Regioselectivity in the rhodium catalysed 1,4-hydrosilylation of isoprene. Aspects on reaction conditions and ligands
Authors:
- Torbjörn FrejdTFTorbjörn Frejd
- 1 January 2004
- journal article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 689 (2) , 438-443
Abstract
No abstract availableKeywords
This publication has 33 references indexed in Scilit:
- Enhanced catalytic activity in asymmetric hydrosilylation of 1,3-dienes with a soluble palladium catalystTetrahedron: Asymmetry, 2002
- Preparation of a New MOP Ligand Containing a Long-Chain Alkyl Group and Its Use for Palladium-Catalyzed Asymmetric Hydrosilylation of Cyclic 1,3-DienesChemistry Letters, 2001
- Modification of Chiral Monodentate Phosphine Ligands (MOP) for Palladium-Catalyzed Asymmetric Hydrosilylation of Cyclic 1,3-DienesAdvanced Synthesis & Catalysis, 2001
- Asymmetric hydrosilylation of cyclic 1,3-dienes catalyzed by an axially chiral monophosphine-palladium complexTetrahedron Letters, 1996
- Selective addition of hydrosilanes to 1,3-dienes catalyzed by polyamide-supported metal complex catalystsJournal of Organometallic Chemistry, 1995
- Mechanism of a cobalt(III)-catalyzed olefin hydrosilation reaction: direct evidence for a silyl migration pathwayJournal of the American Chemical Society, 1993
- Mechanism of homogeneous hydrosilation of alkenes by (.eta.5-cyclopentadienyl)rhodiumOrganometallics, 1992
- Photochemical Reaction of [(CO)4Co(SiEt3)] with Ethylene: Implications for Cobaltcarbonyl‐Catalyzed Hydrosilation of AlkenesAngewandte Chemie International Edition, 1988
- Photochemical reactions of (.eta.5-pentamethylcyclopentadienyl)dicarbonyliron alkyl and silyl complexes: reversible ethylene insertion into an iron-silicon bond and implications for the mechanism of transition-metal-catalyzed hydrosilation of alkenesJournal of the American Chemical Society, 1986
- Regioselective hydrosilylation of 1,3-dienes catalyzed by phosphine complexes of palladium and rhodiumJournal of Organometallic Chemistry, 1978