Laura M. Esteves
Current Organizations / Institutes
The organizations/institutes from the scholar's latest article
Research Subjects
Laura M. Esteves has a total of 3 co-authors. Here are the top co-authors by number of shared publications:
- Isabel A. A. C. Esteves
LAQV-REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal
1 shared publication - José Manuel Silva Simões Esperança
LAQV, REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal
1 shared publication - Tiago J. Ferreira
LAQV/REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade NOVA de Lisboa, 2829-516 Almada, Portugal
1 shared publication
Latest Publications
- Open Access
Unveiling the Temperature Influence on the Sorptive Behaviour of ZIF-8 Composite Materials Impregnated with [CnMIM][B(CN)4] Ionic Liquids
Composite sorbent materials (IL@MOF) with a metal-organic framework (MOF) ZIF-8 and [B(CN)4]−-based ionic liquids (ILs) were produced for the first time. Characterization results indicate the successful IL impregnation and conservation of the ZIF-8 crystalline structure and morphology. The data collected from the nitrogen (N2) physisorption at 77 K suggest that these IL@ZIF-8 materials are nonporous as their textural properties, such as BET specific surface area and total pore volume, are negligible. However, CO2, CH4, and N2 adsorption/desorption measurements in the IL@ZIF-8 composites at 303 and 273 K contradict the N2 data at 77 K, given that the obtained isotherms are Type I, typical of (micro)porous materials. Their gas adsorption capacity and ultramicroporous volume are in the same order of magnitude as the pristine microporous ZIF-8. The case study [C6MIM][B(CN)4] IL revealed a high affinity to both CO2 and CH4. This compromised the selectivity performance of its respective composite when compared with pristine ZIF-8. This work highlights the importance of accurate experimental gas adsorption/desorption equilibrium measurements to characterize the adsorption uptake and the porous nature of adsorbent materials.
Open AccessUnveiling the Temperature Influence on the Sorptive Behaviour of ZIF-8 Composite Materials Impregnated with [CnMIM][B(CN)4] Ionic Liquids
Composite sorbent materials (IL@MOF) with a metal-organic framework (MOF) ZIF-8 and [B(CN)4]−-based ionic liquids (ILs) were produced for the first time. Characterization results indicate the successful IL impregnation and conservation of the ZIF-8 crystalline structure and morphology. The data collected from the nitrogen (N2) physisorption at 77 K suggest that these IL@ZIF-8 materials are nonporous as their textural properties, such as BET specific surface area and total pore volume, are negligible. However, CO2, CH4, and N2 adsorption/desorption measurements in the IL@ZIF-8 composites at 303 and 273 K contradict the N2 data at 77 K, given that the obtained isotherms are Type I, typical of (micro)porous materials. Their gas adsorption capacity and ultramicroporous volume are in the same order of magnitude as the pristine microporous ZIF-8. The case study [C6MIM][B(CN)4] IL revealed a high affinity to both CO2 and CH4. This compromised the selectivity performance of its respective composite when compared with pristine ZIF-8. This work highlights the importance of accurate experimental gas adsorption/desorption equilibrium measurements to characterize the adsorption uptake and the porous nature of adsorbent materials.