Zhaokang Zheng

Molybdenum trioxide (MoO₃) is an attractive semiconductor. Thus, bandgap engineering toward photoelectronic applications is appealing yet not well studied. Here, we report the incorporation of sulfur atoms into MoO₃, using sulfur powder as a source of sulfur, via a self-developed hydrothermal synthesis approach. The formation of Mo-S bonds in the MoO₃ material with the synergistic effect of sulfur doping and oxygen vacancies (designated as S-MoO_3−x) is confirmed using Fourier-transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and electron paramagnetic resonance (EPR). The bandgap is tuned from 2.68 eV to 2.57 eV upon sulfur doping, as confirmed by UV-VIS DRS spectra. Some MoS₂ phase is identified with sulfur doping by referring to the photoluminescence (PL) spectra and electrochemical impedance spectroscopy (EIS), allowing significantly improved charge carrier separation and electron transfer efficiency. Therefore, the as-prepared S-MoO_3−x delivers a sensitive photocurrent response and splendid cycling stability. This study on the synergistic effect of sulfur doping and oxygen vacancies provides key insights into the impact of doping strategies on MoO₃ performance, paving new pathways for its optimization and development in relevant fields.

Due to the depletion of the global ozone layer and the presence of ozone holes, humans are increasingly exposed to threats from solar ultraviolet radiation. Therefore, researching and developing a highly selective, sensitive, simple, and fast ultraviolet sensor is of significant importance for personal protection. In recent years, new nanomaterials have shown good application prospects in the research of ultraviolet sensors. MoOx nanostructures were prepared by a hydrothermal method. The experimental results show that, compared to traditional photochromic compounds, the new MoOx nanostructures exhibit high uniqueness, high selectivity, and excellent stability, and can perform rapid and accurate detection under full-band light. The beam sensor can not only detect through traditional electrical signal output, but also amplify, display, and analyze the beam through visualization and visual analysis, further improving the reliability and practicality of its application.