Zhi-Yuan Zheng
Current Organizations / Institutes
The organizations/institutes from the scholar's latest article
Research Subjects
Zhi-Yuan Zheng has a total of 5 co-authors. Here are the top co-authors by number of shared publications:
- Ying Yu
College of Physics and Optoelectronics, Taiyuan University of Technology, Taiyuan 030024, China
4 shared publications - Ming-Ming Fan
College of Physics and Optoelectronic Engineering, Taiyuan University of Technology, Taiyuan 030024, China
2 shared publications - Zhiyuan Gu
College of Physics and Optoelectronics Taiyuan University of Technology Taiyuan China
2 shared publications - Qiao Jiang
Taiyuan University of Technology
1 shared publication Ying Yu
Taiyuan University of Technology
1 shared publication
Latest Publications
- 7 August 2026
- Published by Optica Publishing Group in Optics Express
- Vol. 34 (16) , 30575
Phase-state tuning and near-Γ modal-state selection for critical coupling in a metal-backed phase-change metasurface absorber
In metal-backed phase-change metasurface absorbers, the opaque reflector suppresses transmission and converts near-unity absorption into a single-port reflection-suppression problem. Near a dominant resonance, this suppression is achieved when radiative leakage is matched to intrinsic loss; phase transition can alter this balance through changes in material dissipation and modal field distribution. Here, we investigate a Si/Ge 2 Sb 2 Te 5 (GST)/Si metasurface on an Au substrate within a mode-resolved critical-coupling framework. At the Γ point, mode-resolved loss analysis identifies three spectrally separated resonant branches whose radiative/non-radiative loss balance evolves differently under GST crystallization. One branch is close to critical coupling in the amorphous state, whereas two initially radiation-dominated branches approach critical coupling at higher crystallization fractions. Together, these spectrally separated branches make high absorption accessible over discontinuous intervals covering approximately 70% of the crystallization-fraction range, while providing linewidth-resolvable, phase-state-selective spectral absorption channels. Near-Γ dispersion analysis further shows that finite- k x modal-state selection modifies the modal loss balance in a branch- and polarization-dependent manner, giving rise to angularly robust high absorption, polarization-dependent shifts of high-absorption conditions, and extension or reshaping of high-absorption intervals. These results establish a mode-resolved loss-balance picture for designing phase-change metasurface absorbers with broad crystallization-state coverage and for explaining how finite- k x modal dispersion enables angle-accessible high-absorption states.
- 7 August 2026
- Published by Optica Publishing Group in Optics Express
- Vol. 34 (16) , 30575
Phase-state tuning and near-Γ modal-state selection for critical coupling in a metal-backed phase-change metasurface absorber
In metal-backed phase-change metasurface absorbers, the opaque reflector suppresses transmission and converts near-unity absorption into a single-port reflection-suppression problem. Near a dominant resonance, this suppression is achieved when radiative leakage is matched to intrinsic loss; phase transition can alter this balance through changes in material dissipation and modal field distribution. Here, we investigate a Si/Ge 2 Sb 2 Te 5 (GST)/Si metasurface on an Au substrate within a mode-resolved critical-coupling framework. At the Γ point, mode-resolved loss analysis identifies three spectrally separated resonant branches whose radiative/non-radiative loss balance evolves differently under GST crystallization. One branch is close to critical coupling in the amorphous state, whereas two initially radiation-dominated branches approach critical coupling at higher crystallization fractions. Together, these spectrally separated branches make high absorption accessible over discontinuous intervals covering approximately 70% of the crystallization-fraction range, while providing linewidth-resolvable, phase-state-selective spectral absorption channels. Near-Γ dispersion analysis further shows that finite- k x modal-state selection modifies the modal loss balance in a branch- and polarization-dependent manner, giving rise to angularly robust high absorption, polarization-dependent shifts of high-absorption conditions, and extension or reshaping of high-absorption intervals. These results establish a mode-resolved loss-balance picture for designing phase-change metasurface absorbers with broad crystallization-state coverage and for explaining how finite- k x modal dispersion enables angle-accessible high-absorption states.
