Sara Piedrahita-Rodríguez

Coastal regions concentrate livestock and fisheries activities that generate large volumes of organic residues, often managed inadequately and contributing to nutrient loading, soil degradation, and marine pollution. At the same time, these territories face increasing pressure to decarbonise energy systems and restore degraded soils under climate change. This article proposes an integrated conceptual framework for the valorisation of livestock and fisheries residues through hydrogen-centred energy recovery and biochar-based soil regeneration, with a focus on coastal regions of Colombia. The framework integrates biological and thermochemical conversion pathways, including anaerobic digestion, fermentation, gasification, and pyrolysis, within a unified system boundary that treats organic residues as secondary resources rather than environmental liabilities. Hydrogen is a transitional energy carrier enabling near-term decarbonisation within decentralised residue valorisation systems, while biochar is positioned as a key co-product enabling long-term carbon stabilisation and soil regeneration. By linking material and energy flows at the territorial scale and accounting for governance constraints and environmental vulnerabilities, the framework highlights the potential of decentralised residue valorisation systems. These systems can reduce coastal pollution, enhance soil resilience, and contribute to climate mitigation in fragile ecosystems.

Coastal regions concentrate livestock and fisheries activities that generate large volumes of organic residues, often managed inadequately and contributing to nutrient loading, soil degradation, and marine pollution. At the same time, these territories face increasing pressure to decarbonise energy systems and restore degraded soils under climate change. This article proposes a process-oriented conceptual framework for the integrated valorisation of livestock and fisheries residues through hydrogen-centred energy recovery and biochar-based soil regeneration, with a focus on coastal regions of Colombia. The framework integrates biological and thermochemical conversion pathways, including anaerobic digestion, fermentation, gasification, and pyrolysis, within a unified system boundary that treats organic residues as secondary resources rather than environmental burdens. Hydrogen is conceptualised as a short-term energy carrier, while biochar is positioned as a key co-product enabling long-term carbon stabilisation and soil regeneration. By explicitly integrating material and energy flows, territorial scale considerations, and governance dimensions, the proposed framework provides a process-level basis for designing decentralised residue-to-energy and soil-regeneration systems capable of delivering simultaneous benefits in renewable energy supply, waste management, soil restoration, and climate mitigation in environmentally vulnerable coastal regions.

Microplastic quantification in marine vegetated ecosystems remains analytically demanding, yet little is known about the environmental footprint of the laboratory procedures required to isolate and measure these particles. This study applies Life Cycle Assessment (LCA) to laboratory analytical workflows for microplastics quantification, focusing exclusively on sample preparation and analytical procedures rather than natural environmental absorption or fate processes, in two ecologically relevant matrices: (i) pelagic algae (Sargassum) and (ii) seagrass biomass. Using the openLCA 2.5 and the ReCiPe Midpoint (H) v1.13 methods, the analysis integrates foreground inventories of digestion, filtration, drying, and spectroscopic identification, combined with background datasets from OzLCI2019, ELCD 3.2 and USDA. Results show substantially higher impacts for the algae scenario, particularly for climate change, human toxicity, ionising radiation and particulate matter formation, largely driven by longer digestion times, increased reagent use and higher energy demand during sample pre-treatment. Conversely, the seagrass scenario exhibited lower burdens per functional unit due to reduced organic complexity and shorter laboratory processing requirements. These findings highlight the importance of matrix-specific methodological choices and the influence of background datasets on impact profiles. This study provides the first benchmark for the environmental performance of microplastic analytical workflows and underscores the need for harmonised, low-impact laboratory protocols to support sustainable monitoring of microplastic pollution in marine ecosystems.

