Hong-Yao Guo
Current Organizations / Institutes
The organizations/institutes from the scholar's latest article
Hong-Yao Guo has a total of 2 co-authors. Here are the top co-authors by number of shared publications:
- Ji-Dong Leng
School of Chemistry and Chemical Engineering/Institute of Clean Energy and Materials, Guangzhou University No. 230 Wai Huan Xi Road, Guangzhou Higher Education Mega Center, Guangzhou 510006, P. R. China
1 shared publication - Wei-Quan Lin
School of Chemistry and Chemical Engineering/Institute of Clean Energy and Materials, Guangzhou University No. 230 Wai Huan Xi Road, Guangzhou Higher Education Mega Center, Guangzhou 510006, P. R. China
1 shared publication
Latest Publications
- Open Access
Field-Induced Slow Magnetic Relaxation in Pentacoordinate Co(II) Complexes: Tuning Magnetic Anisotropy Through Halide Substitution
We report the synthesis, structural characterization, and magnetic properties of three pentacoordinate Co(II) complexes [CoX(dppb)2]X (X = Cl (1Cl), Br (2Br), and I (3I)) supported by the bidentate phosphine ligand 1,2-bis(diphenylphosphino)benzene (dppb). Single-crystal X-ray diffraction reveals that all three complexes adopt similar vacant octahedron (C4v) geometries with the halide ligand in one axial position. Magnetic studies demonstrate that these complexes exhibit field-induced slow magnetic relaxation behaviors, with positive D values of 25.3(2), 21.6(1), and 19.4(2) cm−1 for 1Cl, 2Br, and 3I, respectively. Detailed analysis of the relaxation dynamics reveals that Raman processes dominate at higher temperatures, with systematic variations in relaxation parameters across the series. The systematic variations in magnetic anisotropy and slow magnetic relaxation behaviors of the three complexes correlate with the decreasing electronegativity of the halide ligands.
Open AccessField-Induced Slow Magnetic Relaxation in Pentacoordinate Co(II) Complexes: Tuning Magnetic Anisotropy Through Halide Substitution
We report the synthesis, structural characterization, and magnetic properties of three pentacoordinate Co(II) complexes [CoX(dppb)2]X (X = Cl (1Cl), Br (2Br), and I (3I)) supported by the bidentate phosphine ligand 1,2-bis(diphenylphosphino)benzene (dppb). Single-crystal X-ray diffraction reveals that all three complexes adopt similar vacant octahedron (C4v) geometries with the halide ligand in one axial position. Magnetic studies demonstrate that these complexes exhibit field-induced slow magnetic relaxation behaviors, with positive D values of 25.3(2), 21.6(1), and 19.4(2) cm−1 for 1Cl, 2Br, and 3I, respectively. Detailed analysis of the relaxation dynamics reveals that Raman processes dominate at higher temperatures, with systematic variations in relaxation parameters across the series. The systematic variations in magnetic anisotropy and slow magnetic relaxation behaviors of the three complexes correlate with the decreasing electronegativity of the halide ligands.