Enantioselective synthesis of α-chiral sulfonates through palladium-catalyzed Tsuji–Trost sulfonylation with sulfur dioxide

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Abstract
We present a novel palladium-catalyzed asymmetric Tsuji–Trost reaction featuring sulfur dioxide insertion through a palladium-sulfonyl intermediate. This method yields α-chiral sulfonates with high efficiency and excellent enantioselectivities.
Funding Information
  • National Natural Science Foundation of China (22301192)
  • West China Hospital, Sichuan University (2024HXBH027)

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