Kai Wang
Current Organizations / Institutes
The organizations/institutes from the scholar's latest article
Research Subjects
Kai Wang has a total of 5 co-authors. Here are the top co-authors by number of shared publications:
Quanchun Sun
College of Chemistry and Bioengineering (Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials), Guilin University of Technology, No. 12, Jian gan RD, Guilin, Guangxi, 541004, P. R. China
1 shared publicationShaomei Zhang
College of Chemistry and Bioengineering (Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials), Guilin University of Technology, No. 12, Jian gan RD, Guilin, Guangxi, 541004, P. R. China
1 shared publication- Shu-Hua Zhang
Key Laboratory of New Processing Technology for Nonferrous Metal & Materials, Ministry of Education/Guangxi Key Laboratory of Optical and Electronic Materials and Devices, College of Materials Science and Engineering
1 shared publication - Yu Xiao
Guilin University of Technology
1 shared publication Zhonghang Chen
College of Chemistry and Bioengineering (Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials), Guilin University of Technology, No. 12, Jian gan RD, Guilin, Guangxi, 541004, P. R. China
1 shared publication
Latest Publications
- 7 February 2019
- Published by Wiley in Chempluschem
- Vol. 84 (2) , 190-202
Cadmium‐Based Coordination Polymers from 1D to 3D: Synthesis, Structures, and Photoluminescent and Electrochemiluminescent Properties
Cadmium‐based coordination polymers, namely, {[Cd(HL)(L)] ⋅ HN(Et)3}n (1), [Cd2(L)2(H2O)5]n (2), [Cd(L)(phen)]n (3), [Cd(L)(2,2′‐bpy)]n (4), [Cd(L)(4,4′‐bpy)]n (5), [Cd(L)(bpp)]n (6), [Cd(L)(dpa)]n (7), {[Cd(L)(dpa)] ⋅ H2O}n (8) (H2L=4,4′‐((p‐tolylazanediyl)bis(methylene))dibenzoic acid, phen=1,10‐phenanthroline, 2,2′‐bpy=2,2′‐bipyridine, 4,4′‐bpy=4,4′‐bipyridine, bpp=1,3‐bis(4‐pyridyl)propane, dpa=bis(4‐pyridyl)amine) have been synthesized in hydro/solvothermal reactions. 1 is a 4‐connect 3D network with an eightfold interpenetrating diamond topology. The 1D ladder chain structure of 2 was composed of the dinuclear [Cd2(CO2)4] subunit bridged with two L2− ligands. 3 shows a 1D double‐chain with a channel formed by edging out the coordination water with the rigid co‐ligand phen. Polymer 4 displays a 2D lamellar structure based on superseding the coordination water molecules by the rigid chelating auxiliary ligands 2,2′‐bpy. By substituting the small molecules with a rigid bridging ligand 4,4′‐bpy, a 2D undulating structure of 5 was built. Compounds 6 and 7 exhibit a 2D layer structure with a 4‐connect (44 ⋅ 62) sql‐net. Compound 8 presents a 3D architecture with a sixfold interpenetrating diamond topology. Through our construction strategy, versatile structures from 1D–3D have been rationally designed by controlling the process condition and rigid/flexible of N‐donor spacers. Additionally, the photoluminescence, charge transfer, and electrochemical luminescence (ECL) properties of 1–8 have been demonstrated.
- 7 February 2019
- Published by Wiley in Chempluschem
- Vol. 84 (2) , 190-202
Cadmium‐Based Coordination Polymers from 1D to 3D: Synthesis, Structures, and Photoluminescent and Electrochemiluminescent Properties
Cadmium‐based coordination polymers, namely, {[Cd(HL)(L)] ⋅ HN(Et)3}n (1), [Cd2(L)2(H2O)5]n (2), [Cd(L)(phen)]n (3), [Cd(L)(2,2′‐bpy)]n (4), [Cd(L)(4,4′‐bpy)]n (5), [Cd(L)(bpp)]n (6), [Cd(L)(dpa)]n (7), {[Cd(L)(dpa)] ⋅ H2O}n (8) (H2L=4,4′‐((p‐tolylazanediyl)bis(methylene))dibenzoic acid, phen=1,10‐phenanthroline, 2,2′‐bpy=2,2′‐bipyridine, 4,4′‐bpy=4,4′‐bipyridine, bpp=1,3‐bis(4‐pyridyl)propane, dpa=bis(4‐pyridyl)amine) have been synthesized in hydro/solvothermal reactions. 1 is a 4‐connect 3D network with an eightfold interpenetrating diamond topology. The 1D ladder chain structure of 2 was composed of the dinuclear [Cd2(CO2)4] subunit bridged with two L2− ligands. 3 shows a 1D double‐chain with a channel formed by edging out the coordination water with the rigid co‐ligand phen. Polymer 4 displays a 2D lamellar structure based on superseding the coordination water molecules by the rigid chelating auxiliary ligands 2,2′‐bpy. By substituting the small molecules with a rigid bridging ligand 4,4′‐bpy, a 2D undulating structure of 5 was built. Compounds 6 and 7 exhibit a 2D layer structure with a 4‐connect (44 ⋅ 62) sql‐net. Compound 8 presents a 3D architecture with a sixfold interpenetrating diamond topology. Through our construction strategy, versatile structures from 1D–3D have been rationally designed by controlling the process condition and rigid/flexible of N‐donor spacers. Additionally, the photoluminescence, charge transfer, and electrochemical luminescence (ECL) properties of 1–8 have been demonstrated.