Yangchuan Cai

In this study, the synergistic tuning mechanism of heat treatment (600, 800, and 1000 °C) and dealloying (40, 60, and 80 °C) on the microstructure and electrocatalytic performance of an FCC + BCC-type CoCrNi0.5Ti0.3V0.2Al0.4 eutectic high-entropy alloy (EHEA) was systematically investigated. The findings indicate that with an increase in heat treatment temperature, there is a gradual increase in grain size and a change in the fraction of the two phases. Notably, heat treatment at 800 °C resulted in an FCC-dominated dual-phase structure with uniformly refined grains. As the dealloying temperature increased, the pore size also increased, leading to a uniform distribution of the internal FCC and BCC phases. The sample subjected to heat treatment at 800 °C and dealloying at 80 °C exhibited an OER overpotential of only 265 mV and a Tafel slope of 67.84 mV/dec, significantly enhancing the electrocatalytic activity and stability of the alloy. This study elucidates the mechanism by which the combination of heat treatment and dealloying processes optimizes the electrocatalytic performance of eutectic high-entropy alloys, providing a novel strategy for the design of non-precious metal electrocatalysts.

To expand the fundamental understanding of eutectic high-entropy alloys (EHEAs), three novel alloy systems—Cr_1.3Ni₂TiAl, CoCr_1.5NiTi_1.5Al_0.2, and V_0.3CoCr_1.2NiTi_1.1Al_0.2—were rationally designed through synergistic phase diagram analysis and thermodynamic parameter calculations. Comprehensive microstructural characterization coupled with mechanical property evaluation revealed that these alloys possess FCC+BCC dual-phase architectures with atypical irregular eutectic morphologies. Notably, progressive microstructural evolution was observed, including amplified grain boundary density and the emergence of brittle nanoscale precipitates. Mechanical testing demonstrated superior compressive yield strengths in these alloys compared to conventional FCC+BCC EHEAs with ordered eutectic structures, albeit accompanied by reduced fracture strain. The Cr_1.3Ni₂TiAl alloy exhibited optimal ductility, with a maximum fracture strain of 15.6%, while V_0.3CoCr_1.2NiTi_1.1Al_0.2 achieved peak strength, with a compressive yield strength of 1389.5 MPa. Multiscale analysis suggests that the enhanced mechanical performance arises from the synergistic interplay between irregular eutectic configurations, expanded grain boundary area, and precipitation strengthening mechanisms.

Eutectic high-entropy alloys (EHEAs) exhibit excellent casting properties and comprehensive mechanical performance, making them suitable for fabricating spatial engineering components using additive manufacturing techniques. However, the rapid solidification process also leads to increased internal stress and reduced structural stability in the components. Therefore, this study focuses on the AlFeCoCrNi_2.1 EHEA as the research subject, utilizing laser additive manufacturing to fabricate components and systematically investigating the influence of heat treatment processes on the microstructure and mechanical properties of the components. The research demonstrates that low-temperature heat treatment (700 °C and below) acts as a stress relief-annealing process for the components. The yield strength decreased from 1003.2 MPa to 742.1 MPa. At 900 °C heat treatment, the constraining effect between recrystallized grains and surrounding grains outweighs the dislocation release effect caused by recrystallization, resulting in an increase in dislocation density. The yield strength remained approximately stable at around 730 MPa. High-temperature heat treatment (1100 °C) alters the orientation of phase structures and fragments the two-phase structure through recrystallization, leading to generally stable mechanical properties of the components. The yield strength of the cast components further decreased to 582.6 MPa, while that of the LMD-fabricated parts retained stability at approximately 730 MPa.

This feature article summarizes the principles, fabrication techniques, and recent advancements of nanoporous high-entropy alloys and metallic glasses for application in electrochemical water splitting.

