Development of a Polyethylene Breathable Packaging Film with Modified Microcrystalline Cellulose for Fresh Products
Open Access
Abstract
In this study, a material based on polyethylene (PE) and microcrystalline cellulose (MC) was developed as a breathable packaging film. Surface functionalization of MC with 3-aminopropyltriethoxysilane (APTES) has been shown to be an efficient option to tailor their properties and increase opportunities for the application of MC on the reinforcement of polymers such as polyethylene (PE). The functionalization of MC with the mentioned silane derivative was achieved using a green method and later used in the development of composites with PE in three percentages (1, 3, and 5%). All the materials were prepared by melt blending and characterized in terms of structural properties (ATR-FTIR and FTIR in transmittance mode, EDX, and SEM), thermal properties (DSC and TGA), thermomechanical properties (DMA), contact angle measurements and permeability to water vapor. The materials demonstrated the potential to be used as breathable film packaging for fresh products.Keywords
All Related Versions
Funding Information
- scope of the project TSSiPRO—technologies for sustainable and smart innovative products (NORTE-01-0145-FEDER-000015, NORTE-08-5369-FSE-000034)
- Portugal 2020 (NORTE-01-0145-FEDER-000015, NORTE-08-5369-FSE-000034)
This publication has 25 references indexed in Scilit:
- Calculation of the degree of crystallinity of HDPE/GNPs nanocomposites by using various experimental techniques: a comparative studyJournal of Materials Science, 2023
- A Review on Surface-Functionalized Cellulosic Nanostructures as Biocompatible Antibacterial MaterialsNano-Micro Letters, 2020
- Characterization of silane treated and untreated natural cellulosic fibre from corn stalk waste as potential reinforcement in polymer compositesCarbohydrate Polymers, 2019
- Designing cellulose nanofiber surface for high density polyethylene reinforcementCellulose, 2018
- Combination of cellulose nanofibers and chain‐end‐functionalized polyethylene and their applications in nanocompositesJournal of Applied Polymer Science, 2017
- Cellulose reinforced polymer composites and nanocomposites: a critical reviewCellulose, 2013
- Modified Atmosphere Packaging Technology of Fresh and Fresh-cut Produce and the Microbial Consequences—A ReviewFood and Bioprocess Technology, 2012
- Silane coupling agents used for natural fiber/polymer composites: A reviewComposites Part A: Applied Science and Manufacturing, 2010
- The use of silane technology in crosslinking polyethylene/wood flour compositesComposites Part A: Applied Science and Manufacturing, 2006
- Determination of the crystallinity of polyethylene/α‐olefin copolymers by thermal analysis: Relationship of the heat of fusion of 100% polyethylene crystal and the densityJournal of Polymer Science Part B: Polymer Physics, 2002