Anna I. Chernysheva
Current Organizations / Institutes
The organizations/institutes from the scholar's latest article
Research Subjects
Anna I. Chernysheva has a total of 8 co-authors. Here are the top co-authors by number of shared publications:
- Andrey S. Esin
Department of Chemical Technology of Plastic Materials, Mendeleev University of Chemical Technology of Russia, Miusskaya Square 9, 125047 Moscow, Russia
1 shared publication - Ekaterina A. Karpova
Department of Chemical Technology of Plastic Materials, Mendeleev University of Chemical Technology of Russia, Miusskaya Square 9, 125047 Moscow, Russia
1 shared publication - Ekaterina A. Yurasova
Department of Plastic Processing Technology, Mendeleev University of Chemical Technology of Russia, Miusskaya Square 9, 125047 Moscow, Russia
1 shared publication - Igor S. Sirotin
Faculty of Petrochemistry and Polymer Materials, Mendeleev University of Chemical Technology of Russia, Miusskaya sq. 9, 125047 Moscow, Russia
1 shared publication - Mikhail A. Soldatov
Department of Chemical Technology of Polymer Composite Paint Materials and Coatings, Mendeleev University of Chemical Technology of Russia, Miusskaya Square 9, 125047 Moscow, Russia
1 shared publication - Mikhail V. Gorlov
D. Mendeleev University of Chemical Technology of Russia, Miusskaya sq. 9, 125047 Moscow, Russia
1 shared publication
Latest Publications
- Open Access
Hydrosilylation vs. Piers–Rubinsztajn: Synthetic Routes to Chemically Cross-Linked Hybrid Phosphazene-Siloxane 3D-Structures
Exploration of new ways for the direct preparation of cross-linked structures is a significant problem in terms of materials for biomedical applications, lithium batteries electrolytes, toughening of thermosets (epoxy, benzoxazine, etc.) with interpenetrating polymer network, etc. The possibility to utilize hydrosilylation and Piers–Rubinsztajn reactions to obtain cross-linked model phosphazene compounds containing eugenoxy and guaiacoxy groups has been studied. It was shown that Piers–Rubinsztajn reaction cannot be used to prepare phosphazene-based tailored polymer matrix due to the catalyst deactivation by nitrogen atoms of main chain units. Utilizing the hydrosilylation reaction, a series of cross-linked materials were obtained, and their properties were studied by NMR spectroscopy, FTIR, DSC, and TGA. Rheological characterizations of the prepared tailored matrices were conducted. This work showed a perspective of using eugenoxy functional groups for the preparation of three-dimensional hybrid phosphazene/siloxane-based materials for various applications.
Open AccessHydrosilylation vs. Piers–Rubinsztajn: Synthetic Routes to Chemically Cross-Linked Hybrid Phosphazene-Siloxane 3D-Structures
Exploration of new ways for the direct preparation of cross-linked structures is a significant problem in terms of materials for biomedical applications, lithium batteries electrolytes, toughening of thermosets (epoxy, benzoxazine, etc.) with interpenetrating polymer network, etc. The possibility to utilize hydrosilylation and Piers–Rubinsztajn reactions to obtain cross-linked model phosphazene compounds containing eugenoxy and guaiacoxy groups has been studied. It was shown that Piers–Rubinsztajn reaction cannot be used to prepare phosphazene-based tailored polymer matrix due to the catalyst deactivation by nitrogen atoms of main chain units. Utilizing the hydrosilylation reaction, a series of cross-linked materials were obtained, and their properties were studied by NMR spectroscopy, FTIR, DSC, and TGA. Rheological characterizations of the prepared tailored matrices were conducted. This work showed a perspective of using eugenoxy functional groups for the preparation of three-dimensional hybrid phosphazene/siloxane-based materials for various applications.