Microplastic quantification in marine vegetated ecosystems remains analytically demanding, yet little is known about the environmental footprint of the laboratory procedures required to isolate and measure these particles. This study applies Life Cycle Assessment (LCA) to laboratory analytical workflows for microplastics quantification, focusing exclusively on sample preparation and analytical procedures rather than natural environmental absorption or fate processes, in two ecologically relevant matrices: (i) pelagic algae (Sargassum) and (ii) seagrass biomass. Using openLCA 2.5 and the ReCiPe Midpoint (H) v1.13 method, the analysis integrates foreground inventories of digestion, filtration, drying, and spectroscopic identification, combined with background datasets from OzLCI2019, ELCD 3.2 and USDA. Results show substantially higher impacts for the algae scenario, particularly in climate change, human toxicity, ionising radiation and particulate matter formation, largely driven by longer digestion times, increased reagent use and higher energy demand during sample pre-treatment. Conversely, the seagrass scenario exhibited lower burdens per functional unit due to reduced organic complexity and shorter laboratory processing requirements. These findings highlight the importance of matrix-specific methodological choices and the influence of background datasets on impact profiles. The study provides a first benchmark for the environmental performance of microplastic analytical workflows and underscores the need for harmonised, low-impact laboratory protocols to support sustainable monitoring of microplastic pollution in marine ecosystems.

Coastal ecosystems represent a complex and dynamic interface for renewable energy development, combining solar radiation, coastal winds, and marine biomass. In regions such as La Guajira (Colombia), these resources create a unique opportunity to design hybrid systems that integrate solar, wind, and bio-based energy generation. This study applied a multicriteria assessment encompassing technical, economic, environmental, and social dimensions to evaluate the feasibility of this integration. The study adopts a narrative review approach supported by peer-reviewed literature, satellite-derived environmental datasets, and regional technical reports. Three criteria were used to assess the potential of these bioresources: (i) availability and spatiotemporal variability, (ii) physicochemical and energetic characteristics, and (iii) suitability for thermochemical and biochemical valorisation routes. Reported data indicate that pelagic Sargassum reaching the wider Caribbean contains 20–30% ash, 25–35% carbohydrates, and lower heating values between 8 and 12 MJ kg⁻¹, while cactus biomass in arid environments can reach LHV of 13–16 MJ kg⁻¹ and moisture contents below 15%. The coastal region of La Guajira also receives solar irradiation levels exceeding 6 kWh m⁻² day⁻¹ and wind speeds above 8 m s⁻¹, creating favourable conditions for hybrid bioenergy–renewable systems. Finally, the multicriteria analysis reveals that integrating coastal renewable resources could drive the transition towards a circular, inclusive, and low-carbon bioeconomy in coastal territories such as La Guajira.

Cocoa is a key tropical crop with profound environmental, social, and economic implications throughout its value chain. Life Cycle Assessment (LCA) has been widely employed to assess these impacts; however, most applications remain fragmented and focus primarily on environmental dimensions. This review addresses the issue related to which phases of the cocoa life cycle generate the most significant environmental impacts and how LCA methodological choices, such as the definition of system boundaries, functional units, and data sources, influence the integration of socioeconomic dimensions. A systematic literature review of 33 LCA studies published between 2008 and 2025 was conducted. The dominant categories, impact indicators, and boundary conditions were identified by applying the PRISMA methodology and cluster analysis. Results show that cultivation involves high water consumption, especially in conventional monocultures, while processing is the most energy-intensive due to machinery and transport demands. Most studies adopt cradle-to-gate system boundaries and rely heavily on secondary databases, that is, pre-existing datasets from LCA repositories like Ecoinvent or GaBi, which provide generic or averaged inventory data rather than specific measurements for each case, such as those obtained in the field of study. Overall, LCA helps identify environmental hotspots and guide decisions, but is limited by data gaps and poor integration of social and economic factors. Advancing toward comprehensive assessments requires region-specific datasets, sensitivity analyses, and hybrid frameworks, including UNEP/SETAC Social LCA guidelines, to fully integrate environmental, social, and economic dimensions of cocoa value chains.