- 5 August 2026
- Published by AIP Publishing in Journal of Applied Physics
- Vol. 140 (5)
Enhancing optical confinement in hybrid surface plasmonic nanocavities via external mode coupling near avoided resonance crossings
Plasmonic devices have been intensively studied in the past few decades. However, the substantial intrinsic ohmic losses imposed by noble metals highly limited further applications of such devices. Herein, we demonstrate the formation of long-lived states via external mode coupling in coupled hybrid surface plasmonic nano-resonators in which improved Q factors have been achieved. By systematically engineering the spatial intervals between three silicon nanorods on a silver substrate, we demonstrate the formation of long-lived states through destructive interference of optical fields. Numerical simulations reveal that, at a critical spacing, the Q factor of a resonant mode is significantly boosted to approximately 450—an eightfold enhancement compared to isolated single-rod resonators. Notably, this drastic improvement in photon lifetime is achieved while maintaining an ultrasmall effective mode volume Veff of the order of 10−4 μm3. These findings provide an alternative strategy to material optimization for mitigating metallic losses, offering a robust framework for developing high-efficiency, low-threshold plasmonic nanolasers, and advanced on-chip photonic components.
- 5 August 2026
- Published by AIP Publishing in Journal of Applied Physics
- Vol. 140 (5)
Enhancing optical confinement in hybrid surface plasmonic nanocavities via external mode coupling near avoided resonance crossings
Plasmonic devices have been intensively studied in the past few decades. However, the substantial intrinsic ohmic losses imposed by noble metals highly limited further applications of such devices. Herein, we demonstrate the formation of long-lived states via external mode coupling in coupled hybrid surface plasmonic nano-resonators in which improved Q factors have been achieved. By systematically engineering the spatial intervals between three silicon nanorods on a silver substrate, we demonstrate the formation of long-lived states through destructive interference of optical fields. Numerical simulations reveal that, at a critical spacing, the Q factor of a resonant mode is significantly boosted to approximately 450—an eightfold enhancement compared to isolated single-rod resonators. Notably, this drastic improvement in photon lifetime is achieved while maintaining an ultrasmall effective mode volume Veff of the order of 10−4 μm3. These findings provide an alternative strategy to material optimization for mitigating metallic losses, offering a robust framework for developing high-efficiency, low-threshold plasmonic nanolasers, and advanced on-chip photonic components.
- Open Access
- 1 August 2026
- Published by AIP Publishing in AIP Advances
- Vol. 16 (8)
Angle-enhanced phase-change tuning of a guided-mode resonance in a GSST-integrated compound grating metasurface
High-Q resonant metasurfaces are attractive for narrowband spectral control, and integrating phase-change materials enables their resonant features to be tuned after fabrication. Beyond this material-state modulation, the external excitation condition can provide an additional degree of freedom for controlling the observable resonant response. Here, we propose a GSST-integrated one-dimensional compound grating metasurface for programmable guided-mode-resonance (GMR) tuning in the mid-infrared region. The structure consists of two Si/Ge2Sb2Se4Te1 (GSST)/Si multilayer ridges within one supercell of period A. A lateral displacement between the ridges breaks the half-period translational periodicity of the equally spaced reference grating, increasing the primitive period from A/2 to A. This period-doubling perturbation opens radiative coupling to an otherwise dark folded guided branch and forms an observable displacement-activated folded GMR with a deep transmission notch. Full-wave simulations show that the observable amorphous-to-crystalline tuning span increases from 7.13 nm at normal incidence to 26.20 nm at 10° incidence, while strong transmission suppression is maintained. Eigenmode analysis shows that accessing finite-kx operating points shifts the operating window toward shorter wavelengths along a strongly dispersive folded GMR branch and enlarges the separation between GSST states, rather than increasing the modal field concentration inside the GSST layer. Loss-channel analysis further explains the gradual lifting of the transmission minimum at larger incident angles. These results provide a practical strategy for dual-degree-of-freedom programmable spectral control in phase-change GMR metasurfaces.
