Porous coordination polymers with zeolite topologies constructed from 4-connected building units
- 13 April 2006
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- No. 20,p. 2399-2402
Abstract
Two novel 3D coordination polymers, Cd(CTC)(H2O)·(H2PIP)0.5(H2O) (1) with zeolite ABW topology and Cd(CTC)·(HIPA) (2) with zeolite BCT topology, have been synthesized by constructing inorganic and organic 4-connected building units and using the organic bases as templates, and the frameworks of 1 and 2 not only expand the original structures of zeolites ABW and BCT, but also exhibit significant advantages over them in terms of thermal stability, ion exchange and adsorption.Keywords
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