lei Quan

The insufficient optimization of calcination process parameters severely restricts the enhancement of rice husk ash (RHA) volcanic ash activity. In this study, an intelligent muffle furnace was used for multi-parameter coupled regulation, combined with microscopic characterization techniques, to elucidate the effects of temperature, cooling mode, heating rate, and holding time on the reactivity of RHA. The results showed that the effect of calcination temperature on the volcanic ash activity of RHA was dominant. RHA calcined at 600–700 °C showed a honeycomb porous structure, displayed broad amorphous SiO₂ diffraction peaks and up to 95% content of SiO₂, and exhibited the best volcanic ash activity. The increased crystallinity of RHA calcined at 800 °C led to a decrease in its activity. The subcooling treatment with distilled water effectively rebuilt the lamellar structure, reduced the crystallinity, and enhanced the reactivity. The samples incorporated with 600 °C calcined RHA showed higher compressive strength at 3 days compared to 800 °C calcined RHA.

Under the action of freeze–thaw cycles, the internal temperature and water distribution of slope soils in cold regions change significantly, which directly affects the stability of slopes. In order to study the differences in hydrothermal reactions at different depths and their impacts on the stability of slopes. This study establishes both a freeze–thaw model and a hydrothermal coupling model, combining field measurements with numerical simulations to examine the dynamic changes in hydrothermal characteristics within the slope. The results indicate that the variation in slope temperature with depth can be divided into three stages: initial freezing, stable freezing, and thawing. In the freezing stage, the negative temperature gradient drives water to migrate towards the freezing front, forming segregated ice and inducing frost heave. In the thawing stage, the latent heat released by the phase change in segregated ice promotes water to move towards the slope toe, increasing the water content there and indirectly exacerbating the risk of slope instability. The heat and moisture transfer in frozen soil slopes shows non-linear and dynamic characteristics. The unique process of one-way freezing and two-way thawing makes the thawing rate 1.35 times that of the freezing rate, and this asymmetric characteristic is the key to understanding the mechanism of slope instability.

Ultra-low humidity environments will lead to changes in the microstructure of C–S–H, which will reduce the mechanical properties and service life of cement-based concrete. Thus, to further explore the mechanism on the microscale, this paper studied the water migration and the changes in the hydration products in white cement that was cured for 7 days at 20 °C and at different ambient relative humidities (RHs). The migration and transformation of different types of water in cement paste were studied by low-field nuclear magnetic resonance (NMR). At the same time, Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) were used to analyze semi-quantitatively the crystal phase in the hydration products. The results showed that in the first 7 days of the curing process, the content of the different types of water and the hydration products in the cement samples were influenced by the ambient RH. The total water content of the samples will decrease with the decrease in the RH; when the RH decreases to 54% or below, the chemically bound water in the samples will increase with the decline in the RH. Additionally, when the ambient RH is lower than 54%, the grossular will gradually transform into hydrogrossular crystals with the decrease in the RH, and the hibschite with less chemically bound water will transform into katoite with more chemically bound water. In future research, the water migration and hydrate changes under different curing ages, drying processes, and coupling effects should be explored.