- 1 August 2026
- Published by AIP Publishing in AIP Advances
- Vol. 16 (8)
Open AccessAngle-enhanced phase-change tuning of a guided-mode resonance in a GSST-integrated compound grating metasurface
High-Q resonant metasurfaces are attractive for narrowband spectral control, and integrating phase-change materials enables their resonant features to be tuned after fabrication. Beyond this material-state modulation, the external excitation condition can provide an additional degree of freedom for controlling the observable resonant response. Here, we propose a GSST-integrated one-dimensional compound grating metasurface for programmable guided-mode-resonance (GMR) tuning in the mid-infrared region. The structure consists of two Si/Ge2Sb2Se4Te1 (GSST)/Si multilayer ridges within one supercell of period A. A lateral displacement between the ridges breaks the half-period translational periodicity of the equally spaced reference grating, increasing the primitive period from A/2 to A. This period-doubling perturbation opens radiative coupling to an otherwise dark folded guided branch and forms an observable displacement-activated folded GMR with a deep transmission notch. Full-wave simulations show that the observable amorphous-to-crystalline tuning span increases from 7.13 nm at normal incidence to 26.20 nm at 10° incidence, while strong transmission suppression is maintained. Eigenmode analysis shows that accessing finite-kx operating points shifts the operating window toward shorter wavelengths along a strongly dispersive folded GMR branch and enlarges the separation between GSST states, rather than increasing the modal field concentration inside the GSST layer. Loss-channel analysis further explains the gradual lifting of the transmission minimum at larger incident angles. These results provide a practical strategy for dual-degree-of-freedom programmable spectral control in phase-change GMR metasurfaces.
- Open Access
Nonvolatile Spectral Tuning of UGR-like Resonances via Near-Merging C-Point Pairs in a GSST Phase-Change Metasurface
Unidirectional guided resonances (UGRs) provide a compact route to highly directional radiation without metallic reflectors, but their realization usually relies on precise structural tuning and is often restricted to isolated points in momentum or parameter space. Here, we propose a Ge2Sb2Se4Te1 (GSST)-based phase-change metasurface that enables nonvolatile spectral tuning of UGR-like resonances by controlling the momentum-space evolution of paired circular-polarization singularities. Instead of relying on an exact C-point merging condition at a single phase state, the proposed structure controls the approach and departure of a symmetry-related C-point pair relative to the line, with the closest sampled approach occurring near an intermediate crystallization state. This near-merging evolution selectively suppresses air-side radiation, giving rise to continuously tunable UGR-like resonances with persistent high directionality. At the high-directionality operating point selected for each of the crystallization states considered, the eigenwavelength shifts by , exceeding three times the largest eigenmode linewidth. Meanwhile, the downward-to-upward radiation asymmetry ratio consistently exceeds over the investigated phase states and reaches approximately near the optimal crystallization state. A self-consistent fixed-angle analysis further shows that a fixed substrate-side direction of , equivalent to in air, retains throughout all 11 states considered while preserving a tuning range. Despite increased crystalline-state absorption, the intrinsic substrate-side modal branching fraction remains at least . These results establish a nonvolatile strategy for combining spectrally resolvable tuning, persistent directional radiation, and substantial dominant-side modal out-coupling in a single phase-change metasurface.Open AccessNonvolatile Spectral Tuning of UGR-like Resonances via Near-Merging C-Point Pairs in a GSST Phase-Change Metasurface
Unidirectional guided resonances (UGRs) provide a compact route to highly directional radiation without metallic reflectors, but their realization usually relies on precise structural tuning and is often restricted to isolated points in momentum or parameter space. Here, we propose a Ge2Sb2Se4Te1 (GSST)-based phase-change metasurface that enables nonvolatile spectral tuning of UGR-like resonances by controlling the momentum-space evolution of paired circular-polarization singularities. Instead of relying on an exact C-point merging condition at a single phase state, the proposed structure controls the approach and departure of a symmetry-related C-point pair relative to the line, with the closest sampled approach occurring near an intermediate crystallization state. This near-merging evolution selectively suppresses air-side radiation, giving rise to continuously tunable UGR-like resonances with persistent high directionality. At the high-directionality operating point