Y. Derimian

During the dry season in the Western Africa region the outbreaks of biomass burning aerosols occur on a background of frequent dust storms. In the frame of the African Monsoon Multidisciplinary Analysis (AMMA) campaign we studied optical properties and radiative effects of aerosol mixture and dust observed from January to March 2006 over M'Bour, Senegal. The aerosol burden during the observing period was notably below the average of previous years. However, variability of aerosol sizes and spectral absorption were found as representative. The lidar obtained extinction profiles suggested aerosol transport in two layers (or one elevated layer) for events with two different aerosol types, called aerosol mixture in the paper. Low‐altitude transport was observed for dust. The broadband solar radiative fluxes and aerosol radiative effects were analyzed by combining measurements and simulations. The simulations relied on retrieved column aerosol properties and are products of Aerosol Robotic Network data processing. The 24‐h average aerosol radiative effect yielded cooling at the bottom and at the top of the atmosphere for all the analyzed events of aerosol mixture and dust. The radiative efficiency (radiative effect scaled by optical thickness) at the bottom of the atmosphere and within the aerosol layer appeared to be stronger in case of mixture than in case of pure dust due to enhanced absorption ability of former. We also evaluated the importance of accounting for dust particles nonsphericity for simulating radiative effects. Our test showed that neglecting of aerosol particle shape can result in pronounced bias, up to 10% overestimation of daily average aerosol radiative effect.

Iron is a major component of atmospheric aerosols, influencing the light absorption ability of mineral dust, and an important micronutrient that affects oceanic biogeochemistry. The regional distribution of the iron concentration in dust is important for climate studies; however, this is difficult to obtain since it requires in-situ aerosol sampling or simulation of complex natural processes. Simultaneous studies of aerosol chemical composition and radiometric measurements of aerosol optical properties, which were performed in the Negev desert of Israel continuously for about eight years, suggest a potential for deriving a relationship between chemical composition and light absorption properties, in particular the spectral single-scattering albedo. The two main data sets of the present study were obtained by a sun/sky radiometer and a stacked filter unit sampler that collects particles in coarse and fine size fractions. Analysis of chemical and optical data showed the presence of mixed dust and pollution aerosol in the study area, although their sources appear to be different. Spectral SSA showed an evident response to increased concentrations of iron, black carbon equivalent matter, and their mixing state. A relationship that relates the spectral SSA, the percentage of iron in total particulate mass, and the pollution components was derived. Results calculated, using this relationship, were compared with measurements from dust episodes in several locations around the globe. The comparison showed reasonable agreement between the calculated and the observed iron concentrations, and supported the validity of the suggested approach for the estimation of iron concentrations in mineral dust.

Iron is a major component of atmospheric aerosols, influencing the light absorption ability of mineral dust, and an important micronutrient that affects oceanic biogeochemistry. The regional distribution of the iron concentration in dust is important for climate studies; however, this is difficult to obtain since it requires in-situ aerosol sampling or simulation of complex natural processes. Simultaneous studies of aerosol chemical composition and radiometric measurements of aerosol optical properties, which were performed in the Negev desert of Israel continuously for about eight years, suggest a potential for deriving a relationship between chemical composition and light absorption properties, in particular the spectral single-scattering albedo. The two main data sets of the present study were obtained by a sun/sky radiometer and a stacked filter unit sampler that collects particles in coarse and fine size fractions. Analysis of chemical and optical data showed the presence of mixed dust and pollution aerosol in the study area, although their sources appear to be different. Spectral SSA showed an evident response to increased concentrations of iron, black carbon equivalent matter, and their mixing state. An empirical relationship that relates the spectral SSA, the percentage of iron in total particulate mass, and the pollution components was derived. Results calculated using this relationship were compared with measurements from dust episodes in several locations around the globe. The comparison reveals that dust over the eastern Mediterranean and Saudi Arabia contains less iron than that over Asia and the Sahara desert.