Jiajia Yang

The performance of remote sensing-based mineral alteration extraction is significantly restricted in the vegetation area. Spectral unmixing is one of the effective methods to address the vegetation problem during mineral alteration extraction. However, the spectral curves of different tree species vary a lot; if multiple tree species are regarded as a whole during the spectral unmixing stage, the proportions of vegetation would be estimated with more errors. The purpose of this study was to verify the effects of dominant tree species classification on spectral unmixing and reconstruction, and to apply the proposed method to the mineral alteration extraction practice. To accomplish this, the Shabaosi gold deposit region in Mohe City, China, with an area of 650 km², was selected as the study area. Firstly, reference spectral curves, GaoFen-1/6 (GF-1/6) satellite imageries, ZiYuan-1F (ZY-1F) satellite imageries, Sentinel-1B satellite synthetic aperture radar (SAR) data, the ALOS digital elevation model (DEM), and sub-compartment dominant tree species data were collected; subsequently, simulated mixed-pixel reflectance images of ZY-1F, reflectance images of GF-1/6, ZY-1F, backscattering data of Sentinel-1B, slope, aspect, and 5484 tree species samples were derived from the collected data. Secondly, to verify the effect of dominant tree species classification on mineral alteration extraction, the reference spectra of pine, oak, goethite, and kaolinite were used to construct a simulated ZY-1F mixed-pixel image, and spectral unmixing and reconstruction experiments were conducted. Thirdly, fourteen independent variables were selected from the derived data, five dominant tree species classification models were trained and tested using tree species samples via the ResNet50 algorithm, and the pine- and birch-dominated parts were segmented from the ZY-1F images. Fourthly, minimum noise fraction (MNF), pixel purity index (PPI), n-dimensional visualizer auto-clustering, and spectral angle mapper (SAM) methods were separately applied to the pine- and birch-dominated parts of ZY-1F images to extract and identify endmembers; subsequently, the fully constrained least squares (FCLS) and linear spectral unmixing (LSU) methods were separately applied to the pine- and birch-dominated parts to estimate endmember proportions and generate spectrally reconstructed ZY-1F images. Fifthly, the pine- and birch-dominated parts of spectrally reconstructed ZY-1F images were mosaiced, and the SAM was utilized to extract mineral alteration in the study area. The result showed that in the spectral unmixing and reconstruction experiment, the spectral reconstruction error declined from 0.0594 (simulated ZY-1F image without segmentation) to 0.0292 and 0.0388 (simulated ZY-1F image that was segmented by pine- and oak-dominated parts), suggesting that dominant tree species classification could improve the accuracy of spectral unmixing and reconstruction and help obtain a more reliable mineral alteration extraction result. In the study area, the tested overall accuracies (OA) and Kappa coefficients of the five dominant tree species classification models were 0.75 ± 0.03 and 0.50 ± 0.05, respectively, suggesting that conducting dominant tree species classification was feasible in dense vegetation areas and could facilitate mineral alteration extraction. After segmenting the ZY-1F image by pine- and birch-dominated parts and spectral reconstruction, eight main types of alteration, including kaolinite, vesuvianite, montmorillonite, rutile, limonite, mica, sphalerite, and quartz, were identified, and nine mineral alteration areas (MA) were delineated accordingly.

Organophosphorus esters (OPEs), widely utilized as flame retardants and plasticizers, are physically incorporated into those products and exhibit semi-volatility, resulting in release throughout their lifecycle. The ocean serves as a significant sink and plays a pivotal role in the global distribution and environmental fate of OPEs. However, the OPEs’ behavior and ecological effects in marine systems are not well understood. This review systematically examines recent advances in the sources, transport pathways, transformation mechanisms, and distributions of OPEs in the marine environment, and it also addresses current research limitations and suggests directions for future work. It is found that OPEs predominantly enter the marine environment through terrestrial input and in situ release; the transportation means include river input, long-range atmospheric transport, air–sea exchange, and oceanic circulation; and the degradation processes of OPEs are recognized as hydrolysis, photodegradation, and biodegradation. The distributions of OPEs in marine environments vary in different media, with their concentrations observed to range from pg m⁻³ to ng m⁻³ in marine air, ng L⁻¹ to hundreds of ng L⁻¹ in seawater, and pg g⁻¹ dw to ng g⁻¹ dw in sediments. The distributions of different species of OPEs are affected by many factors, such as compound properties, environmental conditions, and policy regulations. Comparisons between different regions and different seasons need to be further studied, and predictive models should be developed to better assess ecological risks and exposure pathways of OPEs.