selected for each of the crystallization states considered, the eigenwavelength shifts by , exceeding three times the largest eigenmode linewidth. Meanwhile, the downward-to-upward radiation asymmetry ratio consistently exceeds over the investigated phase states and reaches approximately near the optimal crystallization state. A self-consistent fixed-angle analysis further shows that a fixed substrate-side direction of , equivalent to in air, retains throughout all 11 states considered while preserving a tuning range. Despite increased crystalline-state absorption, the intrinsic substrate-side modal branching fraction remains at least . These results establish a nonvolatile strategy for combining spectrally resolvable tuning, persistent directional radiation, and substantial dominant-side modal out-coupling in a single phase-change metasurface. - 7 July 2026
- Published by IOP Publishing in Journal of Physics D: Applied Physics
- Vol. 59 (27) , 275102
Polarization-selective access to an intrinsic high- Q mode family via a localized Ge 2 Sb 2 Te 5 perturbation in a mid-infrared dielectric metasurface
High- Q metasurfaces enable narrowband spectral control, yet active tuning with phase-change materials is often accompanied by linewidth broadening and reduced spectral contrast. Here we numerically show that a localized Ge 2 Sb 2 Te 5 (GST) patch on an otherwise symmetric silicon metasurface can serve simultaneously as a perturbative radiative coupler and an active tuning element. The patch selectively opens radiative access to an intrinsic dark high- Q mode family of the pristine structure while largely preserving the off-resonant background, yielding five narrow polarization-selective resonances in the 4 μ m to 5 μ m band. As GST evolves from the amorphous to the crystalline state, all resonances redshift, but the accompanying linewidth broadening and spectral-contrast degradation are strongly mode dependent. To quantify this behavior, we combine eigenmode analysis, a GST-region weighted overlap factor η GST , and same-polarization two-port temporal coupled-mode theory. Modes with larger η GST generally exhibit larger spectral shifts but are also more susceptible to absorption-induced contrast degradation. As GST crystallizes, the increased local asymmetric perturbation is expected to promote radiative access to the originally dark high- Q modes, while the concurrent rise in material absorption increases non-radiative loss and reduces the available interference amplitude. Across the resonance family, the maximum shift-to-linewidth ratio R SL reaches 9.08, while a semi-crystalline regime can provide a favorable compromise between tunability and spectral contrast. These results provide a symmetry- and loss-based framework for designing actively tunable high- Q metasurfaces using localized phase-change perturbations to selectively access and engineer intrinsic dark high- Q mode families.
- 7 July 2026
- Published by IOP Publishing in Journal of Physics D: Applied Physics
- Vol. 59 (27) , 275102
Polarization-selective access to an intrinsic high- Q mode family via a localized Ge 2 Sb 2 Te 5 perturbation in a mid-infrared dielectric metasurface
High- Q metasurfaces enable narrowband spectral control, yet active tuning with phase-change materials is often accompanied by linewidth broadening and reduced spectral contrast. Here we numerically show that a localized Ge 2 Sb 2 Te 5 (GST) patch on an otherwise symmetric silicon metasurface can serve simultaneously as a perturbative radiative coupler and an active tuning element. The patch selectively opens radiative access to an intrinsic dark high- Q mode family of the pristine structure while largely preserving the off-resonant background, yielding five narrow polarization-selective resonances in the 4 μ m to 5 μ m band. As GST evolves from the amorphous to the crystalline state, all resonances redshift, but the accompanying linewidth broadening and spectral-contrast degradation are strongly mode dependent. To quantify this behavior, we combine eigenmode analysis, a GST-region weighted overlap factor η GST , and same-polarization two-port temporal coupled-mode theory. Modes with larger η GST generally exhibit larger spectral shifts but are also more susceptible to absorption-induced contrast degradation. As GST crystallizes, the increased local asymmetric perturbation is expected to promote radiative access to the originally dark high- Q modes, while the concurrent rise in material absorption increases non-radiative loss and reduces the available interference amplitude. Across the resonance family, the maximum shift-to-linewidth ratio R SL reaches 9.08, while a semi-crystalline regime can provide a favorable compromise between tunability and spectral contrast. These results provide a symmetry- and loss-based framework for designing actively tunable high- Q metasurfaces using localized phase-change perturbations to selectively access and engineer intrinsic dark high- Q mode families.
