Junctionless Poly-GeSn Ferroelectric Thin-Film Transistors with Improved Reliability by Interface Engineering for Neuromorphic Computing
Authors:
- 9 December 2019
- journal article
- research article
- Published by American Chemical Society (ACS) in ACS Applied Materials & Interfaces
- Vol. 12 (1) , 1014-1023
Abstract
Ferroelectric HfZrOx (Fe-HZO) with a larger remnant polarization (Pr) is achieved by using a poly-GeSn film as a channel material as compared with a poly-Ge film because of the lower thermal expansion that induces higher stress. Then two-stage interface engineering of junctionless poly-GeSn (Sn of ∼5.1%) ferroelectric thin-film transistors (Fe-TFTs) based on HZO was employed to improve the reliability characteristics. With stage I of NH3 plasma treatment on poly-GeSn and subsequent stage II of Ta2O5 interfacial layer growth, the interfacial quality between Fe-HZO and the poly-GeSn channel is greatly improved, which in turn enhances the reliability performance in terms of negligible Pr degradation up to 106 cycles (±2.7 MV/1 ms) and 96% Pr after a 10 year retention at 85 °C. Furthermore, to emulate the synapse plasticity of the human brain for neuromorphic computing, besides manifesting the capability of short-term plasticity, the devices also exhibit long-term plasticity with the characteristics of analog conductance (G) states of 80 levels (>6 bit), small linearity for potentiation and depression of −0.83 and 0.62, high symmetry, and moderate Gmax/Gmin of 9.6. By employing deep neural network, the neuromorphic system with poly-GeSn Fe-TFT synaptic devices achieves 91.4% pattern recognition accuracy. In addition, the learning algorithm of spike-timing-dependent plasticity based on spiking neural network is demonstrated as well. The results are promising for on-chip training, making it possible to implement neuromorphic computing by monolithic 3D ICs based on poly-GeSn Fe-TFTs.Keywords
Funding Information
- Ministry of Science and Technology, Taiwan (MOST 108-2628-E-007-003-MY3)
- Taiwan Semiconductor Research Institute (JDP108-Y1-010)
This publication has 43 references indexed in Scilit:
- Low temperature growth of high crystallinity GeSn on amorphous layers for advanced optoelectronicsOptical Materials Express, 2013
- Ferroelectricity in Simple Binary ZrO2 and HfO2Nano Letters, 2012
- Amorphous to crystalline transformation in Ta2O5 studied by Raman spectroscopyJournal of Raman Spectroscopy, 2012
- Intrinsic ferroelectric polarization of orthorhombic manganites with-type spin orderPhysical Review B, 2012
- Junctionless Ge p-Channel Metal–Oxide–Semiconductor Field-Effect Transistors Fabricated on Ultrathin Ge-on-Insulator SubstrateApplied Physics Express, 2011
- High-Performance a-IGZO TFT With $\hbox{ZrO}_{2}$ Gate Dielectric Fabricated at Room TemperatureIEEE Electron Device Letters, 2010
- Monte Carlo simulations of imprint behavior in ferroelectricsApplied Physics Letters, 2005
- Direct Comparison of ZrO2 and HfO2 on Ge Substrate in Terms of the Realization of Ultrathin High-κ Gate StacksJapanese Journal of Applied Physics, 2005
- Electrical characteristics of metal–ferroelectric (PbZrxTi1−xO3)–insulator(Ta2O5)–silicon structure for nonvolatile memory applicationsJournal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena, 2000
- Crystallization and Phase Transformation Process in Zirconia: An in situ High‐Temperature X‐ray Diffraction StudyJournal of the American Ceramic Society, 1992