Dong Li

Bulk two dimensional (2D) superconductivity has gained considerable attention due to its intricate interplay between symmetry breaking, nontrivial topology, 2D phase fluctuations, and unconventional superconductivity. However, certain intercalated layered superconductors, despite their short c-axis superconducting coherence length, have been misclassified as anisotropic three-dimensional (3D) superconductors. Here, we investigate (Li,Fe)OHFeSe superconductors with varying degrees of interlayer misalignment, revealing sample-dependent superconducting dimensionality while consistently observing Berezinskii Kosterlitz Thouless (BKT) transitions. To resolve this discrepancy, we develop an extended 2D Tinkham model that quantitatively captures the blurring effects induced by interlayer misalignment. We further demonstrate the validity of this model in both (Li,Fe)OHFeSe and cetyltrimethyl ammonium (CTA+) intercalated (CTA)0.5SnSe2 superconductors, highlighting its broad applicability. This work provides valuable insights into bulk 2D superconductivity and establishes an extended 2D Tinkham model for quantitatively extracting intrinsic superconducting properties in intercalated layered superconductors, particularly those exhibiting significant interlayer misalignments.

Symmetry elegantly governs the fundamental properties and derived functionalities of condensed matter. For instance, realizing the superconducting diode effect (SDE) demands breaking space-inversion and time-reversal symmetries simultaneously. Although the SDE is widely observed in various platforms, its underlying mechanism remains debated, particularly regarding the role of vortices. Here, we systematically investigate the nonreciprocal transport in the chiral type-I superconductor NbGe₂. Moreover, we induce type-II superconductivity with elevated superconducting critical temperature on the artificial surface by focused ion beam irradiation, enabling control over vortex dynamics in NbGe₂ devices. Strikingly, we observe negligible diode efficiency (Q < 2%) at low magnetic fields, which rises significantly to Q ~ 50% at high magnetic fields, coinciding with an abrupt increase in vortex creep rate when the superconductivity of NbGe₂ bulk is suppressed. These results unambiguously highlight the critical role of vortex dynamics in the SDE, in addition to the established symmetry rules.

Symmetry elegantly governs the fundamental properties and derived functionalities of condensed matter. For instance, realizing the superconducting diode effect (SDE) demands breaking space-inversion and time-reversal symmetries simultaneously. Although the SDE is widely observed in various platforms, its underlying mechanism remains debated, particularly regarding the role of vortices. Here, we systematically investigate the nonreciprocal transport in the chiral type-I superconductor NbGe2. Moreover, we induce type-II superconductivity with elevated superconducting critical temperature on the artificial surface by focused ion beam irradiation, enabling control over vortex dynamics in NbGe2 devices. Strikingly, we observe negligible diode efficiency (Q < 2%) at low magnetic fields, which rises significantly to Q ~ 50% at high magnetic fields, coinciding with an abrupt increase in vortex creep rate when the superconductivity of NbGe2 bulk is suppressed. These results unambiguously highlight the critical role of vortex dynamics in the SDE, in addition to the established symmetry rules.

Vortex pinning is a crucial factor that determines the critical current of practical superconductors and enables their diverse applications. However, the underlying mechanism of vortex pinning has long been elusive without a clear microscopic description^1,2. Here using high-resolution scanning tunneling microscopy, we studied single vortex pinning induced by point defect in layered FeSe-based superconductors. We found the defect-vortex interaction drives low-energy vortex bound states away from E _F, resulting a “mini” gap which effectively lowered the system energy and caused the pinning. By measuring the local density-of-states, we directly obtained the elementary pinning energy and estimated the pinning force through the spatial gradient of pinning energy. The results align with the bulk critical current measurement. We further show that a general microscopic quantum model with considering defect-vortex interaction can naturally capture our observation. It indicates the local pairing near pinned vortex core is actually enhanced, which is beyond the traditional understanding that non- superconducting regions pin vortices^1-3. Our study thus reveals a general microscopic mechanism of vortex pinning in superconductors, and provides guidance for enhancing the critical current of real superconductors.

The Kagome lattice, naturally encompassing Dirac fermions, flat bands, and van Hove singularities, tends to intertwine exotic electronic states. Revealing the characteristics of its Fermi surface will help on clarifying the nature of the complex quantum phenomena in kagome material. Here we report the Fermi surface properties of the new kagome superconductor CsTi₃Bi₅ by the de Haas–van Alphen oscillations. The observed oscillations are clear and consist of six principal frequencies ranging from 214 T to 1013 T. The angular dependence of the frequency implies a quasi-two-dimensional electronic structure. In addition, the Berry phase corresponding to 281 T, determined by the Landau level fan diagram method and full Lifshitz-Kosevich formula fitting, yields a value close to π, which indicates a band structure with nontrivial topological property. These results underscore the potential of CsTi₃Bi₅ as a promising new platform to explore the interplay between topological order, electronic nematicity, and superconductivity.

Intertwined spin and charge orders have been widely studied in high-temperature superconductors, since their fluctuations may facilitate electron pairing; however, they are rarely identified in heavily electron-doped iron selenides. Here, using scanning tunneling microscopy, we show that when the superconductivity of (Li_0.84Fe_0.16OH)Fe_1-xSe is suppressed by introducing Fe-site defects, a short-ranged checkerboard charge order emerges, propagating along the Fe-Fe directions with an approximately 2a_Fe period. It persists throughout the whole phase space tuned by Fe-site defect density, from a defect-pinned local pattern in optimally doped samples to an extended order in samples with lower T_c or non-superconducting. Intriguingly, our simulations indicate that the charge order is likely driven by multiple-Q spin density waves originating from the spin fluctuations observed by inelastic neutron scattering. Our study proves the presence of a competing order in heavily electron-doped iron selenides, and demonstrates the potential of charge order as a tool to detect spin fluctuations.

The intercalated iron selenide (Li,Fe)OHFeSe has a strongly layered structure analogous to the quasi two-dimensional (2D) bismuth cuprate superconductors, and exhibits both high-temperature (Tc) and topological superconductivity. However, the issue of its superconductivity dimensionality has not yet been fully investigated so far. Here we report that the quasi-2D superconductivity features, including the high anisotropy {\gamma} = 151 and the associated quasi-2D vortices, are also revealed for (Li,Fe)OHFeSe, based on systematic experiments of the electrical transport and magnetization and model fittings. Thus, we establish a new vortex phase diagram for (Li,Fe)OHFeSe, which delineates an emergent quasi-2D vortex-liquid state, and a subsequent vortex-solid dimensional crossover from a pancake-like to a three-dimensional state with decreasing temperature and magnetic field. Furthermore, we find that all the quasi-2D characteristics revealed here for the high-Tc iron selenide superconductor are very similar to those reported for the high-Tc bismuth cuprate superconductors.