- Open Access
Loss-Managed BIC-Derived GSST Metasurface for Robust Phase-Change-Tunable Mid-Infrared Transmission Suppression
We propose a loss-managed BIC-derived GSST metasurface for robust phase-change-tunable mid-infrared transmission suppression. The metasurface consists of a SiO2 substrate, a Si grating layer, and an upper Si/Ge2Sb2Se4Te1 (GSST)/Si trilayer with an off-centered air slot. The slot plays a dual role: it breaks the mirror symmetry of the unit cell to convert a symmetry-protected bound state in the continuum into an externally accessible high-Q resonance, while reducing the effective GSST filling region to limit material-loss participation. Lossless eigenmode analysis confirms the BIC-derived origin of the resonance, with the quality factor following . A crystalline-state loss-channel analysis further identifies as a finite-coupling operating point that preserves good up/down radiation balance, a large resonant amplitude factor, and a moderate-high quality factor under the fully crystalline GSST condition. Full-wave simulations show that the transmission-dip wavelength shifts from about to about as GSST evolves from the amorphous to the crystalline state, while the extracted quality factor remains in the range of 483–780 and the transmission minimum stays deeply suppressed throughout the phase-change trajectory. A two-port temporal coupled-mode theory analysis reveals that this persistent low-transmission state originates from destructive interference between the resonant and background transmission channels. Fabrication tolerance analysis shows that variations in GSST thickness and slot width, as well as moderate variations in the slot displacement, preserve the deep transmission suppression across GSST phase states, although the absolute resonance wavelength shifts with geometry. These results provide a practical strategy for balancing radiative coupling and material-loss participation in phase-change high-Q metasurfaces.Open AccessLoss-Managed BIC-Derived GSST Metasurface for Robust Phase-Change-Tunable Mid-Infrared Transmission Suppression
We propose a loss-managed BIC-derived GSST metasurface for robust phase-change-tunable mid-infrared transmission suppression. The metasurface consists of a SiO2 substrate, a Si grating layer, and an upper Si/Ge2Sb2Se4Te1 (GSST)/Si trilayer with an off-centered air slot. The slot plays a dual role: it breaks the mirror symmetry of the unit cell to convert a symmetry-protected bound state in the continuum into an externally accessible high-Q resonance, while reducing the effective GSST filling region to limit material-loss participation. Lossless eigenmode analysis confirms the BIC-derived origin of the resonance, with the quality factor following . A crystalline-state loss-channel analysis further identifies as a finite-coupling operating point that preserves good up/down radiation balance, a large resonant amplitude factor, and a moderate-high quality factor under the fully crystalline GSST condition. Full-wave simulations show that the transmission-dip wavelength shifts from about to about as GSST evolves from the amorphous to the crystalline state, while the extracted quality factor remains in the range of 483–780 and the transmission minimum stays deeply suppressed throughout the phase-change trajectory. A two-port temporal coupled-mode theory analysis reveals that this persistent low-transmission state originates from destructive interference between the resonant and background transmission channels. Fabrication tolerance analysis shows that variations in GSST thickness and slot width, as well as moderate variations in the slot displacement, preserve the deep transmission suppression across GSST phase states, although the absolute resonance wavelength shifts with geometry. These results provide a practical strategy for balancing radiative coupling and material-loss participation in phase-change high-Q metasurfaces. - Open Access
Tunable Unidirectional Guided Resonances in Momentum Space via a Si-Ge2Sb2Te5 Metasurface
Unidirectional guided resonances (UGRs) in periodic metasurfaces have recently attracted research interest because of their ability to achieve unidirectional radiation in all-dielectric structures without metal reflectors, which offers new possibilities for efficient grating couplers and unidirectional lasers. Here, we propose a hybrid metasurface consisting of silicon and (GST) phase change material for controlled UGR generation in the mid-infrared region. Leveraging GST’s phase-change properties to modulate the optical response of the metasurface, we achieve tunable generation of the UGR, which is demonstrated to carry a topological charge of +1. Moreover, by adjusting the degree of GST phase transition, continuous tuning of the radiation asymmetry ratio from to 1 is achieved for a specific in-plane momentum and operating wavelength. These findings offer a promising avenue for dynamically controllable UGRs, with potential applications in tunable on-chip optical couplers and light sources.Open AccessTunable Unidirectional Guided Resonances in Momentum Space via a Si-Ge2Sb2Te5 Metasurface