Coastal ecosystems represent a complex and dynamic interface for renewable energy development, combining solar radiation, coastal winds, and marine biomass. In regions such as La Guajira (Colombia), these resources create a unique opportunity to design hybrid systems that integrate solar, wind, and bio-based energy generation. This study applied a multicriteria assessment encompassing technical, economic, environmental, and social dimensions to evaluate the feasibility of this integration. The results indicate that La Guajira’s coastal zone can be considered a “natural energy laboratory” due to its exceptional solar and wind conditions and its abundance of marine biomass such as sargassum, seaweed, and fishing waste. While the technical potential of these resources is high, particularly for hybrid solar–wind systems and bioenergy production, economic challenges persist, mainly related to biomass collection, pre-treatment, and drying. Environmentally, the valorisation of problematic macroalgae such as sargassum contributes to waste reduction and ecosystem restoration. Socially, the development of coastal bioeconomy initiatives can generate employment and foster community engagement in sustainable practices. Overall, the multicriteria analysis reveals that integrating coastal renewable resources could drive the transition towards a circular, inclusive, and low-carbon bioeconomy in coastal territories such as La Guajira.

Panela is the second most important rural agro-industry after coffee in Colombia. This agro-industry produces a large amount of bagasse from non-centrifugal sugar (B-NCSP) without valorization. B-NCSP is used in combustion boilers in panela production, causing greenhouse gas emissions and health problems. This research aims to compare the sustainability of two B-NCSP biorefineries considering the current residue use. The sustainability of the biorefinery scenarios was analyzed to promote rural economic development in Colombia. In both biorefinery scenarios, biogas was evaluated as an energy vector to meet the energy demand of panela production. Two biorefinery scenarios were considered: (i) saccharification, bioethanol, and biogas production and (ii) acid pretreatment, saccharification, xylitol, bioethanol, and biogas production. Experimental data of the pretreatment, saccharification, and anaerobic digestion stages were used as input information in simulations. Technical, economic, environmental, and social metrics were used to estimate a sustainability index. The experimental glucose yield in scenario 2 was 0.42 ± 0.03 (31.52 ± 2.36 g/L) g/g B-NCSP, 1.8 times greater than scenario 1. The biogas yield in scenario 2 was 504.23 ± 21.68 (71.16% CH4) L/kg B-NCSP, 3.3 times greater than scenario 1. Scenario 1 was unfeasible at different scales. Xylitol production helps to improve the economic feasibility in scenario 2 since the payback period was 15 years. This scenario can create 36 job positions with a wage 18% higher than the minimum wage in Colombia (highest sustainability index of 72.44%). Finally, biogas produced in scenario 2 supplies 62.76% of the energy demand needed in the panela production process, reducing the environmental impact.

Lignocellulosic materials are usually processed toward C5 and C6 corresponding sugars. Trifluoroacetic acid (TFA) is a pretreatment method to solubilize hemicellulose to sugars such xylose without degrading cellulose. However, this pretreatment has not been compared to other processes. Thus, this paper focuses on the techno-economic comparison of the C5–C6 production of C5–C6 as raw materials platforms using non-centrifuged sugarcane bagasse (NCSB) and Pinus patula wood chips (PP). Hydrolysates using TFA 2.5 M as an acid were characterized through HPLC regarding arabinose, galactose glucose, xylose, and mannose sugars. Then, simulations of the processes according to the experimental results were done. The economic assessment was performed, and compared with some common pretreatments. The mass and energy balances of the simulations indicate that the process can be compared with other pretreatments. From the economic perspective, the main operating expenditures (OpEx) are related to raw materials and capital depreciation due to the cost of TFA corrosion issues. The processes showed a CapEx and OpEx of 0.99 MUSD and 6.59 M-USD/year for NCSB, and 0.97 MUSD and 4.37 MUSD/year for PP, considering a small-scale base (1 ton/h). TFA pretreatment is innovative and promising from a techno-economic perspective.