Lebo Molefe

On the surface of a vibrating liquid bath, instead of coalescing, a drop will continually bounce on a thin film of air between the drop and the free surface, giving rise to rich chaotic dynamics and quantum analog behavior. However, perpetual bouncing is yet to be demonstrated on a vibrating rigid solid, where the control of the drop’s motion is not limited by the bath dynamics. Here we show that vibration of an atomically smooth mica surface prolongs a drop’s hovering state by several orders of magnitude, increasing the time to wet from less than a second to several minutes. The excitation of the second spherical harmonic mode determines a transition between a bouncing state with high-amplitude rebounds, and a bound state, where the drop’s motion is locked onto the vibrating solid above a thin air layer. We further develop a coupled linear spring model, accounting for the drop’s deformation, that predicts bouncing trajectories without fitting parameters. Our results extend the scope of bouncing drop studies beyond the liquid bath and highlight the potential for precision manipulation of small liquid quantities in air.

Surface roughness significantly modifies the liquid film thickness entrained when dip coating a solid surface, particularly at low coating velocity. Using a homogenization approach, we present a predictive model for determining the liquid film thickness coated on a rough plate. A homogenized boundary condition at an equivalent flat surface is used to model the rough boundary, accounting for both flow through the rough texture layer, through an interface permeability term, and slip at the equivalent surface. While the slip term accounts for tangential velocity induced by viscous shear stress, accurately predicting the film thickness requires the interface permeability term to account for additional tangential flow driven by pressure gradients along the interface. We find that a greater degree of slip and interface permeability signifies less viscous stress that would promote deposition, thus reducing the amount of free film coated above the textures. The model is found to be in good agreement with experimental measurements, and requires no fitting parameters. Furthermore, our model may be applied to arbitrary periodic roughness patterns, opening the door to flexible characterization of surfaces found in natural and industrial coating processes.