Thidarat Imyen
Current Organizations / Institutes
The organizations/institutes from the scholar's latest article
Thidarat Imyen has a total of 8 co-authors. Here are the top co-authors by number of shared publications:
- Anusith Thanapimmetha
Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, Thailand
1 shared publication - Chih-Feng Huang
National Chung Hsing University 145 Xingda Road, South District
1 shared publication - Khemmathin Lueangwattanapong
Department of Chemical Engineering, Kasetsart University, Bangkok 10900, Thailand
1 shared publication - Maythee Saisriyoot
Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, Thailand
1 shared publication - Nutchapon Chiarasumran
Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, Thailand
1 shared publication - Penjit Srinophakun
Kasetsart University
1 shared publication
Latest Publications
- Open Access
Efficient Binary Solution Adsorption Using Polyurethane Foam Composites Integrated with Zr-MOF and Milled Activated Carbon
Wastewater containing heavy metals and dyes poses serious environmental risks. This study developed a multifunctional composite by coating polyurethane foam (PUF) with milled activated carbon (mAC) and a zirconium-based metal–organic framework (Zr-MOF) for the simultaneous removal of hexavalent chromium (Cr(VI)) and Congo red (CR). The composite was synthesized using a hydrothermal method to grow Zr-MOF on the surface. The SEM analysis confirmed the successful incorporation of mAC and surface modification with Zr-MOF, which resulted in increased surface roughness and porous morphology. XRD and FTIR confirmed the presence of organic ligands connected to the metal structure and the functional groups of each component in composite materials. The optimum conditions for Zr-MOF/mAC/PUF adsorption (nearly 100% removal) in the binary Cr(VI)/CR solution (50 mg/L each) were 25 °C, pH 9, and 150 rpm for 24 h. The Zr-MOF/mAC/PUF was hydrophilic with a swelling ratio of 2.64 g/g. The thermodynamic investigation of Zr-MOF/mAC/PUF resulted in 141.6218 kJ/mol for Cr(VI) and 166.111 kJ/mol for CR of ΔH° (rapid adsorption), negative ΔG° (spontaneous adsorption), a high positive value of ΔS° (disorder structure) and low activation energy (approximately 2.5 to 2.8 kJ/mol). After analyzing the isotherm and reaction kinetics, the possible mechanism could be endothermic physicochemical adsorption and pseudo-second-order kinetic behavior, with electrostatic attraction and diffusion control. The study of 6-times-reused Zr-MOF/mAC/PUF adsorption identified as a decrease of 7.55 percentage point without changing notable morphology and functional groups, based on SEM and FTIR.
Open AccessEfficient Binary Solution Adsorption Using Polyurethane Foam Composites Integrated with Zr-MOF and Milled Activated Carbon
Wastewater containing heavy metals and dyes poses serious environmental risks. This study developed a multifunctional composite by coating polyurethane foam (PUF) with milled activated carbon (mAC) and a zirconium-based metal–organic framework (Zr-MOF) for the simultaneous removal of hexavalent chromium (Cr(VI)) and Congo red (CR). The composite was synthesized using a hydrothermal method to grow Zr-MOF on the surface. The SEM analysis confirmed the successful incorporation of mAC and surface modification with Zr-MOF, which resulted in increased surface roughness and porous morphology. XRD and FTIR confirmed the presence of organic ligands connected to the metal structure and the functional groups of each component in composite materials. The optimum conditions for Zr-MOF/mAC/PUF adsorption (nearly 100% removal) in the binary Cr(VI)/CR solution (50 mg/L each) were 25 °C, pH 9, and 150 rpm for 24 h. The Zr-MOF/mAC/PUF was hydrophilic with a swelling ratio of 2.64 g/g. The thermodynamic investigation of Zr-MOF/mAC/PUF resulted in 141.6218 kJ/mol for Cr(VI) and 166.111 kJ/mol for CR of ΔH° (rapid adsorption), negative ΔG° (spontaneous adsorption), a high positive value of ΔS° (disorder structure) and low activation energy (approximately 2.5 to 2.8 kJ/mol). After analyzing the isotherm and reaction kinetics, the possible mechanism could be endothermic physicochemical adsorption and pseudo-second-order kinetic behavior, with electrostatic attraction and diffusion control. The study of 6-times-reused Zr-MOF/mAC/PUF adsorption identified as a decrease of 7.55 percentage point without changing notable morphology and functional groups, based on SEM and FTIR.