Ivan Rostovsky

This study presents the development of a one-part phosphate-activated geopolymer foam based on fayalite flotation residue from the copper industry. The solid activator consisted of triple superphosphate, enabling a dry-mix binder that requires only water addition prior to use. Foamed materials were characterized by XRD, FTIR, Mössbauer spectroscopy, DSC-TG, hot-stage microscopy, SEM-EDX and physical and mechanical testing. The foaming of the geopolymer reduced the densities between 0.753 and 2.15 g/cm³, relative porosities up to 73.6%, and compressive strengths ranging from 1.4 to 28.8 MPa. The foamed geopolymer maintained dimensional stability up to about 1000 °C. The thermal conductivity coefficient measured on large-sized specimen blocks was 0.099 W/mK at a density of 0.753 g/cm³. These results demonstrate that fayalite slag can be effectively utilized as a precursor for sustainable geopolymer foams combining low thermal conductivity, high thermal stability, and the utilization of industrial by-products.

The present work is the first study exploring the potential of geopolymer foams based on fayalite slag, an industrial by-product, as the primary precursor, for lightweight and fireproof construction applications. The research involved the synthesis and characterization of geopolymer foams with varying water to solid ratio, followed by testing their physical and mechanical properties. The phase composition and microstructure of the obtained geopolymer foams were examined using powder XRD, Micro-CT and SEM. The geopolymer foams at optimal water to solid ratio (0.15) demonstrated 73.2% relative porosity, 0.92 g/cm³ apparent density and 1.3 MPa compressive strength. The use of an air-entraining admixture improved compressive strength to 2.8 MPa but lowered the relative porosity to 64.5%. Real-size lightweight panel (300 × 300 × 30 mm) specimens were prepared to measure thermal conductivity coefficient (0.243 W/mK) and evaluate size effect and the reaction to direct fire. This study demonstrates the successful preparation of geopolymer foam products containing 81% fayalite slag, highlighting its potential as a lightweight, insulating and fire-resistant material for sustainable construction applications.

The present work is the first study exploring the potential of geopolymer foams based on fayalite slag, an industrial by-product, as the primary precursor, for lightweight and fireproof construction applications. The research involved synthesis and characterization of geopolymer foams with varying water to solid ratio, followed by testing their physical and mechanical properties. The phase composition and microstructure of the obtained geopolymer foams were examined using powder XRD, Micro-CT and SEM. The geopolymer foams at optimal water to solid ration (0.15) demonstrated 73.2% relative porosity, 0.92 g/cm³ apparent density and 1.3 MPa compressive strength. The use of an air-entraining agent improved compressive strength to 2.8 MPa but lower to 64.5% the relative porosity. Real-size lightweight panel (300 × 300 × 30 mm) specimens were prepared and to measure thermal conductivity coefficient (0.243 W/mK), to evaluate size effect, and the reaction to direct fire. The results of the study of geopolymer foams based on fayalite slag demonstrate their potential as lightweight, insulating and fire-resistant materials suitable for implementation in environmentally friendly construction methods.