Old materials with new tricks: multifunctional open-framework materials
Top Cited Papers
- 8 February 2007
- journal article
- review article
- Published by Royal Society of Chemistry (RSC) in Chemical Society Reviews
- Vol. 36 (5) , 770-818
Abstract
The literature on open-framework materials has shown numerous examples of porous solids with additional structural, chemical, or physical properties. These materials show promise for applications ranging from sensing, catalysis and separation to multifunctional materials. This critical review provides an up-to-date survey to this new generation of multifunctional open-framework solids. For this, a detailed revision of the different examples so far reported will be presented, classified into five different sections: magnetic, chiral, conducting, optical, and labile open-frameworks for sensing applications. (413 references.)Keywords
This publication has 637 references indexed in Scilit:
- Pentasupertetrahedral Clusters as Building Blocks for a Three‐Dimensional Sulfide SuperlatticeAngewandte Chemie International Edition, 2004
- Tetrahedral Chalcogenide Clusters and Open FrameworksChemistry – A European Journal, 2004
- Luminescent 2D Macrocyclic Networks Based on Starburst Molecules:[{Ag(CF3SO3)}1.5(tdapb)] and[{Ag(NO3)}3(tdapb)]Angewandte Chemie International Edition, 2004
- Three‐Dimensional Frameworks of Gallium Selenide Supertetrahedral ClustersAngewandte Chemie International Edition, 2004
- Open-Framework Nickel Succinate, [Ni7(C4H4O4)6(OH)2(H2O)2]⋅2 H2O: A New Hybrid Material with Three-Dimensional Ni−O−Ni ConnectivityAngewandte Chemie International Edition, 2002
- Nanoporous Structures by Design2000
- An Unusual Open-Framework Cobalt(II) Phosphate with a Channel Structure That Exhibits Structural and Magnetic Transitions2000
- Manganese(III) Formate: A Three-Dimensional Framework That Traps Carbon Dioxide MoleculesAngewandte Chemie International Edition, 1999
- Organically Templated Mixed-Valent TiIII/TiIV Phosphate with an Octahedral- Tetrahedral Open FrameworkAngewandte Chemie International Edition, 1999
- A Novel Open‐Framework Cobalt Phosphate Containing a Tetrahedrally Coordinated Cobalt(II) Center: CoPO4 · 0.5 C2H10N2Angewandte Chemie International Edition, 1994