Qingqiao Zeng
Research Subjects
Qingqiao Zeng has a total of 5 co-authors. Here are the top co-authors by number of shared publications:
- Qingchun Meng
PetroChina Huabei Oilfield Company, Renqiu 062552, China
1 shared publication - Xi Huang
PetroChina Huabei Oilfield Company, Renqiu 062552, China
1 shared publication - Xusheng Wang
Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
1 shared publication - Yong Guo
Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
1 shared publication - Yuying Li
PetroChina Huabei Oilfield Company, Renqiu 062552, China
1 shared publication
Latest Publications
- Open Access
Study on the Influence of Composition Differences in Heavy Oil Components on In-Situ Combustion Coking Performance
This study investigates coke formation, structure, and combustion behaviors in paraffin-based Menggulin and naphthenic-based Xinjiang heavy oils under simulated in-situ combustion (ISC) conditions (350 °C, 450 °C), utilizing GC-MS, SEM, 13C ss-NMR, and TG-DSC. The results indicate that the crude oil composition determines the coking mechanisms: Xinjiang oil, rich in cyclic hydrocarbons and O/N/S heteroatoms, forms high-yield, compact, sheet- or block-like coke at 350 °C via π–π stacking. In contrast, Menggulin oil, composed primarily of long-chain alkanes, yields loose coke at 350 °C but produces dense, highly aromatized coke at 450 °C, which corresponds to the critical alkane cracking temperature, through intense cracking–polymerization. Temperature differentially regulates oxidative processes, thereby shaping the divergent functional group distributions. Correlations between coke structure and combustion properties reveal that oxygenated/aliphatic-rich cokes exhibit high reactivity, whereas aromatized cokes release more heat. These findings provide guidance for ISC optimization, suggesting that sufficient high-temperature energy is required for paraffinic oils while medium-temperature oxidation regulation is suitable for naphthenic oils. This work advances the theory of ISC coke formation and supports enhanced recovery of heavy oils.
Open AccessStudy on the Influence of Composition Differences in Heavy Oil Components on In-Situ Combustion Coking Performance
This study investigates coke formation, structure, and combustion behaviors in paraffin-based Menggulin and naphthenic-based Xinjiang heavy oils under simulated in-situ combustion (ISC) conditions (350 °C, 450 °C), utilizing GC-MS, SEM, 13C ss-NMR, and TG-DSC. The results indicate that the crude oil composition determines the coking mechanisms: Xinjiang oil, rich in cyclic hydrocarbons and O/N/S heteroatoms, forms high-yield, compact, sheet- or block-like coke at 350 °C via π–π stacking. In contrast, Menggulin oil, composed primarily of long-chain alkanes, yields loose coke at 350 °C but produces dense, highly aromatized coke at 450 °C, which corresponds to the critical alkane cracking temperature, through intense cracking–polymerization. Temperature differentially regulates oxidative processes, thereby shaping the divergent functional group distributions. Correlations between coke structure and combustion properties reveal that oxygenated/aliphatic-rich cokes exhibit high reactivity, whereas aromatized cokes release more heat. These findings provide guidance for ISC optimization, suggesting that sufficient high-temperature energy is required for paraffinic oils while medium-temperature oxidation regulation is suitable for naphthenic oils. This work advances the theory of ISC coke formation and supports enhanced recovery of heavy oils.