Hailong Wang

Natural pumice can reduce the self-weight of concrete, but its high porosity, high water absorption, and weak interfacial bonding tend to limit the strength and durability of lightweight aggregate concrete. To address this issue, this study proposes a method for preparing and applying reinforced pumice lightweight aggregates, namely, using nano-SiO₂-modified fly ash to construct a nanocomposite material at the micro-interface for the reinforcement treatment of natural pumice aggregates, and reveals the mechanism by which this treatment enhances the performance of lightweight aggregate concrete. Through aggregate performance tests, compressive strength tests, XRD, SEM, and freeze–thaw cycle tests, the effects of the reinforced pumice aggregate on the performance of lightweight concrete were systematically investigated. The results show that after the reinforcement treatment, the water absorption of the pumice aggregate decreases by 17.6%, and the cylinder compressive strength increases by 34.3%. As the replacement ratio of reinforced pumice increases, both the early-age and later-age compressive strengths of the concrete continuously improve. When all the pumice aggregate is reinforced, the 3 d and 28 d compressive strengths increase by 35.1% and 33.44%, respectively. Meanwhile, the reinforced pumice effectively improves the interfacial bonding between the aggregate and the cement paste, reducing the width of the interfacial transition zone by 32%, enhancing the matrix compactness, and delaying crack propagation. The study demonstrates that the reinforced pumice aggregate possesses favorable characteristics, not only effectively improving the mechanical properties and freeze–thaw resistance of lightweight concrete but also providing a new technical pathway for the high-performance utilization of porous lightweight aggregates, offering a reference for the resource utilization of industrial solid waste and engineering applications in cold regions.

To address frost heave in winter-lined canals and sediment accumulation in the Hetao Irrigation District of Inner Mongolia Autonomous Region, while reducing long-term maintenance costs of canal linings and relocating sediment as solid waste, this study proposes the use of low-toxicity, environmentally friendly octadecyltrichlorosilane (OTS) to modify channel sediment. This approach aims to improve the frost heave resistance of canal sediment and investigate optimal modification conditions and their impact on frost heave phenomena, aligning with sustainable development goals of low energy consumption and economic efficiency. Water Droplet Penetration Time (WDPT) tests and unidirectional freezing experiments were conducted to analyze frost heave magnitude, temperature distribution, and moisture variation in modified sediment. A coupled thermal–hydraulic–mechanical (THM) model established using COMSOL Multiphysics 6.2 software was employed for numerical simulations. Experimental results demonstrate that the hydrophobicity of channel sediment increases with higher OTS concentrations. The optimal modification effect is achieved at 50 °C with a silane-to-sediment mass ratio of 0.001, aligning with the economic efficiency of sustainable development. The unidirectional freezing test results indicate that compared to the 0% modified sediment content, the 40% modified sediment proportion reduces frost heave magnitude by 71.3% and decreases water accumulation at the freezing front by 21.1%. The comparison between numerical simulation results and experimental data demonstrates that the model can accurately simulate the frost heave behavior of modified sediment, with the error margin maintained within 15%. In conclusion, OTS-modified channel sediment demonstrates significant advantages in enhancing frost heave resistance while aligning with the economic and environmental sustainability requirements. Furthermore, the coupled thermal–hydraulic–mechanical (THM) model provides a reliable tool to guide sustainable infrastructure development for hydraulic engineering in the cold and arid regions of Inner Mongolia, effectively reducing long-term maintenance energy consumption.

Addressing the complex physicochemical properties of coal gangue from typical mining areas in Inner Mongolia, this study focuses on this area’s abundant reserves coupled with the low utilization rate and significant strength variability of ecological slope protection materials. Notably, research on the alkalization–carbonization of coal gangue remains scarce. To bridge this gap, we propose a method leveraging the moisture migration behavior of coal gangue porous media. By utilizing continuous displacement high-temperature steam carbon sequestration enhancement technology, internal moisture is gradually and precisely controlled to induce the formation of high-temperature carbonic acid gas. This process facilitates internal carbon sequestration and effectively locks in the sequestration effect. This approach enables effective loading of sulfurized CO₂ composite gases in a reversible manner, achieving passive carbon sequestration driven by moisture migration. Consequently, it enhances the negative carbon content within the aggregates while bolstering their mechanical properties. After alkalization pretreatment with various concentrations and three hours of carbon sequestration, the microhardness of the aggregate surface and transition zone were observed to have increased by 24.3% and 36.4%, respectively. Additionally, the compressive and splitting tensile strengths of coal gangue concrete rose by 4.8 MPa and 0.4 MPa, respectively, while porosity decreased by up to 3.6%, and the proportion of harmful pores dropped from 11.22% to 6.54%. A strong correlation between the proportion of harmless/low-harm pores and strength development was observed. Overall, the high-temperature carbonic acid steam displacement method with sulfurized CO₂ composite gases effectively improves the physicochemical properties of coal gangue aggregates and enhances surface activity and hydration in the interface transition zone, meeting the engineering standards for in situ ecological remediation in Inner Mongolia’s mining areas.

