Modeling atrazine molecule dynamics in rhodic ferralsol: calibration and testing of the MACRO 5.2 model

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Abstract
Assessing the risks of pesticide use in the environment, especially in groundwater, requires predicting their movement. Pesticide leaching models represent an accessible and economical method to predict groundwater and surface water pollution and should be calibrated based on experimental data to better understand the dynamics of pesticides in soil and ensure their efficiency. This long-term study explored the ability of the MACRO model to describe water movement and atrazine distribution along the profile of a Rhodic Ferralsol cultivated with corn in western Paraná, Brazil, using data from a drainage lysimeter under high intensity simulated rainfall (150 mm h-1). The soil parameters analyzed in the laboratory were used as pedotransfer functions. The initial simulations showed significant differences, due to the particularities of the model and the complexity of the soil and its pore space, so the tests adjusted the retention curve and the sorption parameters. After final adjustments to the model, the simulated atrazine mass results were evaluated. Calibration of pesticide concentrations required small changes in sorption and degradation rates, and the results were compared to quantities measured at a specific depth. The simulation of atrazine transport was considered acceptable, estimating 0.71, 4.63, and 3.05% of the total mass of atrazine in percolate, runoff and retained in the profile, respectively.

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