Muhammad Fakhar U. Zaman
Current Organizations / Institutes
The organizations/institutes from the scholar's latest article
Muhammad Fakhar U. Zaman has a total of 8 co-authors. Here are the top co-authors by number of shared publications:
- Adeel Mubarik
Department of Chemistry, Government College, University Faisalabad, Faisalabad 38000, Pakistan
1 shared publication - Aqsa Kanwal
Department of Chemistry, Government College University, Faisalabad 38000, Pakistan
1 shared publication - Ayesha Malik
Department of Chemistry, Government College University Faisalabad, Faisalabad 38000, Pakistan
1 shared publication - Magdi Elsayed AbdelSalam Zaki
Department of Chemistry Faculty of Science Imam Mohammad Ibn Saud Islamic University (IMSIU) Riyadh Saudi Arabia
1 shared publication - Maria Sohail
Department of Chemistry, Government College University Faisalabad, Faisalabad 38000, Pakistan
1 shared publication - Matloob Ahmad
Department of Chemistry, Government College University, Faisalabad 38000, Pakistan
1 shared publication
Latest Publications
- Open Access
Facile Synthesis of 4-(Methoxycarbonyl)phenyl 5-Arylfuran-2-Carboxylates via Readily Available Pd Catalyst–Their Thermodynamic, Spectroscopic Features and Nonlinear Optical Behavior
In this work, we described the synthesis of 4-(methoxycarbonyl)phenyl 5-bromofuran-2-carboxylate by reacting 5-bromofuroic acid with methylparaben in the incorporation of DCC/DMAP (Steglich esterification) as coupling agents. Later on, we subsequently synthesized a series of 4-(methoxycarbonyl)phenyl 5-aryl furan-2-carboxylates (5a–5e) through Suzuki coupling catalyzed by palladium (0) between 4-(methoxycarbonyl)phenyl 5-bromofuran-2-carboxylate (3) with several substituted arylated and heteroaryl boronic acids (4). DFT calculations were computed to elucidate electronic structural features of synthesized molecules (5a–5e) and to validate these findings by correlating with theoretical and experimental spectroscopic analysis. Furthermore, geometrical optimization, thermodynamic features, as FMO orbitals, MESP maps, NLO behavior and reactivity descriptors, were also determined from the PBE0 D3BJ/def2-TZVP/SMD1,4-dioxane theory level to confirm the structural features of synthesized molecules.
Open AccessFacile Synthesis of 4-(Methoxycarbonyl)phenyl 5-Arylfuran-2-Carboxylates via Readily Available Pd Catalyst–Their Thermodynamic, Spectroscopic Features and Nonlinear Optical Behavior
In this work, we described the synthesis of 4-(methoxycarbonyl)phenyl 5-bromofuran-2-carboxylate by reacting 5-bromofuroic acid with methylparaben in the incorporation of DCC/DMAP (Steglich esterification) as coupling agents. Later on, we subsequently synthesized a series of 4-(methoxycarbonyl)phenyl 5-aryl furan-2-carboxylates (5a–5e) through Suzuki coupling catalyzed by palladium (0) between 4-(methoxycarbonyl)phenyl 5-bromofuran-2-carboxylate (3) with several substituted arylated and heteroaryl boronic acids (4). DFT calculations were computed to elucidate electronic structural features of synthesized molecules (5a–5e) and to validate these findings by correlating with theoretical and experimental spectroscopic analysis. Furthermore, geometrical optimization, thermodynamic features, as FMO orbitals, MESP maps, NLO behavior and reactivity descriptors, were also determined from the PBE0 D3BJ/def2-TZVP/SMD1,4-dioxane theory level to confirm the structural features of synthesized molecules.