Giacomo Cedrone

Sewage sludge management is a key concern in today’s world. Improper disposal can lead to various environmental issues including air, water and soil pollution. Among the available technologies, thermal treatments, particularly pyrolysis, are gaining interest for their ability to reduce sewage sludge volume and to recover materials and energy from it. This study explored the influence of some relevant parameters in the thermal pyrolysis process. The design of experiment, named central composite design, was accounted to optimize temperature, heating rate and residence time in order to maximize the biochar yield and its CO₂ adsorption capacity. A two-factor interaction model provided a satisfactory interpretation of the results. Within the studied ranges, maximum values of 47.8 wt% and 0.514 mol CO₂/kg were obtained for the yield and CO₂ adsorption capacity, respectively. Two significant experiments were repeated in a different pyrolysis system highlighting how other factors (e.g., reactor geometry, granulometry, etc.) can influence the quantity and the quality of produced biochar. The biochar obtained under the best pyrolysis conditions was characterized by a surface area of 124 m²/g and an ash content of 61 wt%. Lastly, the theoretical energy balance showed that the drying process is the main energy-intensive step in the pyrolysis of sewage sludge.