Anastasiya O. Brovko
Current Organizations / Institutes
The organizations/institutes from the scholar's latest article
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Research Interests
Anastasiya O. Brovko has a total of 5 co-authors. Here are the top co-authors by number of shared publications:
- Gennadiy Alexandrovich Kostin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Avenue, Novosibirsk 630090, Russian Federation
3 shared publications - Natalia V. Kuratieva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Avenue, 630090 Novosibirsk, Russia
3 shared publications - Dmitriy G. Sheven
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Avenue, 630090 Novosibirsk, Russia
2 shared publications - Ivan A. Yakovlev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Avenue, 630090 Novosibirsk, Russia
2 shared publications - Denis P. Pishchur
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
1 shared publication
Latest Publications
- Open Access
- 10 July 2026
- Published by MDPI AG in International Journal of Molecular Sciences
- Vol. 27 (14) , 6172
Ruthenium Nitrosyl Complexes with Bidentate Heterocycles and Chloride Ligands: Synthesis and Photorelease of NO
A set of new coordination compounds of the formula [RuNO(L)Cl3], with L representing the bidentate ligands bipyrimidine (bpym), bipyridine (bpy), or phenanthroline (phen), was prepared and fully characterized. For the isomeric species fac-[RuNO(bpym)Cl3] (1), fac-[RuNO(phen)Cl3] (2), mer-[RuNO(phen)Cl3] (3), fac-[RuNO(bpy)Cl3] (4), and mer-[RuNO(bpy)Cl3] (5), an evaluation of the photoresponse in DMSO was performed under excitation with 450 nm using a continuous-flow arrangement that enabled the simultaneous acquisition of IR and UV-Vis spectral data. Quantum yields for photoinduced release of NO were determined as follows: 5.4 ± 0.5% for fac-[RuNO(bpym)Cl3] (1); 0.8 ± 0.1% for fac-[RuNO(phen)Cl3] (2); 0.6 ± 0.1% for mer-[RuNO(phen)Cl3] (3); 3.7 ± 0.1% for fac-[RuNO(bpy)Cl3] (4); 2.1 ± 0.1% for mer-[RuNO(bpy)Cl3] (5). The product of the photolysis of compound 5 in acetonitrile solution was isolated and structurally characterized as mer-[Ru(CH3CN)(bpy)Cl3] (6). Taking into account the presence of typical DNA intercalating ligands, the complexes can be potentially exploited as photoNORMs.
- 10 July 2026
- Published by MDPI AG in International Journal of Molecular Sciences
- Vol. 27 (14) , 6172
Open AccessRuthenium Nitrosyl Complexes with Bidentate Heterocycles and Chloride Ligands: Synthesis and Photorelease of NO
A set of new coordination compounds of the formula [RuNO(L)Cl3], with L representing the bidentate ligands bipyrimidine (bpym), bipyridine (bpy), or phenanthroline (phen), was prepared and fully characterized. For the isomeric species fac-[RuNO(bpym)Cl3] (1), fac-[RuNO(phen)Cl3] (2), mer-[RuNO(phen)Cl3] (3), fac-[RuNO(bpy)Cl3] (4), and mer-[RuNO(bpy)Cl3] (5), an evaluation of the photoresponse in DMSO was performed under excitation with 450 nm using a continuous-flow arrangement that enabled the simultaneous acquisition of IR and UV-Vis spectral data. Quantum yields for photoinduced release of NO were determined as follows: 5.4 ± 0.5% for fac-[RuNO(bpym)Cl3] (1); 0.8 ± 0.1% for fac-[RuNO(phen)Cl3] (2); 0.6 ± 0.1% for mer-[RuNO(phen)Cl3] (3); 3.7 ± 0.1% for fac-[RuNO(bpy)Cl3] (4); 2.1 ± 0.1% for mer-[RuNO(bpy)Cl3] (5). The product of the photolysis of compound 5 in acetonitrile solution was isolated and structurally characterized as mer-[Ru(CH3CN)(bpy)Cl3] (6). Taking into account the presence of typical DNA intercalating ligands, the complexes can be potentially exploited as photoNORMs.
- Open Access
- 2 July 2026
- Published by MDPI AG in Preprints.org
Ruthenium Nitrosyl Complexes with Bidentate Heterocycles and Chloride Ligands: Synthesis and Photorelease of NO
A series of novel complexes with the general formula [RuNO(L)Cl3], where L is a bidentate ligand (bpym, bpy, phen), was synthesized and characterized. The photochemical activity of fac-[RuNO(bpym)Cl3] (1), fac-[RuNO(phen)Cl3] (2), mer-[RuNO(phen)Cl3] (3), fac-[RuNO(bpy)Cl3] (4), mer-[RuNO(bpy)Cl3] (5) in DMSO was quantified under 450 nm irradiation using a flow-through system, allowing simultaneous IR and UV-Vis spectral monitoring. Quantum yields for photoinduced release of NO were determined as follows: 5.4 ± 0.5 % for fac-[RuNO(bpym)Cl3] (1); 0.8±0.1 % for fac-[RuNO(phen)Cl3] (2); 0.6±0.1 % for mer-[RuNO(phen)Cl3] (3); 3.7±0.1 % for fac-[RuNO(bpy)Cl3] (4); 2.1±0.1 % for mer-[RuNO(bpy)Cl3] (5). The product of photolysis of compound 5 in acetonitrile solution was isolated and structurally characterized as mer-[Ru(CH3CN)(bpy)Cl3] (6). Taking into account the presence of typical DNA intercalating ligands the complexes can be potentially exploited as photoNORMs.