Unidirectional guided resonances (UGRs) in periodic metasurfaces have recently attracted research interest because of their ability to achieve unidirectional radiation in all-dielectric structures without metal reflectors, which offers new possibilities for efficient grating couplers and unidirectional lasers. Here, we propose a hybrid metasurface consisting of silicon and (GST) phase change material for controlled UGR generation in the mid-infrared region. Leveraging GST’s phase-change properties to modulate the optical response of the metasurface, we achieve tunable generation of the UGR, which is demonstrated to carry a topological charge of +1. Moreover, by adjusting the degree of GST phase transition, continuous tuning of the radiation asymmetry ratio from to 1 is achieved for a specific in-plane momentum and operating wavelength. These findings offer a promising avenue for dynamically controllable UGRs, with potential applications in tunable on-chip optical couplers and light sources. - Open Access
- 16 September 2025
- Published by AIP Publishing in Journal of Applied Physics
- Vol. 138 (11)
Exceptional points in microdisk cavities with bound states in the continuum
In the past few decades, bound states in the continuum (BICs) have been intensively studied due to their superiority in suppressing radiation losses, highlighting potential applications in lasers, imaging, and sensors. Up to now, BICs have been theoretically and experimentally verified in microdisks, waveguides, and metasurfaces, which offer new perspectives to explore novel physics in such configurations. Among these preliminary research studies, microdisks based on Friedrich–Wintgen BICs (FW-BICs) show unprecedented properties, which are not accessible in the conventional system, allowing the existence of bound states in configurations possessing structural symmetry and mode interference or structures with a lower refractive index than that of the surrounding. However, compared to thoroughly explored cavity physics for conventional microdisks, only the merits of high quality and etchless fabrication procedures in BIC microdisks are confirmed, and further explorations are still absent, significantly limiting the application potential of these structures. In this work, we investigate a new kind of singularity by merging two FW-BICs into one. The resultant state not only exhibits enhanced sensitivity to perturbations, but also shows totally suppressed radiations. We believe that our findings illustrate an effective way to design devices with novel functions and expand the application potential of FW-BIC microdisks.
- 16 September 2025
- Published by AIP Publishing in Journal of Applied Physics
- Vol. 138 (11)
Open AccessExceptional points in microdisk cavities with bound states in the continuum
In the past few decades, bound states in the continuum (BICs) have been intensively studied due to their superiority in suppressing radiation losses, highlighting potential applications in lasers, imaging, and sensors. Up to now, BICs have been theoretically and experimentally verified in microdisks, waveguides, and metasurfaces, which offer new perspectives to explore novel physics in such configurations. Among these preliminary research studies, microdisks based on Friedrich–Wintgen BICs (FW-BICs) show unprecedented properties, which are not accessible in the conventional system, allowing the existence of bound states in configurations possessing structural symmetry and mode interference or structures with a lower refractive index than that of the surrounding. However, compared to thoroughly explored cavity physics for conventional microdisks, only the merits of high quality and etchless fabrication procedures in BIC microdisks are confirmed, and further explorations are still absent, significantly limiting the application potential of these structures. In this work, we investigate a new kind of singularity by merging two FW-BICs into one. The resultant state not only exhibits enhanced sensitivity to perturbations, but also shows totally suppressed radiations. We believe that our findings illustrate an effective way to design devices with novel functions and expand the application potential of FW-BIC microdisks.