Gasification slag is the solid waste produced in the process of coal gasification. China produces approximately 30 million tons of gasification slag every year, which urgently needs to be recycled in an efficient and sustainable way. This paper discusses the feasibility of using gasification slag as a supplementary cementitious material (SCM). The working properties, mechanical properties, and microstructure of cement paste after the addition of gasification slag were studied and compared with those of pure cement paste. The results indicate that the hydration products of the composite paste contain a significant amount of Ca(OH)₂ and C-S-H gel when the content of gasification slag is less than 30%. However, when the gasification slag content exceeds 30%, the primary hydration product shifts to the C-A-S-H gel. Furthermore, the C-(A)-S-H gel tends to exhibit a lower calcium–silicon ratio and a higher degree of polymerization as the gasification slag content increases. Specifically, the Ca/Si ratio of the 60% C-A-S-H gel is 1.66, with a degree of polymerization of 0.77. When the gasification slag content is maintained at or below 30%, the compressive strength of the gasification slag cement paste decreases by approximately 3.7% to 9.3% compared with that of Portland cement (PC). Nevertheless, the composite cement meets the design requirements of 42.5 composite Portland cement. Thus, gasification slag has emerged as a promising supplementary cementitious material (SCM), with significant potential for widespread application.

Using coal-based solid waste (CSWM) to develop artificial soil (AS) can solve the shortage of planting soil in mine ecological restoration and realize the resource utilization of solid waste, which is a very promising research direction. This study used three common CSWM, coal gangue (CG), fly ash (FA), and desulfurization gypsum (DG), to prepare AS. The physicochemical properties of AS, such as bulk density, specific gravity, porosity, field water capacity, available nutrient content, pH value and EC value, were studied. Simultaneously, Elymus dahuricus was utilized in pot experiments to explore the planting performance of AS. Results show that, as the CG content decreased, the specific gravity of AS decreased, and the porosity increased. Both field capacity and saturation capacity demonstrated a notable upward trend. The results of pot experiments showed that plant growth was best when the CG content in AS was 80% and the FA and DG content was 20%. In comparison to the control group consisting of pure CG, the plant biomass in the optimal experimental group exhibited a significant increase of 20.48%. This study verified the feasibility of making AS by combining various CSWM, and provides a new pathway for ecological restoration and resource utilization in mines.

In order to improve the mechanical properties and durability of lightweight aggregate concrete in extreme environments, this study utilized Inner Mongolia pumice as the coarse aggregate to formulate pumice lightweight aggregate concrete (P-LWAC) with a silica powder content of 0%, 2%, 4%, 6%, 8%, and 10%. Under sulfate dry–wet cycling conditions, this study mainly conducted a mass loss rate test, compressive strength test, NMR test, and SEM test to investigate the improvement effect of silica powder content on the corrosion resistance performance of P-LWAC. In addition, using grey prediction theory, the relationship between pore characteristic parameters and compressive strength was elucidated, and a grey prediction model GM (1,3) was established to predict the compressive strength of P-LWAC after cycling. Research indicates that under sulfate corrosion conditions, as the cycle times and silica powder content increased, the corrosion resistance of P-LWAC showed a trend of first increasing and then decreasing. At 60 cycles, P-LWAC with a content of 6% exhibited the lowest mass loss rate and the highest relative dynamic elastic modulus, compressive strength, and corrosion resistance coefficient. From the perspective of data distribution, various durability indicators showed a clear mirror symmetry towards both sides with a silica powder content of 6% as the symmetrical center. The addition of silica fume reduced the porosity and permeability of P-LWAC, enhanced the saturation degree of bound fluid, and facilitated internal structural development from harmful pores towards less harmful and harmless pores, a feature most prominent at the 6% silica fume mixing ratio. In addition, a bound fluid saturation and pore size of 0.02~0.05 μm/% exerted the most significant influence on the compressive strength of P-LWAC subjected to 90 dry–wet cycles. Based on these two factors, grey prediction model GM (1,3) was established. This model can accurately evaluate the durability of P-LWAC, improving the efficiency of curing decision-making and construction of concrete materials.

To improve the durability of pumice lightweight aggregate concrete applied in cold and drought areas, sodium silicate-modified waste tire rubber powder is used to treat the pumice lightweight aggregate concrete. The pumice lightweight aggregate concrete studied is mainly used in river lining structures. It will be eroded by water flow and the impact of ice and other injuries, resulting in reduced durability, and the addition of modified rubber will reduce the damage. The durability, including mass loss rate and relative dynamic elastic modulus of pumice lightweight aggregate concrete with different sodium silicate dosages and rubber power particle sizes, is analyzed under freeze-thaw cycles, and the microstructure is further characterized by using microscopic test methods such as nuclear magnetic resonance tests, ultra-depth 3D microscope tests, and scanning electron microscopy tests. The results showed that the durability of pumice lightweight aggregate concrete is significantly improved by the addition of modified waste tire rubber powder, and the optimum durability is achieved when using 2 wt% sodium silicate modified rubber power with a particle size of 20, and then the mass loss rate decreased from 4.54% to 0.77% and the relative dynamic elastic modulus increased from 50.34% to 64.87% after 300 freeze-thaw cycles compared with other samples. The scanning electron microscopy test result showed that the surface of rubber power is cleaner after the modification of sodium silicate, so the bonding ability between rubber power and cement hydration products is improved, which further improved the durability of concrete under the freeze-thaw cycle. The results of the nuclear magnetic resonance test showed that the pore area increased with the number of freeze-thaw cycles, and the small pores gradually evolved into large pores. The effect of sodium silicate on the modification of rubber power with different particle sizes is different. After the treatment of 2 wt% sodium silicate, the relationship between the increased rate of pore area and the number of freezing-thawing cycles is 23.8/times for the pumice lightweight aggregate concrete containing rubber power with a particle size of 20 and 35.3/times for the pumice lightweight aggregate concrete containing a particle size of 80 rubber power, respectively.

