Annika Ahlberg Tidblad

Online acoustic emission (AE) sensing is a promising nondestructive technique for battery health monitoring. Herein, we report on the ability of AE sensing to differentiate among different chemomechanical degradation events in a TiS2-based model aqueous chemistry. Short and high-frequency AE signals primarily stem from fracture-related degradation of TiS2, such as layer delamination, exfoliation, and cracking. Longer and lower-frequency signals originate from gas bubbles bursting when the cell is cycled outside the water stability window. The two processes demonstrate distinct AE features, allowing them to be semi-quantitatively distinguished from both time and frequency domains. Complementary physicochemical characterizations have been conducted to correlate with the AE observation, including online electrochemical mass spectrometry, operando synchrotron X-ray diffraction, and ex situ scanning electron microscopy. Our work indicates that online AE sensing holds the promise to identify complex chemomechanical degradation processes in rechargeable batteries.

Gas emissions from lithium-ion batteries (LIBs) have been analysed in a large number of experimental studies over the last decade, including investigations of their dependence on the state of charge, cathode chemistry, cell capacity, and many more factors. Unfortunately, the reported data are inconsistent between studies, which can be explained by weaknesses in experimental methodologies, the misinterpretation of data, or simply due to the comparison of datasets that build on different prerequisites. In the present work, the literature on gassing from battery components and battery cells is reported, with a focus on vent gas composition resulting from internal chemical processing in the battery and excluding studies where the gases are combusted after venting. The aim is to identify datasets of high quality that contribute to the advancement of our understanding of gas emissions from LIBs. Gas compositions from different stages in the gassing process are included, starting with the slow formation of gases during normal operation via mild thermal events to a thermal runaway (TR) with extensive gas production. Available published data are used to map gas quantity and composition from LIBs undergoing venting, with or without a TR, and to identify gaps in understanding and the need for further research.

Nowadays, batteries for electric vehicles are expected to have a high energy density, allow fast charging and maintain long cycle life, while providing affordable traction, and complying with stringent safety and environmental standards. Extensive research on novel materials at cell level is hence needed for the continuous improvement of the batteries coupled towards achieving these requirements. This article firstly delves into future developments in electric vehicles from a technology perspective, and the perspective of changing end-user demands. After these end-user needs are defined, their translation into future battery requirements is described. A detailed review of expected material developments follows, to address these dynamic and changing needs. Developments on anodes, cathodes, electrolyte and cell level will be discussed. Finally, a special section will discuss the safety aspects with these increasing end-user demands and how to overcome these issues.

One way to support the development of new safety practices in testing and field failure situations of electric vehicles and their lithium-ion (Li-ion) traction batteries is to conduct studies simulating plausible incident scenarios. This paper focuses on risks and hazards associated with venting of gaseous species formed by thermal decomposition reactions of the electrolyte and electrode materials during thermal runaway of the cell. A test set-up for qualitative and quantitative measurements of both major and minor gas species in the vented emissions from Li-ion batteries is described. The objective of the study is to measure gas emissions in the absence of flames, since gassing can occur without subsequent fire. Test results regarding gas emission rates, total gas emission volumes, and amounts of hydrogen fluoride (HF) and CO₂ formed in inert atmosphere when heating lithium iron phosphate (LFP) and lithium nickel-manganese-cobalt (NMC) dioxide/lithium manganese oxide (LMO) spinel cell stacks are presented and discussed. Important test findings include the large difference in total gas emissions from NMC/LMO cells compared to LFP, 780 L kg⁻¹ battery cells, and 42 L kg⁻¹ battery cells, respectively. However, there was no significant difference in the total amount of HF formed for both cell types, suggesting that LFP releases higher concentrations of HF than NMC/LMO cells.