A Three-Dimensional Coordination Polymer Featuring Effective Ferrimagnetic Hydroxide-Bridged Manganese(II) Chains
Authors:
- 27 May 2005
- journal article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 44 (13) , 4448-4450
Abstract
A three-dimensional coordination polymer, [Mn3(OH)2Na2(3-cnba)6]n (1) (3-Hcnba = 3-cyanobenzoic acid), has been synthesized by the reaction of MnCl2, NaN3, and 3-Hcnba in water. Its crystal structure was determined by single-crystal X-ray diffraction. Magnetic studies show that the complex behaves as a three-dimensional metamagnet built from effective ferrimagnetic Mn(II) chains in which spin moments are linked by interactions in an AF−F−AF (F = ferromagnetic and AF = antiferromagnetic) sequence in the triangular magnetic repeating unit.Keywords
This publication has 19 references indexed in Scilit:
- Synthesis, Nuclear, and Magnetic Structures and Magnetic Properties of[Mn3(OH)2(SO4)2(H2O)2]Chemistry – A European Journal, 2004
- Temperature-controlled hydrothermal synthesis of a 2D ferromagnetic coordination bilayered polymer and a novel 3D network with inorganic Co 3 (OH) 2 ferrimagnetic chainsChemical Communications, 2004
- From Achiral Ligands to Chiral Coordination Polymers: Spontaneous Resolution, Weak Ferromagnetism, and Topological FerrimagnetismJournal of the American Chemical Society, 2004
- A Three-Dimensional Manganese(II) Complex Exhibiting Ferrimagnetic and Metamagnetic BehaviorsInorganic Chemistry, 2003
- A Novel Three‐Dimensional Metal‐Organic Framework Constructed from Two‐Dimensional Interpenetrating Layers Based on Trinuclear Cobalt Clusters: [Co3(btec)(C2O4)(H2O)2]nEuropean Journal of Inorganic Chemistry, 2003
- Ferromagnetic Ordering and Metamagnetism in Malonate Bridged 3D Diamond-like and Honeycomb-like Networks: [Cu(mal)(DMF)]n and {[Cu(mal)(0.5pyz)]·H2O}n (mal = Malonate Dianion, DMF = N,N-dimethylformamide, pyz = Pyrazine)Inorganic Chemistry, 2003
- Synthesis and Characterization of a Tetrahedral and Octahedral Cobalt(II) Alternate Chain ComplexChemistry Letters, 2002
- The first 3-D ferrimagnetic nickel fumarate with an open framework: [Ni 3 (OH) 2 (O 2 C–C 2 H 2 –CO 2 )(H 2 O) 4 ]·2H 2 OChemical Communications, 2002
- Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese(ii) clusters as subunitsElectronic supplementary information (ESI) available: the theoretical expressions of the intra-/inter-molecular magnetic interactions, two-dimensional view of 1, temperature dependence of ac magnetic susceptibility and field dependence of magnetization at 1.97 K. See http://www.rsc.org/suppdata/cc/b1/b106314f/Chemical Communications, 2001
- A 1D coordination polymer of copper(II) with three different bridging anions: synthesis, crystal structure and magnetic behaviourNew Journal of Chemistry, 2001