Alberto Berardi

Aluminum alloy AA6082 (Al-Si-Mg) is a lightweight alloy that requires thick barrier coatings to be protected from localized corrosion. Plasma Electrolytic Oxidation (PEO) coating is a common anodic surface treatment used for growing protective oxides; the main process variables of PEO are the composition of the electrolytic solution and the electrical input. This work focuses on the optimization of the electrical input by comparing different coatings produced by potentiostatic PEO at the effective potential of 350 V, applied by different combinations of voltage ramps with various slopes and maintenance times at the fixed potential. All processes lasted five minutes. The innovative character of this research work is the evaluation of the combined effect of the anodizing voltage and its different trends with time on the coating structure and morphology. The corrosion resistance of coated AA6082 is assessed in contact with chlorides, reproducing seawater. The resulting anodic coatings were compared in terms of structure, composition (thickness, XRD, SEM-EDS) and corrosion resistance (potentiodynamic polarization and electrochemical impedance spectroscopy), finding that longer maintenance at high anodizing potentials promotes localized high-energy plasma discharges, producing larger pores and thicker, but less protective coatings. Results show that the coating thickness increases with the maintenance time (maximum thickness value~17.6 μm). Shorter maintenance periods and longer voltage ramps lead to a lower surface porosity and enhanced corrosion performances of the oxide. The thinnest and least porous coating exhibits the best corrosion behavior (CR~1.1 μm/year).