Eunyoung Park

In coherent diffraction imaging (CDI), the coherence properties of photons play critical roles in obtaining structural information from specimens without using lenses. While the impact of coherence has been widely studied in CDI, it has not been systematically investigated within the specific framework of X-ray free-electron laser (XFEL)-CDI. Here, we examined the relationship between the transverse and temporal coherence of XFEL pulses and the quality of image reconstruction using XFELs. Specifically, we investigated the properties of self-amplified spontaneous emission and self-seeding beams at an X-ray energy of 5 keV by collecting diffraction patterns from a single gold nanoparticle. Furthermore, the quality of the reconstructed images obtained using the two beam modes was compared. Our results demonstrate that the self-seeding beam offers more reliable image reconstruction that is attributable to the narrower bandwidth of the incident X-rays. This study highlights the advantages of utilizing a self-seeding beam in CDI experiments, particularly for enhancing the reliability and quality of image reconstruction.

A Nanobeam X-ray Experiments (NXE) instrument was developed and installed at the hard X-ray beamline of the Pohang Accelerator Laboratory X-ray Free Electron Laser. This instrument consists of a diagnostic system, focusing optics, an X-ray diffraction endstation and a femtosecond laser delivery system. The NXE instrument enables sophisticated X-ray experiments using nanofocused X-rays. At a 9.5 keV X-ray energy, the beam was successfully focused to 390 nm × 230 nm at the focal plane using Kirkpatrick–Baez mirrors. Following the successful commissioning experiments in December 2021 and April 2022, the instrument became available for regular user experiments in January 2023. The first user experiment was conducted in January 2024. This article provides detailed information on the beamline optics, the NXE instrument, and its performance and capabilities.

Ultrafast photoinduced melting provides an essential platform for studying nonequilibrium phase transitions by linking the kinetics of electron dynamics to ionic motions. Knowledge of dynamic balance in their energetics is essential to understanding how the ionic reaction is influenced by femtosecond photoexcited electrons with notable time lag depending on reaction mechanisms. Here, by directly imaging fluctuating density distributions and evaluating the ionic pressure and Gibbs free energy from two-temperature molecular dynamics that verified experimental results, we uncovered that transient ionic pressure, triggered by photoexcited electrons, controls the overall melting kinetics. In particular, ultrafast nonequilibrium melting can be described by the reverse nucleation process with voids as nucleation seeds. The strongly driven solid-to-liquid transition of metallic gold is successfully explained by void nucleation facilitated by photoexcited electron–initiated ionic pressure, establishing a solid knowledge base for understanding ultrafast nonequilibrium kinetics.