Fulin Li
Current Organizations / Institutes
The organizations/institutes from the scholar's latest article
Research Subjects
Research Interests
Fulin Li has a total of 8 co-authors. Here are the top co-authors by number of shared publications:
- Haitao Xu
School of Environmental Science and Engineering, Nanjing Tech University, Nanjing 210009, China
1 shared publication - Jian Liu
Post-Doctoral Research Center, Shandong Provincial Academician Workstation, Water Resources Research Institute of Shandong Province, Jinan 250014, China
1 shared publication - Jun Lu
School of Environmental Science and Engineering, Nanjing Tech University, Nanjing 210009, China
1 shared publication - Mengfei Yang
College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China
1 shared publication - Qijie Jin
School of Environmental Science and Engineering, Nanjing Tech University, Nanjing 210009, China
1 shared publication - Rutao Liu
School of Environmental Science and Engineering, Shandong University, China-America CRC for Environment & Health, 72# Jimo Binhai Road, Qingdao 266237, China
1 shared publication
Latest Publications
- Open Access
Elucidating Comprehensive Performance Differences of Chlorobenzene Catalytic Oxidation over Cu/W Catalysts: Promotion or Inhibition of Surface Acidity
The development of low-temperature, high-efficiency catalysts for the catalytic elimination of chlorinated volatile organic compounds (CVOCs) remains a significant challenge. Investigating the influence mechanism of catalyst physicochemical properties on chlorobenzene oxidation performance and degradation pathways is particularly important. CuO/WO3 catalysts were developed using a hydrothermal method in this work. The effects of simultaneous or separate addition of ammonium sulphate and ammonium persulphate on the catalytic performance of the CuO/WO3 series catalysts were investigated. The results showed that the introduction of ammonium sulphate alone can facilitate the formation of CuWO4, thereby increasing the chemisorbed oxygen concentration of the CuO/WO3, and making the overall structure of the catalyst looser and increasing the active sites on the catalyst surface. As the optimal catalyst, CuO/WO3-2 exhibited 55.9% of chlorobenzene conversion and 32.9% of CO2 selectivity at 500 °C. Interestingly, although the surface acidity in this work seemed to be one of the reasons for promoting the chlorobenzene oxidation, it could be clearly found that the strong solid acidity of WO3 was actually a key factor in inhibiting the chlorobenzene oxidation. Finally, based on in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) analysis, the primary mechanism for chlorobenzene oxidation on CuO/WO3 catalysts proceeds through a sequential conversion: chlorobenzene was first transformed into phenolic intermediates, followed by quinone compounds, maleates, aldehydes, bidentate carbonates, and ultimately carbonate species.
Open AccessElucidating Comprehensive Performance Differences of Chlorobenzene Catalytic Oxidation over Cu/W Catalysts: Promotion or Inhibition of Surface Acidity
The development of low-temperature, high-efficiency catalysts for the catalytic elimination of chlorinated volatile organic compounds (CVOCs) remains a significant challenge. Investigating the influence mechanism of catalyst physicochemical properties on chlorobenzene oxidation performance and degradation pathways is particularly important. CuO/WO3 catalysts were developed using a hydrothermal method in this work. The effects of simultaneous or separate addition of ammonium sulphate and ammonium persulphate on the catalytic performance of the CuO/WO3 series catalysts were investigated. The results showed that the introduction of ammonium sulphate alone can facilitate the formation of CuWO4, thereby increasing the chemisorbed oxygen concentration of the CuO/WO3, and making the overall structure of the catalyst looser and increasing the active sites on the catalyst surface. As the optimal catalyst, CuO/WO3-2 exhibited 55.9% of chlorobenzene conversion and 32.9% of CO2 selectivity at 500 °C. Interestingly, although the surface acidity in this work seemed to be one of the reasons for promoting the chlorobenzene oxidation, it could be clearly found that the strong solid acidity of WO3 was actually a key factor in inhibiting the chlorobenzene oxidation. Finally, based on in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) analysis, the primary mechanism for chlorobenzene oxidation on CuO/WO3 catalysts proceeds through a sequential conversion: chlorobenzene was first transformed into phenolic intermediates, followed by quinone compounds, maleates, aldehydes, bidentate carbonates, and ultimately carbonate species.