Lilja Tryggvadottir

Currently, there are several deep drill geothermal projects that aim to discharge superheated or supercritical geothermal fluid for sustainable power production. In geothermal power utilisation, the well casing steel and surface equipment is susceptible to corrosion due to corrosive species in the geothermal fluid. The temperature and the phase state of the fluid greatly affect the extent and the forms of corrosion that can occur. To mitigate corrosion damage in the casing and surface equipment, the recently developed production method Extra High-speed Laser Application (EHLA) cladding is proposed as a solution. To simulate application of carbon steel and EHLA clads in superheated geothermal wells, the materials were tested in a superheated steam containing CO₂ and H₂S at 450 °C temperature and 150 barG pressure. Microstructural and chemical analysis was performed with SEM, EDX and XRD, and corrosion rate was analysed with the weight loss method. The carbon steel was prone to corrosion with a double corrosion layer but the corrosion of the EHLA clads was insignificant. The results show that the EHLA clads tested have good corrosion resistance in the test environment, and the study can aid in the selection of casing and clad materials for future deep geothermal wells. Furthermore, this study shows that the EHLA clads increase the variety of corrosion mitigation solutions for future geothermal projects.

Carbon steel casing material in high-temperature deep geothermal wells can be prone to severe corrosion and premature failure due to the oxidation capacity of H₂O, H₂S, CO₂, and more corrosive species in geothermal fluid. Due to the higher temperature and pressure and phase state of fluid in high-temperature deep geothermal wells, the rate and extent of corrosion can be expected to be different than in low-temperature geothermal wells. To reduce the extent of corrosion damage and corrosion rate, and increase the lifetime of geothermal wells, one mitigation method is to clad the internal surface of the geothermal casing with a more noble, corrosion-resistant material. Conventional cladding, however, has been an expensive and time-consuming process up to the current date, but recently, a more economical and productive method has been established, i.e., EHLA cladding. In this study, a 14-day corrosion performance test was conducted on stainless steel and nickel-based alloy clads on a carbon steel substrate in a 262 °C and 95 bar geothermal well in the Hellisheidi geothermal field (SW Iceland). Samples were partially or fully cladded, and some samples were stressed to investigate the clads’ susceptibility to general corrosion and stress corrosion cracking, as well as the substrate’s vulnerability to galvanic corrosion. Corrosion analysis of pure carbon steel substrate was also investigated for comparison. Samples were microstructurally analysed with SEM, and chemical analysis was performed with EDX. The results indicated that the clad materials have good corrosion resistance in the geothermal environment tested, suggesting that EHLA cladding is a more feasible option for strengthening the corrosion resistance of geothermal casing and equipment.