Rhodium(I)‐Catalyzed Tertiary Phosphine Directed C−H Arylation: Rapid Construction of Ligand Libraries
Authors:
- 15 May 2017
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 56 (25) , 7233-7237
Abstract
Modification of commercially available monophosphine ligands with either aryl bromides or chlorides by rhodium(I)‐catalyzed, tertiary phosphine directed C−H activation is described. A series of ligand libraries containing mono‐ and diaryl‐substituted groups, having different steric and electronic properties, were obtained in high yields. Based on the outstanding properties of their parent scaffolds, the modified ligands have been found to be powerful in organic reactions.Keywords
Funding Information
- National Natural Science Foundation of China (21402086, 21401099)
- Natural Science Foundation of Jiangsu Province (BK20140594)
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