Xin Liu

Karst areas are characterized by poor surface water storage capacity, which makes them more sensitive to drought events. To enhance drought resistance in karst landform areas, this study focuses on a typical region in the Yun–Gui Plateau of China, specifically Guizhou Province, which includes 88 counties and districts. According to the regional characteristics, the index system for the assessment of drought resistance and disaster reduction ability was constructed to include 17 indexes in five evaluation layers, including natural conditions, water conservancy project, economic strength, water usage and water conservation level, and emergency support capacity. A comprehensive evaluation was conducted using a fuzzy evaluation model. Furthermore, the drought resistance and disaster reduction capacity of Guizhou Province was evaluated according to the fulfillment of water supply and water demand under the frequency of 75%, 90%, 95%, 97%, and 99% drought frequency inflow in each research unit. This assessment serves to define the spatial distribution pattern of drought resistance and disaster reduction capability within the province. Additionally, according to the results of the supply–demand balance method, the weight of the main influencing factors in regards to drought resistance and disaster reduction ability was optimized and adjusted to identify the key restricting factors of drought resistance and disaster reduction ability. This research data was obtained from the National Disaster Survey database, aiming to provide practical guidance for drought resistance in Guizhou Province. The research findings show that: (1) the distribution characteristics of drought resistance and disaster reduction capability in Guizhou Province are the most significant in Guiyang City, Liupanshui City, and Anshun City in the southwest, with higher drought resistance and disaster reduction ability found in central region, and lower drought resistance primarily identified in the eastern part of Qiandongnan Prefecture, Tongren City, the southern part of Qiannan Prefecture, and the northwestern part of Bijie City; (2) there are six main influencing factors in the three criterion layers, i.e., hydraulic engineering, emergency drought resistance, and social economy, and their contribution rates are as follows: surface water supply and storage rate > average number of soil moisture monitoring stations > per capita GDP > agricultural emergency drought irrigation rate > regional water supply assurance rate > cultivated land effective irrigation rate.

In order to explore the effects of the composition and structure of soil’s dissolved organic matter (DOM) and its electron transfer capacity (ETC) on the bioavailability of the potential toxic elements chromium (Cr), lead (Pb) and cadmium (Cd) after the application of decomposed pig manure organic fertilizer, three-dimensional fluorescence spectroscopy (3D-EEMs), parallel factor analysis (PARAFAC) and electrochemical methods were used to analyze the composition characteristics of DOM in soil solution and the changes in the ETC, and the dynamic relationship between the relative content of DOM, ETC and various forms of potential toxic elements was explored by means of a Pearson correlation analysis and redundancy analysis (RDA). Among them, Cr, Pb and Cd were the elements with significant biological toxicity in farmland soil. The results indicated the following: (1) The soil DOM before and after returning the organic fertilizer to the field contained four components: UV and UVA humic-like (C1), tryptophan-like and UVA humic-like (C2), Exogenous and visible humic-like (C3) and tyrosine-like (C4). Humus-like was the main component. (2) After applying organic fertilizer, the relative contents of the DOM humus and tyrosine-like components in the soil increased by 8% and 8.73%, respectively. In this process, the DOM electron-accepting capacity (EAC) and electron-donating capacity (EDC) increased by 39.98% and 27.91%, respectively. (3) The humic-like fraction showed a highly significant positive correlation with ETC (p < 0.01), and the tyrosine-like fraction showed a significant negative correlation with ETC (p < 0.05). (4) The humus-like substance and ETC were positively correlated with the total amount, reducible state and oxidizable state of the potential toxic elements and negatively correlated with the weak acid extracted state and residue state; this showed that the humus-like components and ETC were more helpful for the transformation of the weak acid extracted state to the reducible state, oxidizable state and residue state in the interaction between the DOM components and Cr, Pb and Cd. In summary, the reasonable application of organic fertilizer could improve the relative content of DOM and ETC in soil, inhibit the biological toxicity of potential toxic elements in soil and provide a theoretical basis for the safe use of organic fertilizer.

In order to investigate the effects of water-fertilizer-air-coupling drip irrigation on soil health status, including soil aeration (SA), enzyme activity (EA) and microbial biomass (MB), and its response relationship, this glasshouse experiment was conducted using tomato as the test crop, and we designed two fertilization gradients of 135 and 180 kg N·ha⁻¹, two irrigation levels of 0.6-fold and 1.0-fold of the crop-pan coefficient, and two aeration treatments of 5 and 15 mg·L⁻¹ for the three-factor and two-level completely randomized block experiment. The effects of soil dissolved-oxygen concentration, oxygen diffusion rate, soil respiration rate, soil urease, catalase, phosphatase activities and soil microbial biomass were systematically monitored and analyzed in the middle and at the end of crop growth. A structural equation model was used to comprehensively analyze the response relationship among relevant influencing factors. The results showed that coupled drip irrigation increased the soil’s dissolved oxygen, oxygen diffusion rate and soil respiration rate by 14.05%, 30.14% and 53.74%, respectively. Soil urease, catalase and phosphatase activities increased by 22.83%, 93.01% and 61.35%, respectively. The biomass of bacteria, fungi and actinomycetes increased by 49.06%, 50.18% and 20.39%, respectively. The results of a structural equation model analysis showed that water-fertilizer-air-coupling drip irrigation could effectively improve soil health status, and the descending order of influence was MB > EA > SA. This study provides scientific knowledge to reveal the improvement of soil health status by water-fertilizer-air-coupling drip irrigation.