Xintao Li

Ultrahigh-speed continuous casting is a critical element in achieving high-efficiency continuous casting. In the present work, a three-dimensional model of a 160 mm × 160 mm billet ultrahigh-speed continuous casting mold was developed for use in studying the influences of different casting parameters on molten steel flow. The results showed that the flow pattern in the mold was not associated with its casting speeds, submerged entry nozzle (SEN) immersion depths, or inner diameters. Variation in casting speeds significantly affected the liquid level of the steel–slag interface. Its liquid level fluctuation was reasonable at an SEN immersion depth of 80 mm. Its impact depth reached the shallowest point, which was conducive to upward movement within high-velocity and high-temperature regions, and accelerated the floating of non-metallic inclusions. Expanding the inner diameter of the SEN could effectively weaken the initial kinetic energy of the jet. However, it may cause a deeper impact depth and a degree of upward movement in the raceway, which exhibited the shallowest impact depth in the jet and the most reasonable behavior of molten steel at a liquid level for which the inner diameter of the SEN was 40 mm.

A three‐dimensional model of fluid flow, heat transfer, solidification, and inclusion motion in billet mold at ultrahigh casting speed under electromagnetic field is developed. The low Reynolds number k–ε model coupled with electromagnetic model and Lagrangian discrete phase model is used to investigate the flow field, temperature field, solidification, and inclusions transport under different current intensities. The results show that mold electromagnetic stirring (M‐EMS) significantly alters the flow pattern of molten steel. The impact depth of the molten steel decreases as the stirring current intensity increases, and the horizontal swirl intensities of the molten steel increase with the stirring current intensity. As the current intensity increases from 500 to 700 A, the impact depth decreases from 0.637 to 0.575 m and the maximum tangential velocity increases from 0.477 to 0.898 m s⁻¹. When the stirring current is intense, the flow of molten steel near the mold exit is reversed, and the molten steel flows asymmetrically and unsteadily. The M‐EMS effectively improves the transverse heat transfer of the molten steel in the mold, contributing to the dissipation of the molten steel superheat and the growth of the solidified shell. In addition, the removal ratio of the inclusions is improved significantly.

To study the evolution of non-metallic inclusions in 27SiMn steel, the 27SiMn steel produced using the LD-LF-CCM process was sampled in various stages in a steel factory. The evolutionary behavior of inclusion in various processes was systematically analyzed by scanning electron microscopy (SEM-EDS), and the total oxygen content and nitrogen content in 27SiMn steel were measured at various production steps. On the basis of the calcium treatment for 27SiMn steel, the equilibrium reactions for Ca-Al were calculated according to the thermodynamic equilibrium model. The results showed that the types of inclusions at the start of LF stations are mainly Al₂O₃-FeO and MnS-Al₂O₃. Before calcium treatment, the inclusions are mostly calcium aluminate and CaO-MgO-Al₂O₃. Compared with the process after soft blowing, the number density of inclusions in tundish increased by 77.88%, possibly due to secondary oxidation. From the soft blowing process to the continuous casting round billet, the inclusions translate into spherical CaO-MgO-Al₂O₃-SiO₂, and a large number of CaS were observed. One part of the CaS precipitated separately, the other part was semi-wrapped with the composite inclusions. At the same time, calcium treatment increases the number density, mean diameter, and the area fraction of inclusions. The mass fraction of T.O. (total oxygen content) increased significantly after soft blowing, and the N content increased greatly from station to tundish. The change trend of N content in steel was basically consistent with that of T.O. content. It was necessary to prevent the secondary oxidation of molten steel during calcium treatment and the casting process. When the liquidus temperature of liquid steel is 1873 K, w[Al] = 0.022%, and w[Ca] in steel is controlled between 1.085 × 10⁻⁶ and 4.986 × 10⁻⁶, the Al₂O₃ inclusion degeneration effect is good.

Electric arc furnace dust (EAFD) presents a contamination hazard due to its heavy metal leachability. The traditional disposal methods of landfill or stacking not only pose a threat to the environment but also waste metal resources. This paper adopted vacuum carbothermic reduction to dispose of EAFD and the zinc metal could be obtained as a product. The reduction ratios of the EAFD were carried out under various reaction temperatures and times at 20 Pa. Furthermore, the kinetics of the reduction process was also studied. The reduction ratio of the reaction process can be facilitated through increasing the temperature or lengthening the time and can reach up to 99.6% under the condition of 1373 K with 60 min. The zinc ferrite and zinc oxide were reduced first and then iron oxide reduction occurred. The reduction process could be divided into three stages: Stage 1 involved the direct reduction of zinc ferrite and zinc oxide, and the control step was the phase boundary reaction with the apparent activation energy of 48.54 kJ/mol; Stage 2 involved the reduction of zinc oxide and iron oxide, and the control step was also the phase boundary reaction with the apparent activation energy of 56.27 kJ/mol; Stage 3 involved the escape of gas phase products and the control step was diffusion with the apparent activation energy of 105.3 kJ/mol.

Ultrahigh‐speed casting is the most remarkable feature of billet high‐efficiency continuous casting. The transient fluid flow, heat transfer, and solidification behavior under different casting speeds, submerged entry nozzle (SEN) parameters, and mold electromagnetic stirring (M‐EMS) are investigated using a 3D transient mathematical model. The results show that a typical roll flow pattern is generated for all casting speeds, while a third small recirculation zone developed near the solidified shell at the casting speed of 6.0 m min⁻¹. When the casting speed increases, the impact depth of the molten steel increases from 0.748 to 0.844 m, the velocity and level fluctuation at the steel/slag interface increases, the high‐temperature zone moves downward, and the shell thickness is reduced from 16.2 to 11.1 mm. As the SEN inner diameter and immersion depth increases, the impact depth increases, the velocity and level fluctuation at the steel/slag interface decreases, and the shell thickness at the mold exit is ≈11.0 mm. When the SEN immersion depth and inner diameter are 120 and 40 mm, respectively, the flow and temperature fields in the mold are the most appropriate. In addition, the M‐EMS have a great effect on the fluid flow and heat transfer behavior.