In this current investigation, the impact of Nickel (Ni) on the microstructural attributes and properties of a cold-rolled 316 L sheet was examined. The microstructure and phase configuration of austenitic stainless steels, specifically 316 L and 316LNi, were meticulously characterized through the utilization of metallography, X-ray Diffraction (XRD), and Electron Backscatter Diffraction (EBSD) techniques. Subsequent assessments were conducted to evaluate magnetic characteristics, microhardness, and tensile properties. The phase structure of both austenitic stainless steels conforms to a Face-Centered Cubic (FCC) crystal lattice, whereby the grain content oriented along the (110) plane progressively escalates with augmenting degrees of cold rolling. The magnetic conductivity of these austenitic stainless steels satisfactorily adheres to established standards. The incorporation of Nickel (Ni) into the alloy composition enhances the cold deformation capacity of 316 L stainless steel. However, substantial plastic deformation yields heightened dislocation density, thereby promoting enlarged grain dimensions upon solution treatment. Throughout subsequent cold rolling deformation sequences, the augmented grain size observed in 316LNi stainless steel leads to a reduction in dislocation density within the equivalently ordered cold-rolled plate. Simultaneously, this augmented grain size engenders a decline in grain boundary content coupled with an augmentation in twin content. Consequently, the interplay of grain coarsening, diminished dislocation density, and twin-induced softening collectively bestows upon 316LNi stainless steel a lower tensile strength compared to 316 L stainless steel, albeit accompanied by heightened plasticity.

The long, straight grain boundary of the high-entropy alloy (HEA) produced via laser melting deposition (LMD) is prone to cracking due to unidirectional scanning (single wall). To enhance the competitive growth of columnar grains and improve the overall performance of the alloy, a vertical cross scanning method was employed to fabricate FeCoCrNi HEA (bulk). The influence of grain orientation on the microstructure and mechanical properties of FeCoCrNi-LMD was systematically investigated. Microhardness tests and tensile tests were conducted to assess the mechanical property differences between the single-wall and bulk samples. This study shows that using a single scanning strategy results in monolayer wall grains sized at 129.40 μm, with a max texture strength of 21.29. Employing orthogonal scanning yields 61.15 μm block-like grains with a max texture strength of 11.12. Dislocation densities are 1.084 × 10¹² m⁻² and 1.156 × 10¹² m⁻², with average Schmid factors of 0.471 and 0.416. In comparison to the FeCoCrNi-LMD single wall, the bulk material produced through cross-layer orthogonal scanning exhibited reduced residual stress, weakened anisotropy, and improved mechanical properties. These findings are expected to enhance the potential applications of FeCoCrNi-LMD in various industries.

The friction spot welding (FSpW) method was used to weld 2198-T8 Al-Li alloy at rotational speeds of 500 rpm, 1000 rpm, and 1800 rpm. It was shown that the grains in the FSpW joints were transformed from “pancake” grains to fine equiaxed grains by the heat input of welding, and the reinforcing phases of S’ and θ were all redissolved into the Al matrix. This leads to a decrease in the tensile strength of the FsPW joint compared to the base material and a change in the fracture mechanism from mixed ductile-brittle fracture to ductile fracture. Finally, the tensile properties of the welded joint depend on the size and morphology of the grains and their dislocation density. At the rotational speed setting of 1000 rpm in this paper, the mechanical properties of welded joints consisting of fine and uniformly distributed equiaxed grains are best. Therefore, a reasonable set of the rotational speed of FSpW can improve the mechanical properties of the welded joints of 2198-T8 Al-Li alloy.

In the present study, the laser melting deposition (LMD) technology was adopted to fabricate FeCoCrNiMn and FeCoCrNiMnAl_0.75 high entropy alloys (HEAs). Then, laser welding method was used to join the HEAs in forms of similar (FeCoCrNiMnAl/FeCoCrNiMnAl and FeCoCrNiMnAl0.75/FeCoCrNiMnAl0.75) and dissimilar (FeCoCrNiMnAl0/FeCoCrNiMnAl0.75) combinations, respectively. Ultra-depth field microscope and electron backscatter diffraction detection were used to observe the macro-morphology and microstructure, respectively. It was found that the width of the weld bead and heat-affected zone with higher aluminium content was larger. In both base metals and welded joints, aluminium promoted the face-centered cubic (FCC) phase transfer into body-centered cubic (BCC), significantly refined the grain and the dislocation density of HEA is also increased, which increased strength and hardness, and decreased ductility. Highlights The FeCoCrNiMn/FeCoCrNiMn, FeCoCrNiMn/FeCoCrNiMnAl_0.75, FeCoCrNiMnAl_0.75/FeCoCrNiMnAl_0.75 joints were produced by laser welding. The widths of the weld bead and heat-affected zone increased with higher Al content. The weld bead with higher content of Al exhibited higher strength and hardness, but lower ductility.