- 15 May 2024
- Published by IOP Publishing in Semiconductor Science and Technology
- Vol. 39 (6) , 065013
Fabrication of Al doped α-GaOOH nanorod arrays on FTO for self-powered photoelectrochemical solar-blind UV photodetectors
Al doped α-GaOOH nanorod arrays were grown on FTO via hydrothermal processes by using gallium nitrate and aluminum nitrate mixed aqueous solutions with fixed 1:1 mole ratio as precursors. With increasing the gallium nitrate precursor concentrations, the Ga/Al atom ratios in nanorod arrays increase from 0.36 to 2.08, and the length becomes much longer from 650 nm to 1.04 μm. According to the binding energy difference between Ga 2p3/2 core level and its background in x-ray photoelectron spectroscopy, the bandgap is estimated to be around 5.3 ± 0.2 eV. Al doped α-GaOOH nanorod array/FTO photoelectrochemical photodetectors show enhanced self-powered solar-blind UV photodetection properties, with the decrease of Ga precursor concentrations. The maximum responsivity at 255 nm is 0.09 mA W−1, and the fastest response time can reach 0.05 s. The improved photoresponse speed is ascribed from much shorter transportation route, accelerated carrier recombination by recombination centers, and smaller charge transfer resistance at the α-GaOOH/electrolyte interface with decreasing the gallium nitrate precursor concentrations. The stability and responsivity should be further improved. Nevertheless, this work firstly demonstrates the realization of self-powered solar-blind UV photodetection for α-GaOOH nanorod arrays on FTO via Al doping.
- 15 May 2024
- Published by IOP Publishing in Semiconductor Science and Technology
- Vol. 39 (6) , 065013
Fabrication of Al doped α-GaOOH nanorod arrays on FTO for self-powered photoelectrochemical solar-blind UV photodetectors
Al doped α-GaOOH nanorod arrays were grown on FTO via hydrothermal processes by using gallium nitrate and aluminum nitrate mixed aqueous solutions with fixed 1:1 mole ratio as precursors. With increasing the gallium nitrate precursor concentrations, the Ga/Al atom ratios in nanorod arrays increase from 0.36 to 2.08, and the length becomes much longer from 650 nm to 1.04 μm. According to the binding energy difference between Ga 2p3/2 core level and its background in x-ray photoelectron spectroscopy, the bandgap is estimated to be around 5.3 ± 0.2 eV. Al doped α-GaOOH nanorod array/FTO photoelectrochemical photodetectors show enhanced self-powered solar-blind UV photodetection properties, with the decrease of Ga precursor concentrations. The maximum responsivity at 255 nm is 0.09 mA W−1, and the fastest response time can reach 0.05 s. The improved photoresponse speed is ascribed from much shorter transportation route, accelerated carrier recombination by recombination centers, and smaller charge transfer resistance at the α-GaOOH/electrolyte interface with decreasing the gallium nitrate precursor concentrations. The stability and responsivity should be further improved. Nevertheless, this work firstly demonstrates the realization of self-powered solar-blind UV photodetection for α-GaOOH nanorod arrays on FTO via Al doping.
- 20 March 2024
- Published by Elsevier in Current Applied Physics
- Vol. 62, 40-45
Self-powered α-GaOOH nanorod array/FTO photoelectrochemical photodetectors for solar-blind UV photodetection
- 20 March 2024
- Published by Elsevier in Current Applied Physics
- Vol. 62, 40-45
Self-powered α-GaOOH nanorod array/FTO photoelectrochemical photodetectors for solar-blind UV photodetection