Exploring the magnetic anisotropy and slow relaxation in heterometallic Co II –Ln III –Co II complexes: from synthesis to ab initio insights
- 7 October 2025
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 54 (44) , 16492-16507
Abstract
Isostructural Co II –Ln III –Co II complexes with a pyridine-based bicompartmental ligand were synthesized. Magnetic studies reveal coupling between Co II zero-field splitting and Ln III anisotropy. Tb III and Dy III analogues exhibit zero-field relaxation.Keywords
Funding Information
- National Research Foundation of Korea (RS-2023-00218219, 2022R1A2C100611312)
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