- 2 July 2026
- Published by MDPI AG in Preprints.org
Open AccessRuthenium Nitrosyl Complexes with Bidentate Heterocycles and Chloride Ligands: Synthesis and Photorelease of NO
A series of novel complexes with the general formula [RuNO(L)Cl3], where L is a bidentate ligand (bpym, bpy, phen), was synthesized and characterized. The photochemical activity of fac-[RuNO(bpym)Cl3] (1), fac-[RuNO(phen)Cl3] (2), mer-[RuNO(phen)Cl3] (3), fac-[RuNO(bpy)Cl3] (4), mer-[RuNO(bpy)Cl3] (5) in DMSO was quantified under 450 nm irradiation using a flow-through system, allowing simultaneous IR and UV-Vis spectral monitoring. Quantum yields for photoinduced release of NO were determined as follows: 5.4 ± 0.5 % for fac-[RuNO(bpym)Cl3] (1); 0.8±0.1 % for fac-[RuNO(phen)Cl3] (2); 0.6±0.1 % for mer-[RuNO(phen)Cl3] (3); 3.7±0.1 % for fac-[RuNO(bpy)Cl3] (4); 2.1±0.1 % for mer-[RuNO(bpy)Cl3] (5). The product of photolysis of compound 5 in acetonitrile solution was isolated and structurally characterized as mer-[Ru(CH3CN)(bpy)Cl3] (6). Taking into account the presence of typical DNA intercalating ligands the complexes can be potentially exploited as photoNORMs.
- Open Access
Heteroleptic Complexes of Ruthenium Nitrosyl with Pyridine and Bypiridine—Synthesis and Photoisomerization
The reaction of [RuNO(Py)2Cl2OH] with bipyridine in water–ethanol media results in trans-(NO, OH)-[RuNO(Py)(Bpy)ClOH]+ with an acceptable yield (60–70%) as hexafluorophosphate salt. Further treatment of the hydroxy-complex with concentrated HF quantitatively leads to trans-(NO, F)-[RuNO(Py)(Bpy)ClF]+. Despite the chirality of both coordination spheres, the hexafluorophosphate salts crystallized as racemates. A NO-linkage isomerism study of the obtained complexes was performed at 80 K with different excitation wavelengths (405, 450, 488 nm). The most favorable wavelengths for the MS1 isomer (Ru-ON) formation were 405 and 450 nm, where the linkage isomer populations were 17% and 1% for [RuNO(Py)(Bpy)ClOH]PF6 and [RuNO(Py)(Bpy)ClF]PF6. The shift of the excitation wavelength to the green (488 nm) sharply decreased the MS1 population. The IR-spectral signatures of MS1 were registered. Reverse-transformation Ru-ON (MS1)-Ru-NO (GS) was investigated for [RuNO(Py)(Bpy)ClOH]PF6 using IR and DSC techniques that made it possible to determine the kinetic parameters (Ea and k0) and decay temperature.
Open AccessHeteroleptic Complexes of Ruthenium Nitrosyl with Pyridine and Bypiridine—Synthesis and Photoisomerization
The reaction of [RuNO(Py)2Cl2OH] with bipyridine in water–ethanol media results in trans-(NO, OH)-[RuNO(Py)(Bpy)ClOH]+ with an acceptable yield (60–70%) as hexafluorophosphate salt. Further treatment of the hydroxy-complex with concentrated HF quantitatively leads to trans-(NO, F)-[RuNO(Py)(Bpy)ClF]+. Despite the chirality of both coordination spheres, the hexafluorophosphate salts crystallized as racemates. A NO-linkage isomerism study of the obtained complexes was performed at 80 K with different excitation wavelengths (405, 450, 488 nm). The most favorable wavelengths for the MS1 isomer (Ru-ON) formation were 405 and 450 nm, where the linkage isomer populations were 17% and 1% for [RuNO(Py)(Bpy)ClOH]PF6 and [RuNO(Py)(Bpy)ClF]PF6. The shift of the excitation wavelength to the green (488 nm) sharply decreased the MS1 population. The IR-spectral signatures of MS1 were registered. Reverse-transformation Ru-ON (MS1)-Ru-NO (GS) was investigated for [RuNO(Py)(Bpy)ClOH]PF6 using IR and DSC techniques that made it possible to determine the kinetic parameters (Ea and k0) and decay temperature.