Physicomechanical and Morphological Characterization of Multi-Structured Potassium-Acrylate-Based Hydrogels
Authors:
- José Luis Gradilla-OrozcoJosé Luis Gradilla-Orozco
- José Ángel Hernández-JiménezJosé Ángel Hernández-Jiménez
- Oscar Robles-VásquezOscar Robles-Vásquez
- Jorge Alberto Cortes-OrtegaJorge Alberto Cortes-Ortega
- Maite Renteria-UrquizaMaite Renteria-Urquiza
- María Guadalupe Lomelí-RamírezMaría Guadalupe Lomelí-Ramírez
- José Guillermo Torres RendónJosé Guillermo Torres Rendón
- Rosa María Jiménez-AmezcuaRosa María Jiménez-Amezcua
- Salvador García-EnriquezSalvador García-Enriquez
Open Access
Abstract
In this work, a photo-polymerization route was used to obtain potassium acrylate-co-acrylamide hydrogels with enhanced mechanical properties, well-defined microstructures in the dry state, and unique meso- and macrostructures in the hydrated state. The properties of the hydrogels depended on the concentration of the crosslinking agent. Mechanical properties, swelling capacity, and morphology were analyzed, showing a well-defined transition at a critical concentration of the crosslinker. In terms of morphology, shape-evolving surface patterns appeared at different scales during swelling. These surface structures had a noticeable influence on the mechanical properties. Hydrogels with structures exhibited better mechanical properties compared to unstructured hydrogels. The critical crosslinking concentration reported in this work (using glycerol diacrylate) is a reference point for the future preparation of multistructured acrylic hydrogel with enhanced properties.Keywords
Funding Information
- Mexican Secretariat of Public Education (SEP)
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