To tackle carbon emissions from cement production and address the decline in concrete’s mechanical properties due to the substitution of cement with solid waste (glass powder) and natural mineral admixture (zeolite powder) materials, we employed glass powder and zeolite powder to create composite cementitious materials. These materials underwent alkali activation treatment with a 4% NaOH dosage, replacing 50% of cement to produce low-carbon concrete. Nanoindentation tests and mercury intrusion porosimetry (MIP) were employed to uncover the micro-mechanical properties and influencing mechanisms of alkali-activated low-carbon concrete. The results indicate a notable enhancement in the indentation modulus (19.9%) and hardness (25.9%) of alkali-activated low-carbon concrete compared to non-activated concrete. Simultaneously, the interfacial transition zone thickness decreased by 10 µm. The addition of NaOH led to a reduced volume fraction of pores (diameter >100 nm) and an increased fraction of pores (diameter < 100 nm), thereby reducing porosity by 2.6%, optimizing the pore structure of low-carbon concrete. The indentation modulus, hardness and volume fraction of the hydrated phase derived from Gaussian fitting analysis of the nanoindentation statistics showed that NaOH significantly improved the modulus and hardness of the hydration products of low-carbon concrete. This activation resulted in decreased LDC-S-H gel (low-density hydrated calcium silicate Ca₅Si₆O₁₆(OH)·4H₂O) and pore content, while the HD C-S-H gel (high-density hydrated calcium silicate Ca₅Si₆O₁₆(OH)·4H₂O) and CH (calcium hydroxide crystals Ca(OH)₂) content increased by 13.91% and 23.46%, respectively. Consequently, NaOH influenced the micro-mechanical properties of low-carbon concrete by generating more high-density hydration products, reducing pore content, enhancing the pore indentation modulus and hardness, and shortening the interfacial transition zone. This study offers novel insights into reducing carbon emissions and promoting the use of solid waste (glass powder) and natural mineral admixture (zeolite powder) materials in concrete, contributing to the advancement of sustainable construction practices.

The world is facing the problem of depletion of natural sand and gravel resources, and a large amount of coal gangue solid waste is produced in Inner Mongolia, China, which has low utilization rate and causes ecological pollution. In order to improve the gangue in the mining infrastructure construction of a wide range of application prospects, the use of coal gangue as the coarse aggregate of pumice concrete is of great significance. Inner Mongolia is a cold region, and gangue mixed aggregate concrete (MFC) will certainly face the damage caused by freeze–thaw cycles. Therefore, design gangue by different volume replacement rate (0%, 20%, 40%, 60%, 80%, 100%) to replace pumice coarse aggregate. The results show that with the increase of gangue substitution rate, the mass loss rate, relative dynamic elastic modulus, and peak stress of MFC decrease, but the trend of peak strain increases. It is mainly attributed to the less Al₂O₃ and SiO₂ content of gangue, which makes the MFC hydration products decrease with the increase of substitution rate and more original microcracks and pores in the specimens. In addition, the damage model of MFC was established by using Weibull statistical distribution theory and the principle of LEMAITRE equivalent effect variation assumption, and the damage evolution characteristics were explored by combining the experimental results. It can provide the theoretical basis for the application of MFC in cold regions.

This paper used natural pumice from the Inner Mongolia region as coarse aggregate to produce a lightweight concrete mix with a 3% rubber particle (20 mesh) content and dissimilar slag contents (0%, 5%, 10%, 15%, 20%, 25%, and 30%). It measured the compressive strength in five periods (3, 7, 14, 21, and 28 d). It also observed the development of the microstructure and measured the air content and pore distribution of the concrete using environmental scanning electron microscopy and nuclear magnetic resonance. A microtest combined with macroscopic mechanical experiments were used to analyze the influence on the mechanical properties of the rubber lightweight aggregate by the content of the S95 slag. The results showed that slag can improve the microstructure of rubber lightweight aggregate concrete. It hydrated the products, optimized the porous structure, and enhanced the compressive strength of the rubber lightweight aggregate concrete at 28 days, with excellent results regarding the air entraining. The best compressive strength of the rubber powder lightweight aggregate concrete at 28 days was when the content of the slag was 15%. An Atzeni pore-structure–strength model was introduced that contained a cement mass fraction. The results of the fitting indicate that the pore structure located at 0.1~1 μm had a marked influence on the mechanical properties of the rubber powder concrete.