Laura Henrich
Research Subjects
Laura Henrich has a total of 7 co-authors. Here are the top co-authors by number of shared publications:
- Andreas Houben
Institute of Inorganic Chemistry, RWTH Aachen University, D-52056 Aachen, Germany
2 shared publications - Aylin Koldemir
Institut für Anorganische und Analytische Chemie Universität Münster Corrensstrasse 30 48149 Münster Germany
2 shared publications - Egbert Figgemeier
Institute of Power Electronics and Electric Drives (ISEA), Center for Ageing Reliability and Lifetime Prediction of Electrochemical and Power Electronic Systems (CARL) RWTH Aachen University Aachen Germany
2 shared publications - Jan Hempelmann
Institute of Integrated Research, Materials and Structures Laboratory, Institute of Science Tokyo, Yokohama 226-8503, Japan
2 shared publications - Jan van Leusen
Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, D-52074 Aachen, Germany
2 shared publications - Rainer Pöttgen
Institut für Anorganische und Analytische Chemie Universität Münster Münster Germany
2 shared publications
Latest Publications
- Open Access
- 20 August 2026
- Published by MDPI AG in Inorganics
- Vol. 14 (8) , 218
Synthesis, Crystal Structure and Properties of Iron Bisdicyanamide (Fe[N(CN)2]2) and Iron Diammine Bisdicyanamide (Fe[NH3]2[N(CN)2]2)
The phase-pure syntheses of Fe(dca)2 and Fe(dca)2(NH3)2 have enabled comprehensive investigation of their structural and magnetic properties. Fe(dca)2 crystallizes in the orthorhombic space group Pnnm, with Fe2+ ions octahedrally coordinated by six dca ligands, forming a rutile-like 3D network. Temperature-dependent structural analysis reveals minor distortions and a slight unit cell volume contraction (~2.5 Å3) from 300 K to 25 K. Fe(dca)2(NH3)2 crystallizes in the monoclinic space group P21/c, featuring two axial ammonia ligands and dca-bridged Fe2+ ions forming layers. Magnetic susceptibility measurements of Fe(dca)2 reveal a ferrimagnetic transition at TC = 19.1 K, confirmed by SQUID data, Mößbauer spectroscopic measurements and low-temperature neutron diffraction. A magnetic hysteresis at 5 K indicates long-range cooperative magnetic ordering. ATR-IR spectroscopic measurements support the structural models and confirm the chemical composition of both compounds. TGA shows the thermal decomposition of Fe(dca)2.
- 20 August 2026
- Published by MDPI AG in Inorganics
- Vol. 14 (8) , 218
Open AccessSynthesis, Crystal Structure and Properties of Iron Bisdicyanamide (Fe[N(CN)2]2) and Iron Diammine Bisdicyanamide (Fe[NH3]2[N(CN)2]2)
The phase-pure syntheses of Fe(dca)2 and Fe(dca)2(NH3)2 have enabled comprehensive investigation of their structural and magnetic properties. Fe(dca)2 crystallizes in the orthorhombic space group Pnnm, with Fe2+ ions octahedrally coordinated by six dca ligands, forming a rutile-like 3D network. Temperature-dependent structural analysis reveals minor distortions and a slight unit cell volume contraction (~2.5 Å3) from 300 K to 25 K. Fe(dca)2(NH3)2 crystallizes in the monoclinic space group P21/c, featuring two axial ammonia ligands and dca-bridged Fe2+ ions forming layers. Magnetic susceptibility measurements of Fe(dca)2 reveal a ferrimagnetic transition at TC = 19.1 K, confirmed by SQUID data, Mößbauer spectroscopic measurements and low-temperature neutron diffraction. A magnetic hysteresis at 5 K indicates long-range cooperative magnetic ordering. ATR-IR spectroscopic measurements support the structural models and confirm the chemical composition of both compounds. TGA shows the thermal decomposition of Fe(dca)2.
- Open Access
- 24 July 2026
- Published by MDPI AG in Preprints.org
Synthesis, Crystal Structure and Properties of Iron Bisdicyanamide (Fe[N(CN)2]2) and Iron Diammin Bisdicyanamide (Fe[NH3]2[N(CN)2]2)
The phase-pure syntheses of Fe(dca)₂ and Fe(dca)₂(NH₃)₂ have enabled comprehensive investigation of their structural and magnetic properties. Fe(dca)₂ crystallizes in the orthorhombic space group Pnnm, with Fe²⁺ ions octahedrally coordinated by six dca ligands, forming a rutile-like 3D network. Temperature-dependent structural analysis reveals minor distortions and a slight unit cell volume contraction (~2.5 ų) from 300 K to 25 K. Fe(dca)₂(NH₃)₂ crystallizes in the monoclinic space group P2₁/c, featuring two axial ammonia ligands and dca-bridged Fe²⁺ ions forming layers. Magnetic susceptibility measurements of Fe(dca)₂ reveal a ferrimagnetic transition at TC = 19.1 K, con-firmed by SQUID data, Mößbauer spectroscopic measurements and low-temperature neutron diffraction. A magnetic hysteresis at 5 K indicates long-range cooperative magnetic ordering. ATR-IR spectroscopic measurements support the structural models and confirm the chemical composition of both compounds. TGA shows the thermal decomposition of Fe(dca)₂.
- 24 July 2026
- Published by MDPI AG in Preprints.org
Open AccessSynthesis, Crystal Structure and Properties of Iron Bisdicyanamide (Fe[N(CN)2]2) and Iron Diammin Bisdicyanamide (Fe[NH3]2[N(CN)2]2)
The phase-pure syntheses of Fe(dca)₂ and Fe(dca)₂(NH₃)₂ have enabled comprehensive investigation of their structural and magnetic properties. Fe(dca)₂ crystallizes in the orthorhombic space group Pnnm, with Fe²⁺ ions octahedrally coordinated by six dca ligands, forming a rutile-like 3D network. Temperature-dependent structural analysis reveals minor distortions and a slight unit cell volume contraction (~2.5 ų) from 300 K to 25 K. Fe(dca)₂(NH₃)₂ crystallizes in the monoclinic space group P2₁/c, featuring two axial ammonia ligands and dca-bridged Fe²⁺ ions forming layers. Magnetic susceptibility measurements of Fe(dca)₂ reveal a ferrimagnetic transition at TC = 19.1 K, con-firmed by SQUID data, Mößbauer spectroscopic measurements and low-temperature neutron diffraction. A magnetic hysteresis at 5 K indicates long-range cooperative magnetic ordering. ATR-IR spectroscopic measurements support the structural models and confirm the chemical composition of both compounds. TGA shows the thermal decomposition of Fe(dca)₂.