Juan Wu

A novel magnetic bio-adsorbent was synthesized by modifying cotton linter (CL) cellulose with deep eutectic solvents (DESs) and Fe₃O₄ magnetic nanoparticles. And the adsorption mechanism of Cu²⁺ by Fe₃O₄/CL-DESs in aqueous solution was proposed.

Cotton fiber is favored by people because of its good moisture absorption, heat preservation, soft feel, comfortable wearing and other excellent performance. In recent years, due to the destruction of the ozone layer, the intensity of ultraviolet radiation at ground level has increased. Cotton fiber will degrade under long time ultraviolet irradiation, which limits the outdoor application of cotton fiber. In this study, titanium dioxide (TiO₂) particles were prepared on the surface of cotton fibers with the help of supercritical carbon dioxide (SCCO₂) to improve the UV resistance of cotton fibers. The effects of SCCO₂ treatment on the morphology, surface composition, thermal stability, photostability and mechanical properties of TiO₂ were studied by Fourier transform infrared spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, thermogravimetric analysis, UV-VIS spectroscopy, and single fiber test. The results showed that TiO₂ particles were generated on the fiber surface, which reduced the photo-degradation rate of cotton fiber. This is because TiO₂ can absorb UV rays and reduce the absorption of UV rays by the cotton fiber itself. The synthesis process of SCCO₂ is simple and environmentally friendly, which provides a promising technology for the synthesis of metal nitrogen dioxide on natural plant fibers.