Tayyaba Jamil

The study aims to investigate the effectiveness of photocatalyst (Clay/UV/TiO₂/ZnO) for antibiotic removal from real pharmaceutical wastewater by Combined ultraviolet (UV), Catalytic Ozonation-Electroflucculation process. The experiments were performed in a modified hybrid batch reactor with UV-C lamp. The effect of four operational variables such as the applied voltage of (5-15 V), ozone dose of (0.2- 0.8 mg/min), pH (5-10), and catalyst dose (0.5- 1.5 g/L) on turbidity and Chemical oxygen demand (COD) removal was investigated. Removal efficiencies of antibiotics (carbamazepine and amoxicillin) were evaluated and compared with ozonation (O₃), photocatalytic Ozonation (UV/O₃), Electroflucculation (EF)/UV, catalytic ozonation/UV, and Hybrid O₃/catalytic ozonation/UV/EF. The results showed that the modified hybrid process with UV irradiations provided the highest removal efficiency of 86.9% for COD, and turbidity of 81.66% under optimized conditions of (DC volts of 10 V; catalyst dose of 1 g/L, and ozone dose of 0.6 mg/min). The pharmaceuticals removal obtained for amoxicillin was 100% and 95% for carbamazepine. The detailed mechanism was also explored for better understanding of each process. The combined process was effective for treating pharmaceutical wastewater. Therefore, it was suggested that the novel photocatalyst and hybrid system can be used for treating real effluents in large scale and to meet (United nations) UN sustainability goals.

Due to the rapid growth of industries, and population the water shortage has become a global problem. The most hazardous organic contaminants found in text

The objective of this project was to develop a new hybrid nanocomposite that would maximize chemical oxygen demand (COD) and color removal from effluent from the actual textile industry to overcome the water crisis brought on by increasing industrialization and urbanization. This study is the first to use modified clay/TiO2/ZnO nanocomposites for adsorbing actual textile wastewater treatment. The adsorption capacity from the dye removal was evaluated to optimize the three engineering parameters (pH, adsorbent dose, and time) utilizing response surface methodology. An isotherm kinetic intra-particle diffusion model was developed to study the sorption phenomena. The best fit for sorption was provided by Langmuir isotherms, with an R2 of better than 0.99. The sorption process follows the pseudo-second-order kinetics that favors chemisorption, following kinetic theory. The sorption process is endothermic, viable, and spontaneous in nature, according to a thermodynamic study. At the optimal pH (5.5), adsorbent dose (0.55 g), and time (75 min), the maximum COD and color removal were achieved to be 94 and 91% with a maximum sorption capacity of 660 mg/g. In this optimization, the adj. R2 and R2 correlation coefficients were calculated as 0.7213 and 0.7653, respectively. The hybrid composite seems to be effective for treating real effluents.

This study aims to investigate the treatment of real textile wastewater using a novel bentonite clay/TiO₂/ZnO-based ozonation catalyst. In this study, synergic electroflocculation/catalytic ozonation, catalytic ozonation, and ozonation processes are applied in a modified hybrid reactor. To the authors’ knowledge, this is the first application of bentonite clay/TiO₂/ZnO as an ozonation catalyst for treating real textile wastewater. The four operational variables—ozone dose (0.2–0.8 mg/min), reaction time (0–120 min), DC voltage supply (5–15 V), and catalyst dose (0.5–2 g/L)—were studied for decolorization and for the removal of chemical oxygen demand (COD). The results showed that the combined process (electroflocculation + clay/TiO₂/ZnO/O₃) had the highest removal efficiencies for COD and color (97.86% and 97.90%, respectively) at optimum parameters of 10 DC volts. an ozone dose of 0.8 mg/min, and a catalyst dose of 2 g/L in textile wastewater. The results further revealed that the initial pH of wastewater plays an essential role in the process’s overall performance. The studied synergic process was efficient for real wastewater treatment under alkaline pH (6–9). Based on empirical work, we established that the synergic process is suitable for effectively treating textile wastewater.

Dyes are the most carcinogenic organic compounds that are discarded by most of the textile industries without any prior treatment, which is harmful for the environment. This study aims to develop a bentonite-clay/carbon-nanotube (CNT)-based adsorbent to treat textile wastewater for water sustainability. The preliminary and post-characterization of adsorbent involves scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and Brunauer–Emmett–Teller (BET) and energy-dispersive X-ray (EDX) analysis to determine the changes in surface morphology, functional group, and surface area of the adsorbent. Linear and nonlinear isotherms and kinetic studies were performed to explore the sorption mechanism. The results show that the nonlinear form of the Langmuir isotherm best fits adsorption with a qmax of 550 mg/g. The adsorption followed the nonlinear pseudo-first-order kinetics, favoring chemisorption with R² ≈ 1 and X₂ = 0.22. Maximum dye removal (89.9%) was achieved under the optimum conditions of pH 3, an adsorbent dose of 100 mg, and a contact time of 120 min, with an initial COD concentration of 1140 mgL⁻¹. This study has demonstrated the successful application of a bentonite-clay/CNT-based adsorbent on textile wastewater treatment.