Libing Qian

Clay nanosheets relocate grafting sites to preserve MOF pores in type I porous liquids, enabling selective CO ₂ uptake over N ₂ for efficient gas separation.

Photothermal catalytic methanol (CH ₃ OH) dehydrogenation is a sustainable pathway for the co-production of hydrogen (H ₂ ) and formaldehyde (HCHO) under mild reaction conditions.

Polymer membrane modification via electron beam irradiation has emerged as a powerful technique for tailoring filtration and separation performance. However, the fundamental role of environmental conditions during irradiation, particularly hydration state, remains poorly understood despite its potential to dramatically alter energy deposition pathways and subsequent structural evolution. This study systematically investigates hydration-state-dependent modification of polysulfone membranes through electron beam irradiation. By comparing atmospheric versus aqueous environment irradiation across graded doses, we demonstrate distinct pore structure evolution mechanisms. Electrochemical impedance spectroscopy analyses consistently revealed superior charge transfer resistance in dry-state membranes relative to their hydrated counterparts under equivalent irradiation conditions. Complementary positron annihilation characterization disclosed a critical hydration effect: irradiated hydrated membranes exhibited prolonged positron lifetimes, suggesting pore expansion, whereas dry-processed samples showed enhanced annihilation intensity indicative of increased porosity. These antiparallel trends in pore dimension versus density modulation establish that the hydration state fundamentally governs electron beam energy deposition pathways. The revealed environment-dependent structural control mechanism provides a new paradigm for precisely tailoring membrane architectures through irradiation parameter-space engineering.

A triethylamine (TEA) sensor based on Bi₂Se₃ nanosheets and MoO₃ nanobelts with high response was designed using hydrothermal and ultra-sonication strategies.

A new structure of monolayer h-CSe was predicted, exhibiting excellent stability. It was found to be an indirect semiconductor with a tunable bandgap by altering the strain and layer number. It also exhibits strong light harvesting ability.

The electronic and optical properties of three types of aluminum phosphide bilayers are examined using density functional theory. The results indicate that they all possess proper direct gaps, which exhibit a rich variety of behaviors depending on the strain. The band gaps of these aluminum phosphide bilayers could be easily tuned in the energy range from 0 eV to 1.9 eV under a wide range of biaxial strain. Additionally, band gap transitions between direct and indirect types are found when the external strain applied on them is changed from −12% to 12%. In addition, it was found that these AlP bilayers show strong light-harvesting ability for the ultraviolet light range of the solar spectrum (400–100 nm). The results obtained here indicate that these aluminum phosphide bilayers may have significant potential applications in future nanoelectric fields.

We theoretically investigate the optical bistability in superconductor–semiconductor photonic crystals composed of graphene. The photonic crystals are symmetric to the center and arranged alternately by the superconductor (HgBa₂Ca₂Cu₃O_8+δ) and semiconductor (GaAs) layers. The system supports a defect mode, and graphene is located at the layer interface where the local electric field is the strongest. Consequently, the optical nonlinearity of graphene has been greatly enhanced, and low-threshold optical bistability can be achieved with an incident wavelength red-detuning to the defect mode. The upper and lower thresholds of bistability increase with the increase in the value of low environmental temperature, while the interval between the upper and lower thresholds decreases. This research has a potential application in temperature-controlled optical switches and temperature-controlled optical memory.

Doping is an important method to modulate the physical and chemical properties of two-dimensional materials. By substitutional doping, different group IV–VI atoms are doped in GeSe monolayers to compose the doped models, of which the effects are investigated using first-principles calculations. The results show that local deformations of geometrical structure can be observed around the doping atoms. According to the analysis of the formation energy and the cohesive energy, all the doped models have a strongly bonded network, and GeSe_N possesses the most stable structure. Only the bandgap of Ge_As is direct, while those of other doped models are indirect. Thus, direct and indirect bandgaps are alternative by doping different atoms. The structural and electronic properties, especially for the bond lengths variation around doping atoms, are explained by the charge density difference. Finally, the scanning tunnel microscope images of the doped models are analyzed for further experimental investigations. Our work provides a stimulating account by atom doping which could trigger the developments and applications of new two-dimensional materials for manufacturing microelectronic and optoelectronic devices.