Vartan Simmonds

Chalcedony forms across a wide area in eastern Iran, particularly in the Sarbisheh district near Birjand city, with notable occurrences in the Qazdez-Bahamarz region. Here, cryptocrystalline quartz is found in hydrothermal veins and veinlets within volcanic rocks hosted by carbonate and intermediate igneous formations. Chalcedony samples of various colours—black, purple, green, blue, lavender, grey, lemon yellow and white—were analysed using diverse techniques. These chalcedony samples display fibrous and granular textures, comprising microcrystalline quartz, cryptocrystalline moganite, and opal-CT and opal-C interlayers. Elements that affect the colouration of chalcedony include iron (producing red and yellow tones), chromium (green), manganese (black, blue and grey patterns), nickel (purple) and copper (also purple). Altered carbonate host rocks are enriched in Fe, Cu, Zn and Cd, with Al and Mn depletion. Stable isotope analyses show δ ¹⁸ O values in agates range from +14.9‰ to +25.5‰, whereas δ ¹⁸ O and δ ¹³ C values in carbonate minerals and chalcedony range from +14.1‰ to +24.8‰ and –5.7‰ to +0.7‰, indicating agate formation from mantle-derived hydrothermal fluids mixed with meteoric waters. Raman spectroscopy detected moganite, α-quartz, goethite, aragonite and illite in agate interlayers. Analyses by field-emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray spectroscopy (EDS) revealed minerals of Fe, Cr, Ni, Ti and Sn. X-ray diffraction confirmed chalcedony, moganite and opal-CT, whereas EPR spectroscopy showed strong magnetic backgrounds from goethite and silicon-vacancy centres formed by radioactive decay of U, Th and their byproducts.

The Qaradagh batholith in northwest Iran mainly comprises granodioritic rocks, which makes more than 50% of the batholith. This lithology is the first intrusive pulse within this batholith and the oldest Tertiary magmatism in the region, though other younger pulses of granite, diorite, quartz-diorite, syenite, quartz-syenite, monzonite, quartz-monzonite, quartz monzodiorite, monzogranite and gabbro intruded the main body. These magmatic rocks have intruded the Upper Cretaceous and Paleogene sedimentary, volcano-sedimentary and igneous rocks.The Qaradagh batholith hosts vein-type and some local stock-work type Cu–Au–Mo mineralization, especially in its central parts, while skarn-type deposits have been formed at its contacts with peripheral carbonate rocks. Its extension towards the north into the neighboring south Armenia (which is part of the South Armenian Block) is known as the Meghri–Ordubad pluton (MOP), which hosts several large porphyry Cu–Mo deposits and other precious and base metal mineralizations. U–Pb geochronology on the zircons separated from the granodioritic unit yielded a weighted 206Pb/238U mean age of 43.81 ± 0.18 (MSWD=1.38) and a Pb*/U concordia age of 44.04 ± 1.00 Ma (MSWD= 24), which correspond to Middle Eocene.Since the Qaradagh batholith and especially its earliest magmatic phase are considered as the oldest plutonic event of the Cenozoic age in northwest Iran, thus this investigation testifies to the fact that intrusive activities of Tertiary in this region has commenced in Middle Eocene, contrary to the opinion of the majority of authors who believe that plutonism in this region occurred during Oligocene.However, this age is much older than the molybdenite Re–Os ages of quartz-sulfide veins hosted by granodioritic rocks (25.19 ± 0.19 to 31.22 ± 0.28 Ma), indicating that mineralization in this batholith is related to another much younger intrusive phase, and even to several phases, as the published ages of molybdenites from various veins and mineralized zones show a large interval. Comparing the obtained age with those from the MOP in southern Armenia indicate that southern part of the MOP is almost coeval with the emplacement of the granodioritic rocks in Qaradagh batholith.The U and Th contents of the zircons range from 17.1 to 1534.0 and from 4.9 to 641.0 ppm, respectively, with Th/U ratios between 0.66 and 5.82 (mean of 1.26), indicating a magmatic source. Meanwhile, the εHf(t) values of the zircons range from 8.7 to 11.1 with the mean of 9.5, which are plotted between the CHUR and the Depleted Mantle evolution lines, indicating a juvenile and homogeneous magmatic source and the predominance of mantle-derived magmas with limited crustal assimilation.

The Siah Kamar porphyry Mo deposit is the newly discovered deposit of this type in the Neo Tethys-related Urumieh–Dokhtar magmatic arc, northwest Iran. Mineralization occurs as stock-work quartz–molybdenite and mono-mineralic molybdenite veinlets within the porphyry quartz-monzonite stock and the country rocks, accompanied by locally scattered later-stage and cross-cutting quartz-chalcopyrite-pyrite veinlets in the trachy-andesite and trachy-basalt country rocks. U–Pb zircon geochronology of the porphyry stock yielded Early Oligocene dates of 32.7 ± 0.4 to 30.9 ± 0.4 Ma (at 2σ level). The Th/U ratios of the zircons range between 0.48 and 0.77, and they possess initial εHf_(t) values of 3.2 to 12.1, which may suggest a dominant mantle source for the magma. Molybdenite separates yielded rhenium contents between ~10 and 41 ppm (average ~26 ppm, n = 4) and slightly younger Re–Os ages compared to the porphyry stock, ranging from 29.1 ± 0.2 to 28.1 ± 0.2 Ma (at 2σ level). The Siah Kamar porphyry Mo deposit is nearly temporally coeval with the Haft Cheshmeh porphyry Cu deposit and the vein-type Cu–Mo–Au mineralization in the Qarachilar area, corresponding to the second porphyry Cu–Mo mineralization epoch in NW Iran. However, it is younger than the majority of the porphyry Cu deposits in the southern Lesser Caucasus and only shows temporal correlation with the Paragachay and first-stage Kadjaran porphyry Cu deposits. Moreover, it is older than all the porphyry Cu–Mo systems across the central and south-eastern parts of the Urumieh–Dokhtar magmatic arc, except the Bondar Hanza deposit, which is nearly coeval with the Siah Kamar porphyry Mo deposit. All these data reveal an old to young trend along the UDMA and the porphyry Cu belt of Iran, further testifying to the diachronous and later closure of the Neo-Tethyan oceanic basin in central and SE Iran.