Kaixuan Chen

Excessive levels of Pb²⁺ and Cd²⁺ in seawater pose significant combined toxicity to marine organisms, resulting in harmful effects and further threatening human health through biomagnification in the food chain. Traditional methods for detecting marine Pb²⁺ and Cd²⁺ rely on laboratory analyses, which are hindered by limitations such as sample degradation during transport and complex operational procedures. In this study, we present an electrochemical sensor based on intelligent mobile detection devices. By combining G-COOH-MWCNTs/ZnO with differential pulse voltammetry, the sensor enables the efficient, simultaneous detection of Pb²⁺ and Cd²⁺ in seawater. The G-COOH-MWCNTs/ZnO composite film is prepared via drop-coating and is applied to a glassy carbon electrode. The film is characterized using cyclic voltammetry, electrochemical impedance spectroscopy, and scanning electron microscopy, while Pb²⁺ and Cd²⁺ are quantified using differential pulse voltammetry. Using a 0.1 mol/L sodium acetate buffer (pH 5.5), a deposition potential of −1.1 V, and an accumulation time of 300 s, a strong linear correlation was observed between the peak response currents of Pb²⁺ and Cd²⁺ and their concentrations in the range of 25–450 µg/L. The detection limits were 0.535 µg/L for Pb²⁺ and 0.354 µg/L for Cd²⁺. The sensor was applied for the analysis of seawater samples from Maowei Sea, achieving recovery rates for Pb²⁺ ranging from 97.7% to 103%, and for Cd²⁺ from 97% to 106.1%. These results demonstrate that the sensor exhibits high sensitivity and stability, offering a reliable solution for the on-site monitoring of heavy metal contamination in marine environments.

With the advancement of new synthetic techniques, 5-Methyl-2-ethylfuran (5-MEF) has emerged as a promising renewable biofuel. In this study, the potential energy surfaces for the unimolecular dissociation reaction, H-addition reaction, and H-abstraction reaction of 5-MEF were mapped at the CBS-QB3 level. The temperature- and pressure-dependent rate constants for these reactions on the potential energy surfaces were determined by solving the master equation, using both transition state theory and Rice–Ramsperger–Kassel–Marcus theory. The results showed that the dissociation reaction of the C(6) site on the branched chain of 5-MEF has the largest rate constant and is the main decomposition pathway, while the dissociation reaction of the H atom on the furan ring has a lower rate constant and is not the main reaction pathway. In addition, the dissociation of H atoms on the branched chain and intramolecular H-transfer reactions also have high-rate constants and play an important role in the decomposition of 5-MEF. H-addition reactions mainly occur at the C(2) and C(5) sites, and the generation of the corresponding products through β-breakage becomes the main reaction pathway. With the increase in temperature, the H-addition reaction at the C(2) site gradually changes to a substitution reaction, dominating the formation of C₂H₅ and 2-methylfuran.

Cavitation is typically observed when high-pressure submerged water jets are used. A composite nozzle, based on an organ pipe, can increase shear stress on the incoming flow, significantly enhancing cavitation performance by stacking Helmholtz cavities in series. In the present work, the flow field of the composite nozzle was numerically simulated using Large Eddy Simulation and was paired with the response surface method for global optimizing the crucial parameters of the composite nozzle to examine their effect on cavitation behavior. Utilizing peak gas-phase volume percent as the dependent variable and the runner diameter, Helmholtz chamber diameter, and Helmholtz chamber length as independent variables, a mathematical model was constructed to determine the ideal parameters of the composite nozzle through response surface methodology. The optimized nozzle prediction had an error of only 2.04% compared to the simulation results, confirming the accuracy of the model. To learn more about the cavitation cloud properties, an experimental setup for high-pressure cavitation jets was also constructed. Impact force measurements and high-speed photography tests were among the experiments conducted. The simulated evolution period of cavitation cloud characteristics is highly consistent with the experimental period. In the impact force measurement experiment, the simulated impact force oscillates between 256 and 297 N, and the measured impact force oscillates between 260 N and 289 N, with an error between 1.5% and 2.7%. The simulation model was verified by experimental results. This study provides new insights for the development of cavitation jet nozzle design theory.

The paper presents a wind–photovoltaic-thermal hybrid-driven two-stage humidification and dehumidification desalination system for remote island regions lacking access to electricity and freshwater resources. By conducting an analysis of the wind and solar energy resources at the experimental site, a suitable wind power station and photovoltaic power station are constructed. The performance of the wind–solar complementary power generation system is then evaluated based on factors such as output power, seawater desalination load power, battery compensation output, system energy consumption, and water production costs. A variable step gradient disturbance method based on the power–duty ratio is proposed for tracking the maximum power point (MPPT) of wind power generation. The output power of the photovoltaic power generation system is optimized, employing a fuzzy logic control (FLC) method to track the MPPT of photovoltaic power generation. This approach effectively addresses the issues of slow speed and low accuracy encountered by traditional MPPT algorithms in tracking the maximum power point (MPP) of both photovoltaic and wind power generations. In order to ensure that the desalination system can operate stably under different weather conditions, eight working modes are designed, and a programmable logic controller (PLC) is used to control the system, which provides a guarantee for stable water production. Experimental results demonstrate that the system exhibits stable performance, achieving a maximum water output of 80.63 Kg/h and daily water yield is 751.32 Kg, the cost of desalination equipment is 1.4892 USD/t.