Qingfen Kong

Interactive depositional systems of marine carbonates and gypsum salt rocks are closely related to natural gas reservoirs. Despite continuous progress in the exploration of new areas of marine carbonate genesis within the Ordos Basin, the source and mechanism of “sub-salt” natural gas genesis remains controversial. In this study, we investigated natural gas genesis through geochemical analysis of Lower Paleozoic natural gas samples from the mid-eastern Ordos Basin, obtaining natural gas composition data and carbon/hydrogen isotope compositions. We found evident differences between the geochemical characteristics of “sub-salt” and “post-salt” natural gas; the methane carbon isotope signature of “sub-salt” natural gas was lighter overall than that of “post-salt” natural gas, while the ethane carbon isotope composition of the former was more widely distributed and partially lighter than that of the latter. Combining these data with the regional geological background and existing geochemical data, it is evident that Ordovician “post-salt” natural gas comprises a composite of Upper Paleozoic coal-type gas and Lower Paleozoic oil-type gas, with the oil-type gas accounting for the largest proportion. In contrast, the “sub-salt” natural gas was formed and preserved within the Ordovician marine carbonates or sourced from deeper and more ancient hydrocarbon source rocks. Geochemical anomalies, including light methane carbon isotopes and ethane carbon isotopes with coal-type gas characteristics, are closely related to the prevalence of thermochemical sulfate reduction during hydrocarbon formation and reservoir formation of natural gas in “sub-salt” strata.

The Upper Paleozoic gases from the Longdong areas in the Ordos Basin are characterized by low contents of heavy hydrocarbon gases, the mean value of wetness as 2%, relatively heavy δ¹³C₁(δ¹³C₁ value -28.3‰), and large variations in δ¹³C₂ ⁺. The distribution pattern of carbon isotopic sequence of natural gas is mainly characterized by the abnormal light δ¹³C₂ ⁺ values and carbon isotopic reversal. According to the organic geochemical characteristics of natural gas and the development of gas-source rocks, the upper Paleozoic natural gas in Longdong area belongs to high mature and over-mature “coal-formed gas”. In theory, only the mixture of highly mature gas with extremely low contents of heavy hydrocarbon gases and a small amount of natural gas with higher contents and lighter carbon isotopic composition of heavy hydrocarbon gases can lead to the occurrence of abnormally light δ¹³C₂ ⁺ and the carbon isotope reversal between methane and ethane. The mixed gas is probably derived from the thermal cracking of a small amount of residual soluble organic matter in the gas-source rocks and reservoirs during the initial stage of the uplift movement at the end of Early Cretaceous. Key words: Ethane carbon isotope; Inverted sequence of carbon isotopic composition; Natural gas of high maturity; natural gas genesis; Ordos Basin.